• Title/Summary/Keyword: cadmium analysis

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QTL analysis of for micronutrient content in rice grain

  • Lee, Hyun-Sook;Shim, Kyu-Chan;Jeon, Yun-A;Ahn, Sang-Nag
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.144-144
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    • 2017
  • Micronutrients such as zinc (Zn), iron (Fe), manganese (Mn) have important roles for development and growth in plants but it also have roles in animals and humans. In previous studies, a Korean weedy rice, KH2J was selected to have tolerance to heavy metal, lead (Pb) compared with a cultivar, Milyang23. To identify QTLs for micronutrients concentration in grain, an F2 population (120 plants) were developed from a cross between KH2J and an indica rice cultivar, Milyang23. To measure the concentration of eight ions, Zn, Fe, Mn, Pb, calcium (Ca), copper (Cu), cadmium (Cd) and arsenic (As), grains were collected and digested with 65% nitric acid, and the ion contents were measured using inductively coupled plasma mass spectrometry. A total 27 putative quantitative trait loci (QTLs) were detected on 12 chromosomes by single point analysis and 22 putative QTLs were detected by composite interval mapping. The co-locations of QTL for Zn, Fe and Mn were observed on chromosome 5. The QTLs for Cd, Cu and Zn were co-localized on chromosome 10, and QTLs for Zn, As and Mn was on chromosome 12. The Zn concentration in F2 generation showed significant correlation with concentrations of As (r = -0.4), Cu (r = 0.5) and Fe (r = 0.2) (P < 0.01). Also, the Ca concentration was significantly related with Mn and Fe concentrations (P < 0.01). Fine mapping of these QTLs is underway to analyze their functional relationship.

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Analysis of Chemical Composition and Antioxidant Activity of Suaeda japonica (칠면초의 성분 분석 및 추출물의 항산화 효과)

  • Lee, Kyung-Seok;Kim, Ae-Jung;Lee, Ki-Young
    • Journal of the East Asian Society of Dietary Life
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    • v.22 no.4
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    • pp.521-526
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    • 2012
  • This study was conducted in order to analyze the ingredients and antioxidant activity of Suaeda japonica (turkey), which is abundantly present in Korea where mud flats are well formed due to the characteristics of halophytes. In the analysis of general composition, contents of carbohydrates, proteins, ash, and moisture were 10.7%, 8.3%, 7.6%, and 72.5% respectively. Among minerals, sodium was measured as 5.4%, which means that most ash was made of sodium. Heavy metal contents of lead, cadmium, arsenic, and mercury were 0.86 ppm, 0.04 ppm, 0.39 ppm, and 0.01 ppm, meaning Suaeda japonica satisfied standard food values. The 70% ethanol extract from Suaeda japonica was evaluated for its free radical scavenging activity and compared with a commercial antioxidant, BHA (butylated hydroxyanisole). As a result, the scavenging activities of hydroxyl radical, hydrogen peroxide, and xanthine oxidase of the extracts were equivalent to 30~50% of that of BHA.

Photoluminescent Graphene Oxide Microarray for Multiplex Heavy Metal Ion Analysis

  • Liu, Fei;Ha, Hyun Dong;Han, Dong Ju;Park, Min Su;Seo, Tae Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.281.2-281.2
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    • 2013
  • Since heavy metal ions included in water or food resources have critical effects on human health, highly sensitive, rapid and selective analysis for heavy metal detection has been extensively explored by means of electrochemical, optical and colorimetric methods. For example, quantum dots (QDs), such as semiconductor QDs, have received enormous attention due to extraordinary optical properties including high fluorescence intensity and its narrow emission peaks, and have been utilized for heavy metal ion detection. However, the semiconductor QDs have a drawback of serious toxicity derived from cadmium, lead and other lethal elements, thereby limiting its application in the environmental screening system. On the other hand, Graphene oxide (GO) has proven its superlative properties of biocompatibility, unique photoluminescence (PL), good quenching efficiency and facile surface modification. Recently, the size of GO was controlled to a few nanometers, enhancing its optical properties to be applied for biological or chemical sensors. Interestingly, the presence of various oxygenous functional groups of GO contributes to opening the band gap of graphene, resulting in a unique PL emission pattern, and the control of the sp2 domain in the sp3 matrix of GO can tune the PL intensity as well as the PL emission wavelength. Herein, we reported a photoluminescent GO array on which heavy metal ion-specific DNA aptamers were immobilized, and sensitive and multiplex heavy metal ion detection was performed utilizing fluorescence resonance energy transfer (FRET) between the photoluminescent monolayered GO and the captured metal ion.

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Characteristics of radiographic images acquired with CdTe, CCD and CMOS detectors in skull radiography

  • Queiroz, Polyane Mazucatto;Santaella, Gustavo Machado;Lopes, Sergio Lucio Pereira de Castro;Haiter-Neto, Francisco;Freitas, Deborah Queiroz
    • Imaging Science in Dentistry
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    • v.50 no.4
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    • pp.339-346
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    • 2020
  • Purpose: The purpose of this study was to evaluate the image quality, diagnostic efficacy, and radiation dose associated with the use of a cadmium telluride (CdTe) detector, compared to charge-coupled device (CCD) and complementary metal oxide semiconductor(CMOS) detectors. Materials and Methods: Lateral cephalographs of a phantom (type 1) composed of synthetic polymer filled with water and another phantom (type 2) composed of human skull macerated with polymer coating were obtained with CdTe, CCD, and CMOS detectors. Dosimeters placed on the type 2 phantom were used to measure radiation. Noise levels from each image were also measured. McNamara cephalometric analysis was conducted, the dentoskeletal configurations were assessed, and a subjective evaluation of image quality was conducted. Parametric data were compared via 1-way analysis of variance with the Tukey post-hoc test, with a significance level of 5%. Subjective image quality and dentoskeletal configuration were described qualitatively. Results: A statistically significant difference was found among the images obtained with the 3 detectors(P<0.05), with the lowest noise level observed among the images obtained with the CdTe detector and a higher subjective preference demonstrated for those images. For the cephalometric analyses, no significant difference (P>0.05) was observed, and perfect agreement was seen with regard to the classifications obtained from the images acquired using the 3 detectors. The radiation dose associated with the CMOS detector was higher than the doses associated with the CCD (P<0.05) and CdTe detectors(P<0.05). Conclusion: Considering the evaluated parameters, the CdTe detector is recommended for use in clinical practice.

Analysis and Improvement Specific Frequency Reception Noise Phenomena Due to RF Radiation Signal (RF 방사 신호로 인한 특정 주파수 수신 잡음 현상의 원인분석 및 개선)

  • Kwon, Jung-Hyuk;Kim, Jong-Min;Lee, Wang-Sang
    • Journal of Aerospace System Engineering
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    • v.16 no.3
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    • pp.73-83
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    • 2022
  • The purpose of this paper was to identify a method to improve received noise in a specific frequency band, caused by RF radiation signals during aircraft operation. The communication equipment of the aircraft is critical to the performance and safety of the flight mission, as it is responsible for the function of internal and external communications. Noise-free, clean communication quality, as well as transmission and receiving functions have to be implemented. Thus, the cause analysis of the reception noise in a specific frequency band, was analyzed through trouble shooting. The receiving noise due to the RF radiation signal emitted from the subsystem unit inside the aircraft, was improved by shielding with a CAP with electroless nickel plating applied. Additionally, the measurement and verification results of the improvement method are also described.

Air Pollution Tolerance and Heavy Metal Accumulation of Selected Tree Species at Swamp Forest Research Station, Onne, Rivers State

  • Rosemary Egodi Ubaekwe;Victoria Amarachi Okpara;Uzoma Darlington Chima
    • Journal of Forest and Environmental Science
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    • v.40 no.3
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    • pp.227-240
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    • 2024
  • Trees improve air quality through the accumulation of air pollutants in their leaves; however, the responses of different tree species to air pollution varies. Hence, this study evaluated the responses to air pollution of selected tree species in the Swamp Forest Research Station, Onne. Ten tree species (Cola pachycarpa, Khaya grandifoliolia, Irvingia gabonensis, Garcinia kola, Chrysophyllum albidum, Treculia africana, Dacryodes edulis, Tectonia grandis, Gmelina aborea, and Nauclea diderrichii) were selected based on their abundance in the area. Leaves were collected from all sides in 3 replicates for each tree species. Laboratory analysis was carried out using standard procedures. Portable Multi Gas Detector was used to determine the concentrations of air pollutants. One-way analysis of variance was employed to test for significant difference (p≤0.05) in biochemical parameters among the tree species while Pearson's correlation was utilized to determine the level of association between different biochemical parameters and APTI; heavy metals and APTI. Results showed high concentration of PM10, CO, moderate concentration of NO2, PM2.5, and VOC, and low concentration of ground O3. Heavy metals - Cadmium, Mercury, Lead, Nickel and Copper were all present in the tree species at varying rates. There were significant differences in the biochemical parameters and APTI values. C. pachycarpa exhibited the highest APTI value (89.88), while D. edulis had the lowest APTI value (8.24). C. pachycarpa, K. grandifoliolia, C. albidum, G. kola, T. africana, and N. diderrichii were identified as tolerant tree species to air pollution. G. aborea, T. grandis, and I. gabonensis were considered intermediate tolerant species, while D. edulis was the only tree species sensitive to air pollution. Ascorbic Acid, Chlorophyll, Hg and Ni had positive correlations with APTI; Cd and Cu had negative association with APTI at the 0.05 significance level. C. pachycarpa, T. africana, K. grandifoliolia, C. albidum, N. diderrichii and G. kola, are recommended for planting in pollution-prone areas.

Evaluation of the Relationship between the Exposure Level to Mixed Hazardous Heavy Metals and Health Effects Using Factor Analysis (요인분석을 이용한 유해 중금속 복합 노출수준과 건강영향과의 관련성 평가)

  • Kim, Eunseop;Moon, Sun-In;Yim, Dong-Hyuk;Choi, Byung-Sun;Park, Jung-Duck;Eom, Sang-Yong;Kim, Yong-Dae;Kim, Heon
    • Journal of Environmental Health Sciences
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    • v.48 no.4
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    • pp.236-243
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    • 2022
  • Background: In the case of multiple exposures to different types of heavy metals, such as the conditions faced by residents living near a smelter, it would be preferable to group hazardous substances with similar characteristics rather than individually related substances and evaluate the effects of each group on the human body. Objectives: The purpose of this study is to evaluate the utility of factor analysis in the assessment of health effects caused by exposure to two or more hazardous substances with similar characteristics, such as in the case of residents living near a smelter. Methods: Heavy metal concentration data for 572 people living in the vicinity of the Janghang smelter area were grouped based on several subfactors according to their characteristics using factor analysis. Using these factor scores as an independent variable, multiple regression analysis was performed on health effect markers. Results: Through factor analysis, three subfactors were extracted. Factor 1 contained copper and zinc in serum and revealed a common characteristic of the enzyme co-factor in the human body. Factor 2 involved urinary cadmium and arsenic, which are harmful metals related to kidney damage. Factor 3 encompassed blood mercury and lead, which are classified as related to cardiovascular disease. As a result of multiple linear regression analysis, it was found that using the factor index derived through factor analysis as an independent variable is more advantageous in assessing the relevance to health effects than when analyzing the two heavy metals by including them in a single regression model. Conclusions: The results of this study suggest that regression analysis linked with factor analysis is a good alternative in that it can simultaneously identify the effects of heavy metals with similar properties while overcoming multicollinearity that may occur in environmental epidemiologic studies on exposure to various types of heavy metals.

The analysis of endocrine distruptors in commercial cosmetics (유통 화장품 중 내분비계 장애물질 탐색 및 규명에 관한 연구)

  • Koo, Heesoo;Na, Youngran;Lee, Seungju;Min, Sangkee;Kang, Jungmi;Jin, Sung Hyun
    • Analytical Science and Technology
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    • v.28 no.3
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    • pp.212-220
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    • 2015
  • This study aims to identify the characteristics of phthalates (DMP, DEP, DBP, DEHA, BBP, DEHP, and DNOP) and heavy metals such as lead (Pb), cadmium (Cd), and mercury (Hg) in cosmetics and their containers. Phthalates and heavy metals may be endocrine distruptors. Sixty-five cosmetics were purchased from online and offline stores in Busan. This study developed a simultaneous method for the analysis of phthalates by GC-FID. The results showed that among the 65 cosmetics, DBP, DEHP, and DEP were detected at 20.0%, 7.7%, 1.5%, respectively. The amounts of DBP and DEHP detected in 18 samples were less than 100 μg/g, which satisfies the Regulations of Cosmetic Safety Standards in Korea. In order to detect phthalates in cosmetic containers, a dissolution test was conducted by extracting solutions, such as water, n-heptane, 20% ethanol, 50% ethanol and 4% acetic acid, which were prepared with different levels of pH, alcohol content, and fat content following the Korea Standards and Specifications for Utensils, Containers, and Packaging. The results showed that DMP, DBP, DEHA, BBP, DEHP, and DNOP were not detected, DEP was detected in plastics such as PE, PP, and others, when a 50% alcohol solvent was used. Phthalates may not be detected in cosmetic containers if they are not packaged with the above 20% alcohol constituent. We also analyzed the concentration of heavy metals, such as Pb, Cd, and Hg, by using ICP-OES and a mercury analyzer. The ranges of concentration were ND~2.71 μg/g for Pb, ND~0.31 μg/g for Cd, and ND~0.01 μg/g for Hg, which are below the regulated level.

A Study on UV Filters, Preservatives and Heavy Metals Contained in the Children's and Inorganic Sunscreens Distributed in Korea (국내 유통 어린이 및 무기 자외선차단제에서 자외선 차단성분, 보존제 및 중금속 실태 조사)

  • Kim, Aeran;Lee, You-Jin;Cho, Yun-Sik;Kim, Hyun-Jue;Cho, Sang-Hun;Kim, Yang-Hee;Ro, Jeong-won;Park, Yong-Bae
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.47 no.4
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    • pp.289-296
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    • 2021
  • In this study, 27 inorganic sunscreens and 23 sunscreens for children were collected to investigate the use and incorporation of 17 types of sunscreen agents, 13 types of preservatives, and 5 types of heavy metals. As a result, sunscreen agents were detected in the order of titanium dioxide (41 cases), zinc oxide (29 cases), bis-ethylhexyloxyphenyltriazine (10 cases), ethylhexyl salicylate (8 cases), and ethylhexylmethoxynamate (8 cases), and preservatives were detected in order of phenoxyethanol (6 cases), benzoic acid (1 case), and dihydroacetic acid(1 case). All of the identified sunscreen agents were suitable for labeling, but phenoxyethanol, a preservative component other than labeling, was detected at a concentration of 0.1%. Heavy metals such as lead, cadmium, arsenic, antimony, and nickel were not detected or were detected at various concentrations of less than 3.6 ㎍/g. All the detected UV filters, preservatives, and heavy metals were less than the allowed maximum amount stipulated by the Regulations on Cosmetic Safety Standards in Korea.

Risk Assessment of Airborne Toxic Metals in Thejon Industrial Complex (대전공단지역의 대기중 독성금속에 대한 위해도 평가)

  • Lee, Jin Hong;Yun, Mi Jung;Nam, Byung Hyun;Wang, Chang Keun;Kang, Ho
    • Journal of Environmental Impact Assessment
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    • v.8 no.2
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    • pp.1-8
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    • 1999
  • The research centers on the concentration profile and risk assessment of toxic metals for ambient air in Taejon industrial complex. Airborne concentrations of each toxic metal for risk assessment were obtained from 2-year sampling by high volume air sampler and analysis by ICP-MS and ICP-AES in the complex. The long-term arithmetic mean of human carcinogen, arsenic, hexavalent chromium and nickel subsulfide was 5.53, 2.16 and $3.46ng/m^3$ while the mean of probable human carcinogen, beryllium, cadmium and lead was 0.08, 2.35, $293.29ng/m^3$, respectively. And the long-term arithmetic mean concentration of non-carcinogenic metal, manganese was $55.91ng/m^3$. The point risk estimate for the inhalation of carcinogenic metals was $3.6{\times}10^{-5}$, which was higher than a risk standard of $10^{-5}$. About 75% of the cancer risk was to the inhalation of human carcinogen, arsenic. Thus, it is necessary to properly manage arsenic risk in Taejon industrial complex. The point hazard index by the inhalation of manganese was 1.1. Therefore, an investigation into Taejon industrial complex is needed to obtain more fine long-term concentration data for airborne non-carcinogenic metals including manganese.

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