• Journal of Preventive Medicine and Public Health
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• 제21권1호
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• pp.121-131
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• 1988

This study was performed to investigate the heavy metal contents of freshwater fishes. The samples of 24 species were collected at 7 areas located on the Mankyung River during September in 1987. And then the contents of lead, cadmium, copper and zine were analyzed by atomic absorption spectrophotometer. The results were summarized as follows ; 1. The mean value of lead, cadmium, and copper contents of fishes collected in the downstream were significantly higher than those of upstream. 2. The mean lead content of C. auratus was the highest $1.50{\pm}0.98{\mu}g/g$ in viscera and statistically significant difference from muscle content. 3. The mean cadmium content of C. auratus was the highest $0.087{\pm}0.054{\mu}g/g$ in viscera and significantly higher than that of muscle. 4. In the copper contents, the viscera of C. auratus was the highest $5.25{\pm}0.94{\mu}g/g$ and significantly higher than that of muscle, skeleton and gill. 5. The mean value of zinc content of C. auratus was shown the order of gill, skeleton, viscera and muscle.

• 한국환경농학회지
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• 제5권1호
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• pp.61-66
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• 1986

소석회(消石灰)와 유기물(有機物)의 병용(竝用) 및 규산(硅酸)칼슘의 시용(施用)이 카드뮴으로 오염(汚染)된 토양(土壤)에서 배추의 생육(生育) 및 Cd 함량(含量)에 주는 영향(影響)을 밝히기 위(爲)하여 카드뮴이 처리(處理)된 토양(土壤) 150g 씩을 담은 소형(小型) 화분(花盆)에 시험(試驗)한 결과(結果)는 다음과 같다. 1. 소석회(消石灰) 단용(單用)은 1, 2작(作)에서 배추의 생육(生育)을 심(甚)히 억제(抑制)시켰으며 제(第) 3작(作)에 가서는 오히려 다른 처리구(處理區)보다 생육(生育)을 왕성(旺盛)하게 하였다. 2. 소석회(消石灰)+유기물구(有機物區)는 초기(初期)부터 배추생육(生育)이 량호(良好)하였고, 배추의 Cd 함량(含量)도 소석회단용구(消石灰單用區) 이하(以下)로 낮추었으며 그 효과(效果)는 3작(作)까지 계속(繼續)되었다. 3. 규산(硅酸)칼슘은 토양(土壤)의 pH에는 큰 영향(影響)을 못주면서도 배추를 정상적(正常的)으로 생육(生育)케 하고 소석회(消石灰)만은 못하였으나 배추의 생육(生育)을 억제(抑制)하지 않는 범위(範圍)인 건조(乾燥) 배추 100g 당(當) 0.21me까지 Cd함량(含量)을 감소(減少)시켰다. 4. 대조구(對照區)와 유기물(有機物)만을 단용(單用)했을 때는 토양(土壤)의 pH가 심(甚)히 낮아지고 배추의 Cd함량(含量)도 높았으며 2작(作)부터는 배추가 거의 다 고사(枯死)되었다. 5. 배추의 Cd함량(含量)은 Ca흡수량(吸收量)과는 부상관(負相關), Mg, K, 함량(含量)과는 정상관(正相關)을 보였는데 Mg 함량(含量)과 더 밀접(密接)한 상관(相關)을 갖고 특(特)히 재배(栽培)가 거듭될수록 동관계(同關係)는 더 현저(顯著)하였다.

• 대한수의사회지
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• 제29권3호
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• pp.160-164
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• 1993

In order to clarify the cadmium contents of normal dogs, tissue samples including liver, kidney, muscle, skin and hair were collected from 50 dogs which were slaughtered in Dae Gu area. All samples were dry ashed and analyzed for cadmium content by atomic

• 한국임상수의학회지
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• 제9권1호
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• pp.267-271
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• 1992

Present study was undertaken in order to evaluate the cadmium contents of various feedstuffs produced in Chonbuk area. Fifty-five samples were collected from 5 regions. All of the samples were dry-ashed and analyzed for cadmium content using atomic absorption spectrophotometer. The results obtained were summarized as followed : 1. The cadmium content in $\mu\textrm{g}$/g of agriculture by-products were measured with the following mean values and ranges : soybean pod 3.15${\pm}$0.51(2.40∼3.81), rice bran 2.87${\pm}$0.23(2.50∼3.09), rice straw 1.66${\pm}$0.85(1.08∼3.14), rice hull 0.86${\pm}$0.45(0.41∼1.35). 2. The cadmium content in $\mu\textrm{g}$/g of pasture plants were measured with the following mean values and ranges : kudzu 5.65${\pm}$1.00(4.87∼7.29), sagebrush 4.86${\pm}$1.24(2.89∼6.24), clove, 4.28${\pm}$0.75(2.99∼4.86), lespedeza 3.99${\pm}$1.21(2.38∼4.94), Korean lawn grass 2.24${\pm}$1.04(1.33∼3.44), reed 1.99${\pm}$0.95(0.88∼2.91), cornstalk 1.61${\pm}$0.99(0.38∼3.12). 3. The regional mean values for all kinds of samples were Okgu-gun 3.19${\pm}$2.09$\mu\textrm{g}$/g, Mooju-gun 3.15${\pm}$1.73$\mu\textrm{g}$/g, Wanju-gun 3.05${\pm}$1.76$\mu\textrm{g}$/g, Namwon-gun 2.85${\pm}$1.70$\mu\textrm{g}$/g, Jeongup-gun 2.85${\pm}$1.25$\mu\textrm{g}$/g.

• 한국환경보건학회지
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• 제8권1호
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• pp.31-43
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• 1982

Seventy-seven Mugil cephalus of spinal deformation, living in Hanam, Nogsan, and Myeongji area, the downstreams of the Nagdong River, were collected in order to determine their forms and the levels of heavy metal contamination between March and October, 1981. The specimens were examined by X-ray and content of cadmium, lead, copper, and zinc by atomic absorption spectrophotometer. The results were summarized as follows: 1. The rate of appearance of deformational fish to the total Mugil cephflus were 4.3% (13 fish), 5.7% (17 fish), relatively high in May and June (dry season). Meanwhile during March and October they were low by 1.0% (3 fish), 2.0% (6 fish). As far as the research areas are concerned, they appeared in larger numbers in downstreams than in upper streams Myeongji (39), Nogsan (25), and Hanam (13). 2. Concerning with fractured parts of vertebraes,86 percent (66 out of 77) had their caudal regions fractured and 72 percent (55) their first to seventh caudal regions fractured. 3. The average levels of cadmium, lead, copper, zinc detected from flesh were 0.26ppm, 2.06ppm, 6.35ppm, 0.85ppm on the other hand, they were 0.22ppm, 1.84ppm, 5.03ppm, 0.93ppm in normal fish. 4. The average levels of cadmium, lead, copper, zinc measured in the bones were 0.39ppm, 2.55ppm, 8.97ppm, 2.73ppm. Meanwhile, from normal fish they were 0.33ppm, 2.25ppm, 7.24ppm, 2.42ppm. 5. Compared with regional heavy metal contamination such as cadium, lead, zinc, Myeongji area had higher contamination content than Nogsan area Nogsan area than Hanam area. 6. Compared with heavy metal contamination level in their tissues, cadmium was highly found in bones Lead and copper were highly detected in viscera. Particularly in skeleton cadmium was 560 times, zinc 160 times in proportion to those in the downstreams of the Nagdong River.

• 한국식품영양과학회지
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• 제28권6호
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• pp.1355-1363
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• 1999

The purpose of this study was to investigate the effects of vitamin E on liver microsomal cytochrome P450 contents and xanthine oxidase activity in acute cadmium poisoned rats. Sprague Dawley male rats weighing 100$\pm$10g were randomly assigned to one normal and three cadmium injected groups. Cadmium injected groups were fed vitamin E free diet(0E Cd group), 40mg vitamin E per kg diet(40E Cd group) or 400mg vitamin E per kg diet(400E Cd group). Vitamin E level of normal group was 40mg per kg diet. Animals were injected intraperitoneally with 2.0mg Cd2+/kg bw for 4 days after the rats were fed diets with three different levels of vitamin E for 2 and 4 weeks. Body weight, food intake and feed efficiency ratio of cadmium injected animals, were decreased compared with those of normal group. The weights of liver and kidney in cadmium injected groups were not different from those of normal group. Cadmium contents of liver in cadmium groups were 160 fold higher those that of normal group. Accumulation of cadmium poisoned rat liver was reduced by vitamin E supplementation. Contents of blood hemoglobin and hematocrit in 0E Cd groups were decreased to 2~ 14% of those of the other groups. Contents of serum triglyceride in all experimental groups were not significantly different each other. Levels of serum total cholesterol, LDL cholesterol and antherogenic index in 0E Cd and 40E Cd groups were higher than those of normal group, while the contents of HDL cholesterol in 0E Cd and 40E Cd groups were lower than those of normal group. Xanthine oxidase(XOD) activity and cytochrome P450 contents in the liver were significantly increased in cadmium injected groups but these were reduced by vitamin E supplementations. The present results indicate that acute cadmium poisoning in rats causes increasing free radical generation systems in the liver and that leads to liver tissue damage. But these abnormalities can be reduced by dietary vitamin E supplementations.

• 자원환경지질
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• 제19권spc호
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• pp.139-149
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• 1986

국내(國內)의 여러 열수금속광상(熱水金屬鑛床)에서 채취(採取)한 섬아연석(閃亞鉛石)의 조성(組成) 변화(變化)를 광산(鑛山) 및 국지적(局地的) 단위(單位), 그리고 광역적(廣城的) 단위(單位)로 조사(調査)하였다. 섬아연석(閃亞鉛石)의 Fe, Mn, Cd 함량(含量)은 electron probe microanalyzer(EPMA) 에 의한 부분분석(部分分析) 방법(方法)으로 측정(測定)하였다. 제1연화광산(第一蓮花鑛山)의 월암광산(月岩鑛山)에서 심도별(深度別)(0m에서 -420m level까지)로 채취(採取)한 섬아연석(閃亞鉛石)의 경우 Fe, Cd 함량(含量)은 심도(深度)에 따라 큰 변화(變化)가 없는 반면(反面) Mn 함량(含量) 변화(變化)는 현저하였다. 반심성암(半深成岩) 및 분출암(噴出岩)의 활동(活動)과 성인적(成困的)으로 관련(關聯)된 Zn-Pb 광상(鑛床)의 경우 섬아연석(閃亞鉛石)은 그 Mn 함량(含量)이 높고 (MnS 1.0 mole% 이상(以上)) Cd 함량(含量)이 낮은 (CdS 0.5 mole% 이하(以下)) 특징(特徵)을 보인다. 비교적(比較的) Mn함량(含量)이 높은 섬아연석(閃亞鉛石)은 Fe함량(含量)도 높다. 일반적(一般的)으로 각(各) 광상별(鑛床別)로 보면 Mn에 비(比)해 Cd 함량변화(含量變化)는 일정(一定)하다. 대부분(大部分)의 W광상(鑛床)과 일부(一部) Au-Ag광상(鑛床)에서 산출(産出)된 섬아연석(閃亞鉛石)의 경우 Cd함량(含量)이 현저하게 높으나, 대부분(大部分)의 base metal 광상(鑛床) 및 Fe광상(鑛床)에서는 Cd함량(含量)이 낮다. 성인적(成因的)으로 심성암(深成岩)의 활동(活動)과 관련(關聯)된 금속광상(金屬鑛床)에서 산출(産出)되는 섬아연석(閃亞鉛石)의 Cd 함량(含量) 변화(變化)는 다양한 경향을 나타낸다. 섬아연석중(閃亞鉛石中)의 Cd 근원(根源)은 magma성(性) 내지(乃至)는 후(後) magma성(性)과정중(過程中) 원래(原來)부터 존재(存在)하던 유용(有用) 함량(含量)에 기인(起因)된다고 판단(判斷)된다.

• 한국토양비료학회지
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• 제11권2호
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• pp.113-118
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• 1979

수도에 대한 Cd, Cu, Zn, 등(等) 중금속(重金屬) 원소(元素)들의 흡수억제(吸收抑制) 방법(方法)을 구명(究明)하기 위하여 물관리(管理) 및 석고시용(石膏施用)에 의(依)하여 수도 품종별(品種別) 중금속(重金屬) 흡수(吸收)에 미치는 영향(影響)을 검토한 결과(結果)는 다음과 같다. 1. 수도 전(全) 생육기간(生育期間)동안 계속담수(繼續湛水)로 토양(土壤)을 환원상태(還元狀態)로 유지(維持) 함으로서 산화상태(酸化狀態)보다 현미중(玄米中) Cd 함량(含量)을 현저(顯著)히 감소시켰으며, 환원상태하(還元狀態下)에서 석고(石膏)를 처리(處理)하므로서 더욱 효과적 이었다. Cu, Zn에 대하여도 같은 경향(傾向)을 보였으나 Cd 보다는 그 효과가 현저(顯著)하지는 못하였다. 2. 토양(土壤)의 환원조건(還元條件)에 의(依)한 중금속(重金屬) 흡수(吸收) 억제효과는 통일(統一)>밀양(密陽)23호>아끼바레>육농나>노인도>진흥(振興)의 순(順)이었다. 3. 산화상태(酸化狀態)에서 수도 품종별(品種別) 중금속(重金屬)의 흡수(吸收)는 통일(統一)이 기타(其他)의 품종(品種)(진흥(振興), 아끼바레, 밀양(密陽)23호, 육농나) 보다 컸다.

• Journal of Preventive Medicine and Public Health
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• 제17권1호
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• pp.269-279
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• 1984

The optimum conditions for measuring cadmium content of less than 0.2ppm by flame atomic absorption spectrophotometry were investigated. The cadmium in urine was extracted by APDC-MIBK for the analysis by atomic absorption spectrophotometry after ashing them by a wet method. 1. Optimum conditions by APDC-MIBK and DDTC-MIBK extractions. The acidic aqueous solution was prepared with appropriate amount of 0.IN nitric acid, 5ml of 25% (W/V) sodium potasstum tartarate, 10ml of saturated ammonium sulfate, and 2ml of 2% APDC(or 1 ml of 5% DDTC) chelating agent. The total volume of solution was adjusted to 55 ml and pH to $2{\sim}10$ (or$7{\sim}10$). The aqueous solution was extracted with 10ml MIBK. Concentration of Triton X-100 did not effect the absorbance for APDC-MIBK extraction of cadmium, but absorbance decreased as the concentration increased for DDTC-MIBK extraction. The sensitivity and detection limits for the cadmium determination from APDC-MIBK extraction were 0.0038ppm and 0.0102, 0.0022ppm and 0.0116 for DDTC-MIBK, and 0.0132ppm and 0.0034 for 0.1N nitric acid. APDC-MIBK and DDTC-MIBK extractions were 3 times higher than 0.1N nitric acid for the sensitivity. 2. Excretion of cadmium in 24-hour urine by APDC-MIBK extraction. Determination of cadmium in urine by atomic absorption spectrophotometry of A.A. (Cd=2 mA) mode and B.C. (Cd=4 mA) mode and B.C. (Cd=4mA, $D_2=20mA$) mode showed some difference (p<0.05). The difference of cadmium determination and recovery according to method of standard additions and standard calibration curve method in urine was not significant (p>0.05, $93.48{\pm}11.78%,\;94.83{\pm}22.00%$). Excretion of cadmium in 24-hour urine collection from normal person and variance analysis within measurement variation was not significant (p>0.05), but between interindividual was significant (0.05). Determination of cadmium content by two different methods of flame atomic absorption spectrophotometry and dithizone colorimetry showed that the results from the two methods can be described by a regression line with a good correlation (y=1.0153x-0.2927, x=Cd by D.C., y=Cd by A.A.S., $r=0.8651^*$, p<0.01).

• 한국환경보건학회지
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• 제13권2호
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• pp.45-49
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• 1987

This study was carried out to determine the content of heavy metals in Crayons and Oil Pastele. Samples were collected from 3 manufacturing companies of Crayons and 2 manufacturing comppanies of Oil Pastele. The content of lead and cadmium were analyzed by flame atomic absorption spectrophotometer. The results obtained were as follows: 1. The average content of lead in Crayons and Oil Pastele were 26.2 ppm, 70.5 ppm, and the range 11.0-69.5 ppm, 26.5-353.0 ppm respectively. 2. The average content of cadmium in Crayons and Oil Pastele were all 4.1 ppm and range were 3.0-5.0 ppm, 2.5-5.0 ppm respectively.