• Proceedings of the Korean Vacuum Society Conference
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• 2000.02a
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• pp.139-139
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• 2000

We have investigated the adsorption and reaction of Cu(hfac)(vtms) on Cu(111) surface using TPD. The recombinative desorption of Cu(hfac)(vtms) reversibly occurs between 240 and 340K. The remaining Cu(hfac) after the desorption of vtms preferentially undergo the desorption between 330 and 370K as intact Cu(hfac) than the disproportionation reaction. The disprportionation reaction between adsorbed Cu(hfac) was observed to occur between 420 and 520K with an activation energy of 34~37 kcal/mol. the geometries and adsorption sites of Cu(hfac) have been also calculated by means of extended H ckel method. It is found that standing Cu(hfac) is more stable than lying-down Cu(hfac) on the Cu(111) surface and the Cu(hfac) molecule prefers to adsorb on the hollow site over the top or bridge sites. We also have investigated the surface modification effect by preadsorbed I and Na atoms on the reaction Cu(hfac)(vtms).

• Bulletin of the Korean Chemical Society
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• v.22 no.3
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• pp.267-270
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• 2001

The adsorption of chlorine on a Pt(111) surface at 90 K has been studied using scanning tunneling microscopy (STM) in ultra-high vacuum environments. The adsorbed chlorine atoms give rise to two different ordered structures, (3${\times}$3)-Cl and c(4${\times}$2)- Cl, depending on the coverage. It has been determined from the STM image that the absolute coverage of (3${\times}$3)-Cl structure is 0.44, which is not in agreement with coverage calibrated by a low energy electron diffraction technique together with an Auger electron spectrometer and a thermal desorption spectrometer. The Cl atoms bound to on-top sites at the Pt(111)(3${\times}$3)-Cl surface appeared to effectively perturb the density of states of Pt atoms, as compared with that bound to bridging sites. The other ordered structure, c(4${\times}$2)-Cl, with small domain sizes, consists of both on-top and bridge-bonded species with a saturation coverage of 0.5.

• International Journal of Advanced Culture Technology
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• v.11 no.4
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• pp.81-87
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• 2023

In order to create and utilize experiential equipment that can be effectively used in school safety education, this paper uses the Korean Safety Education Association's CPR simulator to utilize the elements of educational games: goals, rules, competition, challenge, fantasy, safety, and fun. When the content that combines game elements with general educational equipment was utilized in school education sites, significant results were obtained on the effectiveness of education with active participation of students.

• Journal of the Korean Magnetics Society
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• v.17 no.4
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• pp.147-151
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• 2007

We have investigated the half-metallicity and magnetism for the Heusler ferromagnet $Co_2$ZrSi interfaced with semiconductor ZnTe along the (001) plane by using the full-potential linearized augmented plane wave (FLAPW) method. We considered low types of possible interfaces: ZrSi/Zn, ZrSi/Te, Co/Zn, and Co/Te, respectively. From the calculated density of states, it was found that the half-metallicity was lost at all the interfaces, however for the Co/Te system the value of minority spin density of states was close to zero at the Fermi level. These facts are due to the interface states, appeared in the minority spin gap in bulk $Co_2$ZrSi, caused by the changes of the coordination and symmetry and the hybridizations between the interface atoms. At the Co/Te interface, the magnetic moments of Co atoms are 0.68 and $0.78{\mu}_B$ for the "bridge" and "antibridge" sites, respectively, which are much reduced with respect to that ($1.15{\mu}_B$) of the bulk $Co_2$ZrSi. In the case of Co/Zn, Co atoms at the "bridge" and "antibridge" sites have magnetic moments of 1.16 and $0.93{\mu}_B$, respectively, which are almost same or slightly decreased compared to that of the bulk $Co_2$ZrSi. On the other hand, for the ZrSi/Zn and ZrSi/Te systems, the magnetic moments of Co atoms at the sub-interface layers are in the range of $1.13{\sim}1.30\;{\mu}_B$, which are almost same or slightly increased than that of the bulk $Co_2$ZrSi.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.12
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• pp.1353-1359
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• 2007

Water quality constituents, and particle size distributions were characterized in urban bridge road runoff, Bridge road runoff contains significant loads of micro-particles, heavy metals and organic constituents. Bridge road runoff was monitored on four sites of four and six lanes bridge road areas along with traffic volume. A total seven storm events were monitored to characterize the bridge road runoff. The quantity of road runoff and quality constituents, including chemical oxygen demand(COD), suspended solids(SS), total nitrogen(T-N), ortho-phosphorus$(PO_4-P)$, total phosphorus(T-P), and particle size distribution were analyzed. The results indicate that the concentrations of SS, COD, T-N and T-P ranges were $35\sim2,390$ mg/L, $40\sim1,274$ mg/L, $0.03\sim21.25$ mg/L, and $0.05\sim4.58$ mg/L, respectively. And the results showed that the mean range of particle size and $D_{90}$ for bridge road runoff were $4.75\sim14.05{\mu}m$ and $17.33\sim58.15{\mu}m$, respectively.

• Journal of the Earthquake Engineering Society of Korea
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• v.10 no.5 s.51
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• pp.85-97
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• 2006

Capacity design is to guarantee ductile failure of whole bridge system by preventing brittle failure of columns and any other structural elements until the columns develope fully enough plastic deformation capacity. This concept has been explicitly regulated in most bridge design specifications of foreign countries except the current Korea Bridge Design Specifications. In the capacity design, the transformed shear force from flexural overstrength of reinforced concrete column is used as the design lateral shear force for shear design of columns and design of footings and piles. Different calculating methods are adopted by the design specifications, since the variability of material strength and construction circumstances of the local regions should be considered. This paper proposed material overstrength factors by investigating 3,407 reinforcing bar data and 5,405 concrete compressive strength data collected in Korean construction sites. It also proposed calculating procedures for flexural overstrength of reinforced concrete columns using the material overstrength. Finally, overstrength factor was proposed as 1.5 by investigating 1,500 column section data from moment-curvature analysis using the material overstrength.

• Journal of Korea Water Resources Association
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• v.30 no.6
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• pp.721-729
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• 1997

Total scour depth at a bridge is comprised of three components: long-term changes, contraction scour and local scour. Therefore, the analysis of long-term bed elevation changes is very important in the estimation of total scour depth at bridge sites. In this research, long-term bed elevation changes at the Namhan River Bridge are analysed using CHARIMA and HEC-6 models. The results show that, for 5-year steady normal stream flow, the bed elevation is aggreded by 45cm for CHARIMA model but degraded by 5cm for HEC-6 model. For 5-year unsteady flow, the bed elevation is changed greatly and it has a great influence on the estimation of total scour depth. Therefore, to make a proper estimation of total scour depth, not only contraction scour and local scour, but also long-term bed elevation changes should be estimated precisely.

• Proceedings of the Earthquake Engineering Society of Korea Conference
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• 1998.04a
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• pp.89-97
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• 1998

This study is intended to investigate the seismic responses of bridge structures considering site effects. The site effects in the seismic analysis of bridge structures were classified into two parts. At first, the seismic responses of the structures on each "soil profile types" of the code were evaluated in accordance with code-specified method and compared with results of time-history analysis method. And next, as a second stage of the study, the responses of the two different soil with considerably different soil properties, even though they are classified to the same "soil profile types" of the code, were evaluated and compared each other. The first part of study is purposed to evaluate the applicability of code-specified method, while the other part is purposed to find the variance of the seismic responses from the different soil sites in the same soil profile types of the code. For the analysis, two major methods of the code, single-mode spectral anaysis and multi-mode spectral analysis, were used and the time-history analysis method which is expected to give more accurate responses was also used for the comparison purposes. For the time-history analysis, time-domain analysis technique of the lumped-mass model with frequency-independent soil springs and dampers was adopted and artificially generated spectra of the code was used as input motion. As the results of the study, the code specified methods for the seismic responses considering the site effects were verified to give the results in conservative side for the most of the cases. However, for the structures on the site with considerable flexibility, the responses of the bridge girders or deckplates by the code methods both in section forces and horizontal movement responses, may have much smaller values than the actual responses. Therefore, more detailed analysis considering the flexibility of the base soil may be required to have more reasonable results in girder responses.in girder responses.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.32 no.6
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• pp.425-434
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• 2019

It is important to ensure the seismic safety of pile-bent bridges constructed in areas with thick soft ground consisting of various soil layers against seismic motion in these layers. In this study, several synthetic seismic waves that are compatible with the seismic design spectrum for rock sites were generated, and the ground acceleration history of each soil layer was obtained based on ground analyses. Using these acceleration histories, each soil layer was modeled using equivalent linear springs, and multi-support excitation analyses were performed using the input motion obtained at each soil layer. Due to the nonlinear behavior of the soft soil layers, the intensity of the input ground motion was not amplified, which resulted in the elastic behavior of the bridge. In addition, inputting the acceleration history obtained from a particular layer simultaneously into all the ground springs reduced the response. Therefore, the seismic performance of this type of bridge might be overestimated if multi-excitation analysis is not performed.

• Macromolecular Research
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• v.12 no.1
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• pp.100-106
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• 2004

We have prepared the polymethylene-bridged, dinuciear, half-sandwich constrained geometry catalysts (CGC)［Zr(η$\^$5/:η$^1$-C$\_$9/H$\_$5/SiMe$_2$NCMe$_3$)］$_2$［(CH$_2$)$\_$n/］［n=6(9), n=12(10)］by treating 2 equivalents of ZrCl$_4$with the corresponding tetralithium salts of the ligands in toluene. $^1$H and $\^$13/C NMR spectra of the synthesized complexes provide firm evidence for the anticipated dinuciear structure. In $^1$H NMR spectra, two singlets representing the methyl group protons bonded at the Si atom of the CGC are present at 0.88 and 0.64 ppm, which are considerably downfield positions relative to the shifts of 0.02 and 0.05 ppm of the corresponding ligands. To investigate the catalytic behavior of the prepared dinuciear catalysts, we conducted copolymerizations of ethylene and styrene in the presence of MMAO. The prime observation is that the two dinuclear CGCs 9 and 10 are not efficient for copo-lymerization, which definitely distinguishes them from the corresponding titanium-based dinuclear CGC. These species are active catalysts, however, for ethylene homopolymerization; the activity of catalyst 10, which contains a 12-methylene bridge, is larger than that of 9 (6-methylene bridge), which indicates that the presence of the longer bridge between the two active sites contributes more effectively to facilitate the polymerization activity of the dinuciear CGC. The activities increase as the polymerization temperature increases from 40 to 70$^{\circ}C$. On the other hand, the molecular weights of the polyethylenes are reduced when the polymerization temperature is increased. We observe that dinuciear metallocenes having different-length bridges give different polymerization results, which reconfirms the significant role that the nature of the bridging ligand has in controlling the polymerization properties of dinuclear catalysts.