• Title/Summary/Keyword: calcium carbonate content

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Effect of Filter and Shrinkage Reducing Agent Influencing on Setting Shrinkage and Strength Properties of MMA-Modified Polymer Paste (충전재와 수축저감제가 MMA개질 폴리머 페이스트의 경화수축 및 강도특성에 미치는 영향)

  • Yeon, Kyu-Seok;Beck, Jong-Man;Jin, Xing-Qi;Lee, Chi-Won
    • Journal of the Korea Concrete Institute
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    • v.18 no.2 s.92
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    • pp.227-232
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    • 2006
  • This article presents the results of experimental study that investigates the effect of filler and shrinkage reducing agent influencing on the strength properties of MMA-modified polymer paste that was produced to develop the surface-repair and coating materials of the concrete structures. Results show that the flexural and compressive strengths of the polymer paste increased 29 and 27%, respectively, when the aluminum hydroxide completely replaced the calcium carbonate as the filler Furthermore, when the shrinkage reducing agent was used 30%, both strengths decreased about 29% comparing to when the agent was not used. As in the cases of flexural and compressive strengths, the adhesive strength increased as the content of aluminum hydroxide as the filler increased, and it decreased as the content of shrinkage reducing agent increased. The adhesive strength with a dry concrete substrate turned out to be $30{\sim}40%$ higher than that with a wet concrete substrate.

Analysis of carbonation characteristics on waste concrete (폐콘크리트의 탄산화 특성 분석)

  • Kim, Nam Il;Lee, Jong Tae;Chu, Yong Sik
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.4
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    • pp.151-158
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    • 2022
  • In this study, the waste concrete sample obtained as various particle size (0~2.36 mm) was carried out the basic measurements and carbonation for analyzing the possibility of its carbonation. It was then investigated some analysis such as crystallization (XRD pattern), microstructure (SEM), and the production of CaCO3 through the ignition loss (TG-DTA). The content of CaCO3 in the waste concrete sample before carbonation was found in 14.51 % and 28.52 % after carbonation in 24 hours. Moreover, the content of CaCO3 carbonated in 24 hours with fine grinded waste concrete sample was 32.73 %. The carbonation of the waste concrete sample was rapidly performed up to 6 hours, but gradually increased from 12 to 24 hours. Especially, the amount of CaCO3 between 12 and 24 hours was only produced 2.32 %. The calcite-shaped CaCO3 crystals after carbonation of the waste concrete sample were found in microstructure and their peaks were strongly detected on XRD pattern.

Manufacturing and Physicochemical Properties of Wine using Hardy Kiwi Fruit (Actinidia arguta) (다래를 이용한 발효주의 제조 및 이화학적 특성)

  • Park, Kyung Lok;Hong, Sung Wook;Kim, Young Joon;Kim, Soo Jae;Chung, Kun Sub
    • Microbiology and Biotechnology Letters
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    • v.41 no.3
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    • pp.327-334
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    • 2013
  • For the development of hardy kiwi wine, we arranged for the post-maturity of hardy kiwi fruit, treated them with calcium carbonate and a pectinase enzyme complex, investigated the resulting physicochemical properties and conducted a sensory evaluation. The period determined for creating post-maturity in the hardy kiwi fruit was determined as 5 days storage at room temperature following maturity. During this time the yield of fruit juice was increased from 22.1% to 53.5% using 0.1% (v/v) cytolase PCL5 for 2 h at room temperature. 0.1% (w/v) calcium carbonate was also added during the process of aging, for the reduction of the sour taste. The fermentation trial of the hardy kiwi wine was prepared using water (25% or 50%), sugar ($24^{\circ}brix$), 0.1% (w/v) $CaCO_3$, 0.1% (v/v) cytolase PCL5, $K_2S_2O_5$ (200 ppm), and yeast ($1.5{\times}10^7$ cell/ml). Fermentation then occurred for 2 weeks at $20^{\circ}C$. The pH value, total acidity, alcohol, and reducing sugar content of the resulting hardy kiwi wines of 25% (v/w) and 50% (v/w) water, were in a range of pH 3.4-3.7, 1.12-1.21%, 14.3-14.4%, and 15-16 g/l, respectively. Citric acid and fructose constituted the major organic acids and the free sugar of the 25% and 50% hardy kiwi wine, respectively. Volatile flavor components, including 10 kinds of esters, 8 kinds of alcohols, 5 kinds of acids, 3 kinds of others and aldehydes, were determined by GC analysis. The results of sensory evaluation demonstrated that 50% hardy kiwi wine is more palatable than 25% hardy kiwi wine.

Mineralogical Analysis of Calcium Silicate Cement according to the Mixing Rate of Waste Concrete Powder (폐콘크리트 미분말 치환율에 따른 이산화탄소 반응경화 시멘트의 광물상 분석)

  • Lee, Hyang-Sun;Song, Hun
    • Journal of the Korea Institute of Building Construction
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    • v.24 no.2
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    • pp.181-191
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    • 2024
  • In the realm of cement manufacturing, concerted efforts are underway to mitigate the emission of greenhouse gases. A significant portion, approximately 60%, of these emissions during the cement clinker sintering process is attributed to the decarbonation of limestone, which serves as a fundamental ingredient in cement production. Prompted by these environmental concerns, there is an active pursuit of alternative technologies and admixtures for cement that can substitute for limestone. Concurrently, initiatives are being explored to harness technology within the cement industry for the capture of carbon dioxide from industrial emissions, facilitating its conversion into carbonate minerals via chemical processes. Parallel to these technological advances, economic growth has precipitated a surge in construction activities, culminating in a steady escalation of construction waste, notably waste concrete. This study is anchored in the innovative production of calcium silicate cement clinkers, utilizing finely powdered waste concrete, followed by a thorough analysis of their mineral phases. Through X-ray diffraction(XRD) analysis, it was observed that increasing the substitution level of waste concrete powder and the molar ratio of SiO2 to (CaO+SiO2) leads to a decrease in Belite and γ-Belite, whereas minerals associated with carbonation, such as wollastonite and rankinite, exhibited an upsurge. Furthermore, the formation of gehlenite in cement clinkers, especially at higher substitution levels of waste concrete powder and the aforementioned molar ratio, is attributed to a synthetic reaction with Al2O3 present in the waste concrete powder. Analysis of free-CaO content revealed a decrement with increasing substitution rate of waste concrete powder and the molar ratio of SiO2/(CaO+SiO2). The outcomes of this study substantiate the viability of fabricating calcium silicate cement clinkers employing waste concrete powder.

Processing Condition of Seasoning Material of the Mixture of Laminaria and Enzyme-Treated Mackerel Meat (다시마와 효소처리 고등어육을 이용한 조미소재의 제조 조건)

  • Lee, Kang-Ho;Song, Byung-Kwon;Jeong, In-Hak;Hong, Byeong-Il;Jung, Byung-Chun;Lee, Dong-Ho
    • Korean Journal of Food Science and Technology
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    • v.29 no.1
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    • pp.77-81
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    • 1997
  • In order to develop a new type of natural seasoning material combining fish meat with seaweed, a processing method of the mixture of enzyme treated mackerel meat and Laminaria powder was studied. Mackerel meat previously boiled and deboned was treated with proteolytic enzyme to enhance taste of meat by proper hydrolysis. The enzyme-treated meat was dried at $100{\pm}2^{\circ}C$ for 4 hrs, and finally mixed with kelp power, moistened in advance, plus binding agents (0.02% calcium carbonate) to aid the formation of pellets by extrusion. Boiled mackerel meat of enzyme treated (0.03% Protease-A) at $50^{\circ}C$ for 90 min was adequate to result an increase in 6 times of total free amino acid content and about 10% increase of taste-enhancing amino acids such as glutamic acid, glycine, arginine, lysine.

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Geochemical Characteristics of Surface Sediments in the Eastern Part of the Yellow Sea and the Korean West Coast (황해 동부 대륙붕과 한반도 서해안 표층퇴적물의 지구화학적 특성)

  • 조영길;이창복;박용안;김대철;강효진
    • The Korean Journal of Quaternary Research
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    • v.7 no.1
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    • pp.69-91
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    • 1993
  • A total of 76 surface sediment samples, collected from the Korean west coast and the eastern Yellow Sea areas, were analyzed for their elemental composition in order to understand the geochemical characteristics of these deposits. The analyzed elements included 9 major elements (Al, Fe, Na, K, Mg, Ca, Ti, P, Mn), 8 minor elements (Sr, Ba, V, Cr, Co, Ni, Cu, Zn), organic carbon and calcium carbonate. Contents of most analyzed elements, excluding K and Ba, were generally low compared to those of average crust. Contents of most elements, except K and Ca, also correlated with sediment grain size, though the degree of relationship varied widely from one element to another. For fine-grained sediments, a distinction could be made between those in the central Yellow Sea and those in the Keum Estuary based on their characteristic elemental composition: the former were rich in Fe, Na, K, Mg, Ca and V, and the latter in Mn, Co and Ni. The element/aluminium ratios, on the other hand, showed that the central Yellow Sea muds were enriched in Fe, Mg, V, Ni, Cu and Zn and depleted in K, Mn, Ba and Sr relative to the mud located near the Korean Peninsula. Based on the analysis of these results, as well as of the influences of particular mineral phases or pollution effects, we could suggest geochemical criteria which can be used in distinguishing muds from the two different sources, the Keum River and the Yellow River: the former by the higher Mn content and the latter by the higher Mg and V contents, relative to each other.

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Sedimentary Facies and Environmental Changes of the Nakdong River Estuary and Adjacent Coastal Area (낙동강 하구와 주변 연안역의 표층 퇴적상 및 퇴적환경 변화)

  • KIM Seok-Yun;HA Jeong-Su
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.3
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    • pp.268-278
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    • 2001
  • To investigate sedimentary facies and environmental changes of the Nakdong River Estuary and its adjacent coastal area, the grain size analysis and measurement of organic matter, calcium carbonate, clay mineral and metallic elements were carried out for forty surface sediment samples. Based on regional distribution pattern and characteristics of the surface sediments, sedimentary facies in the study area can be divided into sand facies (TYPE I), mud facies (TYPE II) and sand-mud mixed facies (TYPE III). TYPE III is the transition of TYPE I and TYPE II in every aspects of sediment characteristics. It suggests that TYPE III may have been formed by the mixture of two different source of sediment : one derived from Nakdong River and the other resuspended fine-grained sediments from the Jinhae Bay by winnowing action during floods or storms. Among many aspects of environmental change after the construction of the Nakdong Barrage, the most significant is the increase of sand content off the sand barrier region. It could be explained by several reasons including decreased input of fine-grained sediment from river, increased hydrodynamic energy level off the sand barrier region and artificial effects such as dredging and dumping.

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Physical and Mechanical Properties of Polymer Concrete Using Recycled Aggregate (재생골재를 사용한 폴리머 콘크리트의 물리·역학적 특성)

  • Sung, Chan-Yong;Baek, Seung-Chul
    • Korean Journal of Agricultural Science
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    • v.32 no.1
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    • pp.19-27
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    • 2005
  • This study was performed to evaluate the physical and mechanical properties of polymer concrete using unsaturated polyester resin, initiator, heavy calcium carbonate, crushed gravel, recycled coarse aggregate, silica sand and recycled fine aggregate. The unit weight, compressive strength, flexural strength and dynamic modulus of elasticity were decreased with increasing the content of recycled aggregate. The unit weight, compressive strength, flexural strength and dynamic modulus of elasticity were showed in $2,127{\sim}2,239kg/m^3$, 80.5~88.3MPa, 19.2~21.5MPa and $254{\times}10^2{\sim}288{\times}10^2MPa$ at the curing age 7 days, respectively. Therefore, these recycled aggregate can be used for polymer concrete.

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Biochemical and cultural characteristics of mineral-solubilizing Acinetobacter sp. DDP346 (미네랄 가용화능을 갖는 Acinetobacter sp. DDP346의 생화학적 및 배양학적 특성)

  • Kim, Hee Sook;Lee, Song Min;Oh, Ka-Yoon;Kim, Ji-Youn;Lee, Kwang Hui;Lee, Sang-Hyeon;Jang, Jeong Su
    • Journal of Applied Biological Chemistry
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    • v.64 no.4
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    • pp.333-341
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    • 2021
  • In this study, to select strains suitable as microbial agent from among rhizosphere microorganisms present in rhizosphere soil and roots, the mineral solubilization ability, antifungal activity against 10 types of plant pathogenic fungi, and plant growth-promoting activity of rhizosphere microorganisms were evaluated. As a result, DDP346 was selected because it has solubilization ability of phosphoric acid, calcium carbonate, silicon, and zinc; nitrogen fixing ability; production ability of siderophore, indole-3-acetic acid, and aminocyclopropane-1-carboxylate deaminase; and antifungal activity against seven types of plant pathogenic fungi. DDP346 showed a 99.9% homology with Acinetobacter pittii DSM 21653 (NR_117621.1); phylogenetic analysis also revealed a close relationship with Acinetobacter pittii based on the 16S rRNA base sequence. The growth conditions of DDP346 were identified as temperatures in the range of 10-40 ℃, pH in the range of 5-11, and salt concentrations in the range of 0-5%. In addition, a negative correlation coefficient (r2 = -0.913, p <0.01) was shown between pH change and the solubilized phosphoric acid content of Acinetobacter sp. DDP346, and this is assumed to be due to the organic acid generated during culture. Consequently, through the evaluation of its mineral solubilization ability, antifungal activity against plant pathogenic fungi, and plant growth-promoting activity, the potential for the utilization of Acinetobacter sp. DDP346 as a multi-purpose microbial agent is presented.

Characteristics of Direct Aqueous Carbonation Reaction Using Incinerated Ash and Industrial By-Products (소각재 및 산업부산물을 이용한 직접 수성탄산화 반응 특성)

  • Dong Kyoo Park;Seungman Han;Changsik Choi
    • Clean Technology
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    • v.30 no.2
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    • pp.113-122
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    • 2024
  • In order to better understand carbon dioxide recycling, the carbon dioxide capture characteristics of six different alkaline industrial by-products, including incineration ash, desulfurized gypsum, low-grade quicklime, and steelmaking slag were investigated using a laboratory-scale direct aqueous carbonation reactor. In addition to the dissolution characteristics of each sample, the main reaction structure was confirmed through thermogravimetric analysis before and after the reaction, and the reactive CaO content was also defined through thermogravimetric analysis. The carbon dioxide capture capacity and efficiency of quicklime were determined to be 473 g/kg and 86.9%, respectively, and desulfurized gypsum and incineration ash were also evaluated to be relatively high at 51.1 to 131.7 g/kg and 51.2 to 87.7%, respectively. On the other hand, the capture efficiency of steelmaking slag was found to be less than 10% due to the influence of the production and post-cooling conditions. Therefore, in order to apply the carbonation process to steelmaking slag, it is necessary to optimize the slag production conditions. Through this study, it was confirmed that the carbon dioxide capture characteristics of incineration ash, quicklime, and desulfurized gypsum are at levels suitable for carbonation processes. Furthermore, this study was able to secure basic data for resource development technology that utilize carbon dioxide conversion to produce calcium carbonate for construction materials.