• 제목/요약/키워드: bulk structure

검색결과 854건 처리시간 0.034초

알칼리 처리가 제지용 화학펄프의 특성에 미치는 영향 (Effects of Alkaline Treatment on the Characteristics of Chemical Pulps for Papermaking)

  • 원종명;김민현
    • 펄프종이기술
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    • 제43권3호
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    • pp.106-112
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    • 2011
  • The effects of alkaline treatment on the WRV, crystalline structure and sheet structure of softwood and hardwood bleached kraft pulp were investigated. Sodium hydroxide and sodium carbonate were used as chemicals for alkaline treatment and two levels of alkali dosage (5%, 10%) were applied respectively. Alkali treated and untreated pulp were refined to three levels (550, 450 and 350 mL CSF). WRV of the alkali treated pulps depended on the alkaline type and concentration. It was found that the crystalline structures of softwood and hardwood pulp were not changed by refining. Sodium carbonate and lower concentration of sodium hydroxide treatment did not caused any modification of cellulose crystalline structure, while higher concentration of sodium hydroxide treatment caused the partial modification of cellulose crystalline structure. Alkaline treatment of hardwood bleached kraft pulp led to the shrinkage of fiber diameter and bulky structure of sheet. Alkaline treatment of softwood bleached kraft pulp did not cause the significant change in fiber shrinkage and bulk of sheet.

소듐붕규산염 유리의 표면 구조에 대한 분자 동역학 시뮬레이션 연구 (Na Borosilicate Glass Surface Structures: A Classical Molecular Dynamics Simulations Study)

  • 권기덕
    • 한국광물학회지
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    • 제26권2호
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    • pp.119-127
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    • 2013
  • 핵폐기물을 고화시키는 재료로 사용하는 붕규산염(borosilicate) 유리의 용해는 지층 처분장에 처리된 고준위 방사성 폐기물의 생태계 유출을 결정할 수 있는 중요한 화학반응이다. 습식 실험에서 유리의 용해속도(dissolution rate)는 유리 화학조성에 의해 크게 좌우되는 것이 관찰된다. 유리의 bulk 구조를 규명한 분광분석 실험에 의하면 유리의 화학조성과 분자수준(molecular-level) 구조(예: $SiO_4$ 사면체의 연결구조와 B 원소의 배위구조) 사이의 상관관계가 존재한다. 따라서 화학조성에 따른 유리 용해도의 차이는 조성에 따른 bulk 내부구조의 변화로 이해되어 왔다. 그런데 유리 표면은 수용액과 계면을 이루면서 용해 과정에서 가장 직접적으로 반응하는 부분이기 때문에, 화학조성에 따른 표면구조 변화에 대한 지식 또한 필요하다. 본 논문에서는 분자 동역학(molecular dynamics, MD) 시뮬레이션을 사용하여 4가지의 다른 화학조성을 가지는 소듐붕규산염 유리($xNa_2O{\cdot}B_2O_3{\cdot}ySiO_2$ 화학조성)에 대하여 bulk 구조와 실험으로 얻기 어려운 표면(surface) 구조를 연구하였다. MD 시뮬레이션은 유리 표면의 화학조성과 분자수준 구조가 bulk의 것과 매우 상이한 결과를 보여준다. 본 연구의 MD 시뮬레이션 결과는 화학조성에 따른 유리 용해도(특히 초기 용해과정)는 bulk 구조의 변화보다 유리 표면구조의 변화에 의해 크게 좌우될 수 있다는 표면구조에 대한 이해의 중요성을 역설한다.

벌크 비정질 Zr-Ti-Cu-Ni-Be 합금의 고온 소성 변형 특성 (High Temperature Plastic Deformation Behaviors of the Bulk Metallic Glass Zr-Ti-Cu-Ni-Be Alloy)

  • 이광석;하태권;안상호;장영원
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2001년도 추계학술대회 논문집
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    • pp.272-276
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    • 2001
  • Multicomponent $Zr_{41.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ bulk matallic glass alloy shows good bulk glass forming ability due to its high resistance to crystallization in the undercooled liquid state.1) In this study, DSC and X-ray diffractometry have been performed to confirm the amorphous structure of the master $Zr_{41.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ alloy. To investigate the mechanical properties and deformation behaviors of the bulk metallic $Zr_{41.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ alloy, a series of compression tests has been carried out at the temperatures ranging from $351^{\circ}C$ to $461^{\circ}C$ and at the various initial strain rates from $2{\times}10^{-4}s^{-1}\;to\;2{\times}10^{-2}s^{-1}$. There are two types of nominal stress-strain curves. The one shows linear stress-strain relationship meaning fracture at maximum stress, the other shows plastic deformation including steady-state flow. Also DSC analysis for the compressed specimens has been performed to investigate the change of thermal stability and crystallization behavior for the various test conditions.

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181,000 DWT BULK CARRIER 전선 진동해석을 통한 전선진동특성 고찰 (The study of 181,000 DWT BULK CARRIER global vibration characteristic by global vibration analysis)

  • 임구섭;정태석;최영달;석호일
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2008년도 추계학술대회논문집
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    • pp.329-330
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    • 2008
  • The 181,000 DWT Bulk Carrier has a different deck house type, which is not typical for previous bulk carriers, to meet the new international rules for bulk carriers. This new deck house has much smaller transverse breadth than the hull's transverse breath, resulting in large levels of the transverse response of the deck house. In addition, the longitudinal response of the funnel showed rather a large magnitude of vibration, which are excited by the ship's main excitations such as the main engine H-moment and the propeller surface forte when the ship operates at the NCR and the MCR speeds In the ballast condition. To solve these issues, the global forced vibration analysis has been performed for the ship and the ship structure has been modified to reduce the vibration level by increasing the girder depth and adjusting the engine room tank arrangement.

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선수 플레어 충격압력 추정과 구조설계에의 응용 - 탱커와 산적화물선 - (Prediction of Bow Flare Impact Pressure and Its Application to Ship Structure Design - Tanker and Bulk Carrier -)

  • 김용직;신기석;신찬호;강점문;김만수;김성찬;오수관;임채환;김대헌
    • 대한조선학회논문집
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    • 제40권3호
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    • pp.22-28
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    • 2003
  • In rough seas, bow-flare regions of the full ships (tanker and bulk carrier) are subiect to high impact pressures due to the on-coming breaking waves. And many ships suffer structural damages in that region, even though they were built under the bow structure strengthening rules of the ship classes. So, a new design method for bow-flare structure is highly required. In this paper, a new prediction method of the bow-flare impact pressure (in terms of equivalent static pressure) acting on the full ships' bow is presented. This method is based on the 6 full ships' damage analysis and the breaking wave impact mechanism. Calculation results of the bow-flare impact pressure and the shell plate thickness are shown and discussed. Through the example calculations, it was found that the present method is useful for the structure design of the full ships' bow.

불순물 첨가에 따른 $Al_2O_3$세라믹스의 구조적 특성 (Structural Properties of $Al_2O_3$Ceramics with impurities)

  • 우원석;김지헌;임성수;박인길;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.387-390
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    • 2000
  • The $Al_2$O$_3$specimens were prepared by the conventional mixed oxide method with addition La$_2$O$_3$, Bi$_2$O$_3$. The specimens were sintered at 15$25^{\circ}C$, 5hr., in air. The structural properties of the specimens were investigated by XRD and SEM. The $Al_2$O$_3$ceramics with dopants had hexagonal structure and didn't show secondary phases. In the case of specimens with 0.25wt% La$_2$O$_3$and 0.25wt% Bi$_2$O$_3$bulk densities and lattice parameter of c/a were 3.818g/cm$^3$, 3.783g/cm$^3$and ca=2.725, c/a=2.723, respectively. The bulk densities of $Al_2$O$_3$ceramics were decreased with dopants.

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Characterization of uranium species in molten salt : An application of synchrotron-based XAFS spectroscopy

  • Cho, Young-Hwan;Choi, In-Kyu;Kim, Won-Ho
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 2002년도 추계학술발표회요약집
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    • pp.319.2-319
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    • 2002
  • Synchrotron-based X-ray absorption spectroscopy has been applied to determine the changes in bulk oxidation state of uranium oxides in molten salt. From an analysis of XANES data, one can determine the cahnges in bulk oxidation-state of U compounds in salts(LiCl/KCl). XAFS spectroscpy is a powerful tool for probing the changes in valence state and structure of uranium compounds in colten salt as well as in noncrystalline form and doped in other matrices.

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기능성 재료의 간소화된 합성법 (Simplified fabrication method of Functional materials)

  • 이상헌
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2008년도 제39회 하계학술대회
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    • pp.1240-1241
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    • 2008
  • Superconducting ceramics of YBaCuO was fabricated on SrTiO substrate by chemical fabrication method using fine powder of YBaCuO having diameter less than 1um. The pattern of the fabricated superconducting bulk was linear and the thickness of it can be controlled in the range of 50um. The structure of the surface of film by diffraction pattern and composition. The tape like YBaCuO bulk with width of 10mm was formed on substrate using similar method. Tape like film is expected to utilize as material of superconducting tape.

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화합물 반도체 재료의 결정성장과 특성평가 (Crystal Growth and Characterization of Compound Semiconductor Materials)

  • 민석기
    • 한국결정학회지
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    • 제1권2호
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    • pp.115-125
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    • 1990
  • We have investigated bulk and hetero-epitaxial growth of GaAs single crystal. Various growth techniques such as HB, HZM, and VGF for high quality bulk GaAs were successfully developed by appling the specially designed DM(direct monitoring) furnace. Al GaAs/GaAs superlattice structure and In(x)Ga(1-x) As/GaAs epilayers were also grown by MOCVD and VPE, respectively. The characterization of GaAs single crystals and epilayers was made by X-ray diffraction, Hall effect, PL, chemical etching and angle lapping technique.

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Greenhouse Bulk건조기에 의한 태양열이용에 관한 연구 (제I보) (Solar Energy Utilization in a Greenhouse Bulk Curing and Drying System(I))

  • 진정의;이승철;이상하
    • 한국연초학회지
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    • 제2권1호
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    • pp.61-67
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    • 1980
  • 韓國煙草硏究所, 大邱試驗場(北緯35$^{\circ}$49')에서 1979年 透明한 fiber glass로 지은 円柱型 greenhouse(4.50$\times$3.83$\times$2.80m)內에 乾燥室의 外壁 및 天井을 Polyurethan에 함석을 입혀 黑色 paint로 coating한 板을 heat absorber겸 斷熱板으로, 乾燥室 양편에 各各 4.5㎥의 자갈을 넣은 gravel heat storage system 그리고 greenhouse內의 加熱된 空氣를 練燒室로 誘導할 수 있는 air duct를 설치한 8.25㎥의 太陽熱 直接利用 方式의 Bulk 乾燥材와 同一한 크기의 Bulk 乾燥材를 比較 試驗하였다. 乾燥期間中 外溫 30.5~35.5$^{\circ}C$, 總日射量 1004.2~1436.2 cal/$\textrm{cm}^2$의 條件下에서 3回 乾燥 試驗한 結果, 天井 heat absorber의 最高溫度는 89$^{\circ}C$이였으며, 練燒室로 吸入되는 空氣의 最高溫度는 64$^{\circ}C$이며 평균 46$^{\circ}C$로서 外溫에 비하여 18$^{\circ}C$가 높았고, 慣行Bulk乾燥材에 비하여 25%의 燃料가 節減되였다.

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