• Title/Summary/Keyword: bulk morphology

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Nanocrystallization of Cu-Based Bulk Glassy Alloys upon Annealing

  • Pengjun, Cao;Dong, Jiling;Haidong, Wu;Peigeng, Fan;Anruo, Zhou
    • Applied Microscopy
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    • v.46 no.1
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    • pp.32-36
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    • 2016
  • The Cu-based bulk glassy alloys in Cu-Zr-Ti-Ni systems were prepared by means of copper mold casting. The Cu-based bulk glassy alloys samples were tested by X-ray diffractomer (XRD), differential scanning calorimeter, scanning electron microscopy (SEM), Instron testing machine and Vickers hardness instruments. The result indicated that the prepared Cu-Zr-Ti-Ni alloys were bulk glassy alloys. The temperature interval of supercooled liquid region (${\Delta}T_x$) was about 45.48 to 70.98 K for the Cu-Zr-Ti-Ni alloy. The Vickers hardness was up to 565 HV for the $Cu_{50}Zr_{25}Ti_{15}Ni_{10}$ bulk glassy alloy. The $Cu_{50}Zr_{25}Ti_{15}Ni_{10}$ bulk glassy alloys were annealed in order to obtain nanocrystals. The results showed that the Vickers hardness was raise up to 630 HV from 565 HV. As shown in XRD results, the amorphous alloys changed to nanocrystals, which were $Cu_8Zr_3$, $Cu_3Ti_2$ and CuZr, improved the hardness. The SEM analysis showed that the compression fractured morphology of amorphous alloys was brittle fracture, and the fracture morphology after annealing was ductile fracture. This proved that annealing of amorphous to nanocrystals can improve the plasticity and toughness of amorphous alloys.

Numerical Simulation of Phase Separation in Bulk Hetero-junction Photoactive Layer

  • Hang, Nguyen Thi;Van Thuong, Dinh;Nhat, Hoang Nam;Van Chau, Dinh
    • International Journal of Advanced Culture Technology
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    • v.4 no.1
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    • pp.31-36
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    • 2016
  • Morphology evolution of the active layer in bulk hetero-junction organic photovoltaic is modeled and visualized. The width of the phase domain can be predicted using the relationship of characteristics length and evolution time of the process. The 3D numerical simulation of the PCBM/P3HT blend morphology evolution with respect to time is presented. It is observed that the domain width of composition phase can be predicted by using the relationship between value of characteristic length R(t) and evolution time t.

Effects of Morphology on Nanostructured Superconducting Thin Film (나노구조 박막의 Morphology에 따른 초전도 특성 변화에 관한 연구)

  • Kouh, Tae-Joon
    • Journal of the Korean Magnetics Society
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    • v.16 no.1
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    • pp.71-74
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    • 2006
  • Transport and tunneling measurements of nanostructured superconducting thin films are presented. To understand the effects of film morphology on their superconducting properties, thermal annealing experiments have been performed. The transition temperature increases with thermal annealing temperature towards the bulk value. Also, thermal annealing results in a shift of transverse phonon mode. These can be understood with changes in film morphology and suggest its importance on the superconducting state properties.

Bulk Heterojunction Organic Photovoltaics- Nano Morphology Control and Interfacial Layers

  • Kim, Gyeong-Gon
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.59.2-59.2
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    • 2012
  • Polymer solar cells utilize bulk heterojunction (BHJ) type photo-active layer in which the electron donating polymer and electron accepting $C_{60}$ derivatives are blended. We found there is significant charge recombination at the interface between the BHJ active layer and electrode. The charge recombination at the interface was effectively reduced by inserting wide band gap inorganic interfacial layer, which resulted in efficiency and stability enhancement of BHJ polymer solar cell.

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Evaluation of Cutting Characteristics in Bulk Metallic Glasses (벌크비정질합금(BMG)의 절삭특성 평가)

  • Shin, Hyung-Seop;Choi, Ho-Yeon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.6
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    • pp.591-598
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    • 2012
  • In this study, the cutting characteristics of bulk metallic glass (BMG) cut using a computer numerically controlled (CNC) lathe were investigated for different insert tool materials and cutting speeds. The surface roughness, chip morphology, cutting forces, and tool wear during turning of $Zr_{50}Cu_{40}Al_{10}$ BMG alloy were examined. Four kinds of tool materials were used to cut an 8-mm-diameter BMG. The examination of the surface roughnesses of the BMG specimens machined at each cutting speed showed that the surface roughness became better as the cutting speed increased, and the tool materials also influenced the surface roughness. The chip morphology investigations showed that the unoxidized BMG chips had serrated curled chips with adiabatic shear bands, while the oxidized chips exhibited local melting and tangling rather than the usual spiral-shaped chips. The cutting force induced during machining of the Zr-based BMG was the largest for the TiN-WC tool, followed by the polycrystalline diamond (PCD) tool. The cermet tool exerted the smallest cutting force.

Pressure Effects on the Morphology Development of C/C Composites During Carbonization

  • Joo, Hyeok-Jong;Ryu, Seung-Hee;Ha, Hun-Seung
    • Carbon letters
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    • v.1 no.3_4
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    • pp.158-164
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    • 2001
  • It is well known that the fabrication process of carbon/carbon composites is very complex. Above all, the carbonization process have major effect on the morphology development of carbon matrix. Carbon/carbon composites of 4-directional fiber preform were fabricated using the coal tar based pitch as a matrix precursor in this study. According to carbonization pressure of 1 bar, 100 bar, 600 bar, and 900 bar, morphological changes of cokes and matrix of composites were discussed. As the carbonization pressure increased to 600 bar, the flow pattern morphology of bulk mesophse was well developed. On the contrary, mosaic pattern morphology was found in case of 900 bar of carbonization pressure. It is confirmed that the carbonization pressure have profound effect on the degree of graphitization and crystal size of carbon matrix. Even in the highly densified carbon/carbon composites, large voids were still found in the matrix pocket region.

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Nature of Surface and Bulk Defects Induced by Epitaxial Growth in Epitaxial Layer Transfer Wafers

  • Kim, Suk-Goo;Park, Jea-Gun;Paik, Un-Gyu
    • Transactions on Electrical and Electronic Materials
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    • v.5 no.4
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    • pp.143-147
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    • 2004
  • Surface defects and bulk defects on SOI wafers are studied. Two new metrologies have been proposed to characterize surface and bulk defects in epitaxial layer transfer (ELTRAN) wafers. They included the following: i) laser scattering particle counter and coordinated atomic force microscopy (AFM) and Cu-decoration for defect isolation and ii) cross-sectional transmission electron microscope (TEM) foil preparation using focused ion beam (FIB) and TEM investigation for defect morphology observation. The size of defect is 7.29 urn by AFM analysis, the density of defect is 0.36 /cm$^2$ at as-direct surface oxide defect (DSOD), 2.52 /cm$^2$ at ox-DSOD. A hole was formed locally without either the silicon or the buried oxide layer (Square Defect) in surface defect. Most of surface defects in ELTRAN wafers originate from particle on the porous silicon.

Tuning the surface charge of mixed matrix membranes using novel chemistry

  • Priyanka Mistry;C.N. Murthy
    • Membrane and Water Treatment
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    • v.15 no.3
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    • pp.139-152
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    • 2024
  • Mixed matrix membranes have gained significant recognition in the wastewater treatment industry for their effectiveness in removing dyes, proteins, and heavy metals from water sources. Researchers have developed an innovative technique to enhance properties of these membranes by incorporating amine-functionalized carbon nanotubes into the polymer matrix. This approach introduces amine functional groups onto the membrane surface, which are then modified with trimesoyl chloride and cyanuric chloride. The modified membranes are characterized by XPS to confirm successful bonding of amines with the trimesoyl chloride and cyanuric chloride. The surface charge of the modified membrane also plays a role in the modification process; the membrane modified with trimesoyl chloride has a negative surface charge, while the one modified with cyanuric chloride has a more positive charge. At the same acidic pH, the positive or negative charge of the mixed matrix membranes assists in enhancing the rejection of heavy metals. This results in improved antifouling properties for both modified membranes. The heavy metal rejection for all modified membranes is higher than for unmodified membranes, due to both adsorption and complexation abilities of the functional groups on the membrane surface with heavy metal ions. As the membrane surface functionalities increase through modification, the separation due to complexation also increases. The bulk morphology of the membrane remains unchanged, while roughness slightly increases due to the surface treatment.

A Preliminary Study on the Application of Three-Dimensional (3D) Printing Technologies to Hot Bulk Forming Processes - Example of Preform Design and Investigation of Hot-working Tool Steel Deposited Surface (3 차원 프린팅 기술의 열간 체적 성형 공정 적용에 관한 기초 연구 - 예비형상 설계 예 및 열간 금형강으로 적층된 표면 특성 분석)

  • Ahn, Dong-Gyu;Kim, Se-Hun;Lee, Ho-Jin
    • Journal of the Korean Society for Precision Engineering
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    • v.31 no.12
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    • pp.1093-1100
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    • 2014
  • The goal of this paper is to investigate preliminary the applicability of 3D printing technologies for the development of the hot bulk forming process and die. 3D printing technology based on the plastic material was applied to the preform design of the hot forging process. Plastic hot forging dies were fabricated by Polyjet process for the physical simulation of the workpiece deformation. The feasibility of application of Laser-aided Direct Metal Rapid Tooling (DMT) process to the fabrication of the hot bulk metal forming die was investigated. The SKD61 hot-working tool steel was deposited on the heat treated SKD61 using the DMT process. Fundamental characteristics of SKD 61 hot-working tool steel deposited specimen were examined via hardness and wear experiments as well as the observation of the morphology. Using the results of the examination of fundamental characteristics, the applicability of the DMT process to manufacture hot bulk forming die was discussed.