• 제목/요약/키워드: buffer gas

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Development of New GAIM Process for Faster Cooling and Material Reduction (빠른 냉각과 재료절감을 위한 새로운 가스성형 프로세스 개발)

  • 한성렬;박태원;곽진관;김철주;하만영;정영득
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.852-855
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    • 2003
  • Gas-Assisted Injection Molding(GAIM) process, that can be used to provide a hollow shape in a molding, is a variant of the conventional injection molding process. GAIM has many advantages such as reduction of material, sink mark. warpage. and lower injection pressure. Thus, GAIM has been widely applied in the industry to make moldings with a hollow channel such as handles, TV frames and so on. On the other hand, GAIM has some disadvantages such as slow cooling time and flow marks. In the disadvantages, hot gas core causes slow cooling of a molding and the overflow. which is to prevent flow mark. is waste of materials. To solve these problems, we developed a new GAIM system that we called RGIM(Reverse Gas Injection Molding). The RGIM has two special units; one is the overflow buffer, which is used for reduction of a material, and the other tile air unit, which is used for faster cooling of a molding. We conducted an experiment and simulation to verify the efficiency of the RGIM system. Through experiments and simulation, we confirmed the effectively operating of the RGIM system and extracted the optimum process conditions.

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Study on elemental analysis of metal and ceramic samples by using laser ablation ion trap mass spectrometry(LAITMS) (레이저 이온화 이온트랩 질량분석법을 이용한 금속 및 세라믹 시료의 원소분석에 관한 연구)

  • Song, Kyuseok;Park, Hyunkook;Cha, Hyungki;Lee, Sang Chun
    • Analytical Science and Technology
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    • v.15 no.1
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    • pp.7-14
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    • 2002
  • Laser ablation ion trap mass spectrometry (LAITMS) was developed for the analysis of metal and ceramic samples. For this study, XeCl excimer laser (308 nm) was used for ablating the samples and ITMS was used as a detector. Samples were introduced from outside of a ring electrode and this way of sample introduction was very effective for solid samples when laser ablation was employed. Helium gas was used as a buffer gas, and its effect on sensitivity and some parameters (buffer gas pressure, ion storage time, and cut-off RF voltage) were studied. The optimized conditions were $1{\times}10^{-4}$ Torr of buffer gas pressure, 100 ms of ion storage time and $1150V_{p-p}$ of cut-off RF voltage. From that results, copper (Cu) and molybdenum (Mo) metals were tested with LAITMS and the mass spectra of these pure metals were compared with the natural abundance of isotope ratio. We also examined ceramic samples ($Al_2O_3$, $ZrO_2$) and represented the result of elemental analysis.

Dispersion Modeling Methodology for Hazardous/Toxic Gas Releases from Chemical Plant Facilities (화학장치설비의 유해독성가스 누출에 대한 분산모델링 방법론)

  • Song Duk-Man
    • Journal of the Korean Institute of Gas
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    • v.1 no.1
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    • pp.73-80
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    • 1997
  • This study was performed to develop the dispersion modeling methodology for quantitative prediction of the hazard distance or toxic buffer distance by comparing 10-min average, 30-min average, and 1-hr average maximum ground-level concentration with $Cl_2$ regultaion concentration, IDLH and ERPG-3 concentration for hazardous toxic gas, $Cl_2$ releases from the storage tank of the chemical plant facilities. For this dispersion modeling, the source term model, dispersion model, meteorological and topographical data are incorporated into the SuperChems model, and then the effects of the atmospheric stability, wind speed, and surface roughness length changes on the maxum ground-level concentration were estimated.

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Discharge Characteristics of SF6 Mixture Gases due to Processing Status of needle electrode under Non-Uniform Fields (불평등 전계 하에서의 침전극 가공상태에 따른 SF6혼합가스의 방전특성)

  • Go, Y.S.;Seo, H.J.;Rhie, D.H.
    • Proceedings of the KIEE Conference
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    • 2006.10a
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    • pp.198-199
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    • 2006
  • AC spark discharge voltage of SF6/C02and SF6/N2 containing various mixed rate in volume percent (1, 5 and 10%) of SF6 in non-uniform fields are investigated. The needle to plane electrode gap spacing was 5 and 10 mm, and the gas pressure was varied within the range of 0.1${\sim}$0.7 MPa. We have observed a N-characteristic typical for the electronegative gases even in gas mixtures of 1% SF6 with CO2 and N2 as buffer gases. Especially, the materials of the needle electrode affect the insulation properties of the gas mixtures drastically. On the contrary to the case of needle electrodes made by mild steel or high carbon steel, the N-characteristics are hardly perceived in the case of stainless steel needle in this experiment.

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Epitaxial Growth of $CeO_2\;and\;Y_2O_3$ Buffer-Layer Films on Textured Ni metal substrate using RF Magnetron Sputtering (이축정렬된 Ni 금속모재에 RF 마그네트론 스퍼터링에 의해 증착된 $CeO_2$$Y_2O_3$ 완충층 박막 특성)

  • Oh, Y.J.;Ra, J.S.;Lee, E.G.;Kim, C.J.
    • Progress in Superconductivity
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    • v.7 no.2
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    • pp.120-129
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    • 2006
  • We comparatively studied the epitaxial growth conditions of $CeO_2$ and $Y_2O_3$ thin buffers on textured Ni tapes using rf magnetron sputtering and investigated the feasibility of getting a single mixture layer or sequential layers of $CeO_2$ and $Y_2O_3$ for more simplified buffer architecture. All the buffer layers were first deposited using the reducing gas of $Ar/4%H_2$ and subsequently the reactive gas mixture of Ar and $O_2$, The crystalline quality and biaxial alignment of the films were investigated using X-ray diffraction techniques (${\Theta}-2{\Theta},\;{\phi}\;and\;{\omega}\;scans$, pole figures). The $CeO_2$ single layer exhibited well developed (200) epitaxial growth at the condition of $10%\;O_2$ below an $450^{\circ}C$, but the epitaxial property was decreased with increasing the layer thickness. $Y_2O_3$ seldom showed optimum condition for (400) epitaxial growth. The sequential architecture of $CeO_2/Y_2O_3/CeO_2$ having good epitaxial property was achieved by sputtering at a temperature of $700^{\circ}C$ on the initial $CeO_2$ bottom layer sputtered at $400^{\circ}C$. Cracking of the sputtered buffer layers was seldom observed except the double layer structure of $CeO_2/Y_2O_3$.

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The effects of $O_2$ partial pressure on the property of buffer layer in YSZ/CeO$_2$/Ni (YSZ/CeO$_2$/Ni 에서 산소 분압의 완층충 특성에 대한 영향)

  • Lee, Kyu-Han;Youm, Do-Jun
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.326-328
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    • 1999
  • We investigated the effects of residual gas partial pressure on the property of a CeO$_2$ buffer layer on a textured Ni tape, where the buffer layer was deposited by e-beam evaporation. The oxygen partial pressure were varied from 10$^{-7}$ to 10$^{-4}$ Torr. we also changed the surface condition for the surface oxygenation. We'll describe the detail of the resultant textures of the buffer layers and effects of YBCO growth on them

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Effect of Protein Fractionation and Buffer Solubility of Forage Sources on In Vitro Fermentation Characteristics, Degradability and Gas Production (조사료 자원의 단백질 분획 및 Buffer 추출이 In Vitro 발효 성상, 분해율 및 Gas 생성량에 미치는 효과)

  • Jin, Guang Lin;Shinekhuu, Judder;Qin, Wei-Ze;Kim, Jong-Kyu;Ju, Jong-Kwan;Suh, Seong-Won;Song, Man-Kang
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.32 no.1
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    • pp.59-74
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    • 2012
  • Buffer solubility and protein fractionation were evaluated from the hays (timothy, alfalfa and klein) and straws (tall fescue and rice), and $In$ $vitro$ trial was conducted to examine the effect of buffer extraction on fermentation characteristics, degradability and gas ($CO_2$ and $CH_4$) production. Buffer soluble protein (SP) content and A fraction in total protein were highest in alfalfa hay as 61% and 41.77%, respectively while lowest in rice straw (42.8% and 19.78%, respectively). No difference was observed in B1 fraction among forages but B2 fraction was slightly increased in klein hay (12.34%) and tall fescue straw (10.05%) compared with other forages (6.34~8.85%). B3 fraction of tall fescue was highest as 38.49% without difference among other forages while C fraction was highest in rice straw. pH in incubation solution was higher in all forages after extraction than before extraction at 3h (P<0.01) and 6h (P<0.05), and pH from hays of timothy and alfalfa was higher than the other forages at 6h (P<0.05) and 12h (P<0.001). Regardless of extraction, ammonia-N concentration from alfalfa hay was increased at all incubation times and extraction effect was appeared only at 3h incubation time (P<0.01). Total VFA concentration from alfalfa hay was highest up to 24h incubation while those from tall fescue straw and rice straw were lowest. Buffer extraction decreased (P<0.01~P<0.001) the total VFA concentration. Acetic acid proportion was increased (P<0.001) before extraction of forages but no difference was found between forages. Propionic acid($C_3$) proportion was also increased(P<0.001) before extraction in all forages than in straws at 3h, 24h and 48h incubations, and $C_3$ from hays were mostly higher (P<0.05) than from straws. Butyric acid proportion, however, was not affected by extraction at most incubation times. Parameter 'a' regarding to the dry matter (DM) degradation was increase (P<0.001) in all forages before extraction, and was decreased (P<0.05) in tall fescue straw and rice straw compared with hays. Parameter 'b' was also increased (P<0.001) before extraction but no difference was found between forages. Effective degradability of DM (EDDM) was higher (P<0.001) before extraction in most forages except for rice straw. Buffer extraction decreased (P<0.05) all parameters (a, b, and c) regrading to the crude protein (CP) degradation but no difference was found between forages. Effective degradation of CP (EDCP) was lower (P<0.05) in straws than in hays. Parameters 'a' and 'b' regarding to the NDF degradation (P<0.01) and effective degradability of NDF (EDNDF, P<0.001) were also higher in forages before extraction than after extraction but no difference was found between forages. Buffer extraction reduced (P<0.05~P<0.001) $CO_2$ production from all the forages uo to 24h incubation and its production was greater (P<0.05~P<0.01) from hays than straws. Methane ($CH_4$) production was also greater (P<0.01~P<0.001) in all forages at all incubation times, and its production was greater (P<0.05) from hays than from straws at most incubation times. Based on the results of the current study, it can be concluded that buffer solubility and CP fractionation might be closely related with $In$ $vitro$ VFA concentration, degradability and gas ($CO_2$ and $CH_4$) production. Thus, measurement of buffer solubility and protein fractionation of forages might be useful to improve TMR availability in the ruminants.

High speed deposition technique of YSZ film for the superconducting tape (고온초전도테이프 제작을 위한 YSZ 박막의 고속증착방법)

  • Kim Ho-Sup;Shi Dongqui;Chung Jun-Ki;Ko Rock-Kil;Ha Hong-Soo;Song Kyu-Jeong;Youm Do-Jun;Park Chan
    • Progress in Superconductivity and Cryogenics
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    • v.6 no.3
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    • pp.27-32
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    • 2004
  • High temperature superconducting coated conductor has a structure of /< superconducting layer>//. The buffer layer consists of multi layer, and the architecture most widely used in RABiTS approach is CeO$_2$(cap layer)/YSZ(diffusion barrier layer)/CeO$_2$(seed layer). Evaporation technique is used for the CeO$_2$ layer and DC reactive sputtering technique is used for the YSZ layer, A chamber was set up specially for DC reactive sputtering, Detailed features are as following. A separator divided the chamber into two halves a sputtering chamber and a reaction chamber. The argon gas for sputtering target elements flows out of the cap of sputtering gun, and water vapor for reaction with depositing species spouts near the substrate. Turbo pump is connected with reaction chamber. High speed deposition of YSZ film could be achieved in the chamber. Detailed deposition conditions (temperature and partial pressure of reaction gas) were investigated for the rapid growth of high quality YSZ film.

A Study on preionization effect of discharge excited KrF excimer laser (방전여기 KrF 엑사이머 레이저의 에비전리 영향에 관한연구)

  • Kim, Sang-Ook;Choi, Boo-Yeon;Lee, Choo-Hie
    • Proceedings of the KIEE Conference
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    • 1990.07a
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    • pp.459-461
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    • 1990
  • Me performed an experiment about preionization electron number density of charge transfer type KrF excimer laser. At the total pressure of 1.8 and 2.2 atm with helium (He) buffer gas, the experimental range of the electron number density is 8-9 ${\times}$ 10 cm The distance between electrode and preionization pin is 15 mJ at charging voltage of 27kV,gas pressure of 2.2 atm,gas mixture of F /Kr/He = 0.3/396.7(%).

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Analysis of Rotationally Cooled Vibronic Emission Spectra ($1^2A_2→1^2B_2$) of m-Xylyl Radical

  • 최익순;이상국
    • Bulletin of the Korean Chemical Society
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    • v.17 no.8
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    • pp.749-753
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    • 1996
  • The rotationally cooled but electronically excited m-xylyl radical has been generated in a jet from the gas mixture of precursor m-xylene and buffer gas He by a technique of corona excited supersonic expansion. The visible vibronic emission spectra in the transition of 12A2→12B2 of m-xylyl radical in the gas phase have been recorded using a Fourier transform spectrometer. The spectra have been analyzed for the assignments of the vibrational frequencies in the electronic ground state with combination of the torsional frequencies reported previously.