• 한국재료학회지
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• 제32권1호
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• pp.36-43
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• 2022

Breakthrough analysis has widely been explored for the dynamic separation of gaseous mixtures in porous materials. In general, breakthrough experiments measure the components of a flowing gas when a gaseous mixture is injected into a column filled with an adsorbent material. In this paper, we report on the design and fabrication of a breakthrough curve measurement device to study the dynamic adsorptive separation of hydrogen isotopologues in porous materials. Using the designed system, an experiment was conducted involving a 1:1 mixture of hydrogen and deuterium passed through a column filled with zeolite 13X (1 g). At room temperature, both hydrogen and deuterium were adsorbed in negligible amounts; however, at a temperature of 77 K, deuterium was preferentially adsorbed over hydrogen. The selectivity was different from that in the existing literature due to the different sample shapes, measurement methods, and column structures, but was at a similar level to that of cryogenic distillation (1.5).

• 한국지구물리탐사학회:학술대회논문집
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• 한국지구물리탐사학회 2011년도 학술대회 및 정기총회
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• pp.3-12
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• 2011

• 환경위생공학
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• 제17권3호
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• pp.99-109
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• 2002

Charcoal $tube/CS_2$ method are more popularly used than any other in the measurement of the working environment for the exposure evaluation of organic solvent, but it is some weak points that the lower accuracy can be obtained on the polar materials and within the range of the low concentration. Thus solvent desorption method has been developed to make accuracy higher and to overcome some weak points. However, because of high price of adsorption tube for thermal desorption and the short of study on its application to the working environment, it is not popularly used in the domestic industrial hygiene fields. This dissertation aims to develop thermal desorption and adsorption tubes for measuring organic solvents in the working environment, by comparing and analyzing breakthrough condition and adsorption capacity with ACF. Specific surface area of ACF used in this study is wider than the one of AC and micropore of ACF related with adsorption has been developed, and adsorption velocity and adsorption amount are very excellent by linking a pore of surface and an inside well into micropore. 1. Result of analysis on physical characteristics of adsorbent, the specific surface area of ACF was 1.3 times higher than that of AC. Distribution ratio of micropore related to adsorption was 94% on ACF and AC. Result of SEM, micropore of the AC is opened to the surface. In contrast, ACF shows that extremely fast adsorption speed. Because of micropore are exposed on the surface and penetrate through each other. 2. Breakthrough characteristics of adsorbents was not different from slop of breakthrough curve. The effluent concentration reaches 10% of initial concentration($C_{out}/C_{in}=0.1$, break point) of ACF was 30~316min longer than that of AC. Therefore, the adsorption capacities of ACF was 1.1~4.6 times higher than that of AC. ACF can be used as a proper adsorbent for measurement of organic solvent.

• 상하수도학회지
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• 제24권3호
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• pp.333-339
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• 2010

Particle removal is an important step taken at water treatment plants (WTPs) for the safety of tap water due to its proportionality to the pathogen inactivation. Government promulgated a treatment technique for the optimization of filtration including continuous turbidity monitoring using on-line turbidimeters. Based on the turbidity measurements of 460 filters at 31 WTPs operated by K-water, the evaluation of filtration performance and the investigation of major causes related to particle breakthrough were explored. 98.1 % of the filters had an effluent turbidity measurement which was less than 0.1 NTU, but turbidity breakthrough of more than 0.3 NTU was noticed occasionally which is in violation of AWWA 5-Star guidelines. It was shown that the optimization of coagulation, filter-to-waste, the observance of optimal filtration velocity and backwashing process based on filtrate turbidity were crucial for the improvement of filtrate.

• 한국산업보건학회지
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• 제33권1호
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• pp.3-5
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• 2023

Objective: This study introduces exposure concentrations of time-weighted average standard (TWA) evaluation and short-time exposure standard (STEL) evaluation for trichloroethylene in the cleaning process. Methods: Trichloroethylene measurement was conducted according to the KOSHA Guide (A-24-2019) method. It was carried out twice. Results: As a result of the first measurement, TWA concentration exceeded 4 times the exposure standard and STEL concentration exceeded 16 times, but the inaccuracy and breakthrough of the collection time could not be considered, so the second measurement was conducted. The second measurement result was lower than the first measurement result, but exceeded the exposure standards (TWA, STEL). Conclusions: We were able to confirm that the exposure level of workers in the cleaning process using trichloroethylene exceeded the exposure standard. And it is also considered necessary to grasp the approximate concentration using a detector tube in the preliminary survey.

• Journal of Korean Society for Atmospheric Environment
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• 제18권E1호
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• pp.1-12
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• 2002

One technique for determining dry acid deposition fluxes involves measurement of time - averaged ambient concentrations of dry acid deposition species using filter packs (FP) coupled with estimates of mean deposition velocities for the exposure period. A critical problem associated with filter pack data comparisons between various field sampling networks is the use of diverse sampling flow rates and duration protocols. Field experiments were conducted to evaluate the effects of varying sampling flow rates, from 1.5 to 10 standard liters per minute, on total nitrate and sulfate measurements of specific dry acid deposition species . Collocated FP samplers were used to determine sampling and analysis data reproducibility and representativeness . Ambient air samples were simultaneously collected using groups of filter packs operated at various flow rates over identical 7 day periods. The species measured were sulfur dioxide, particulate sulfate , nitric acid and particulate nitrate. Statistical results (ANOVA; alpha level 5%) showed that neither the low nor high sampling flow rates caused a significant difference in the measurements of total sulfate and adjusted total nitrate (ATN) . However, it was concluded that for high flow rate sampling measurements, total nitrate (TN) could be affected during extended sampling durations because of potential nitric acid overloading and breakthrough. Although the previous workers (Costello, 1990; Quillian, 1990) used much higher sampling flow rates (~ 17 sLpm) than employed here, it was assumed that for a high loading (> 50$\mu\textrm{g}$ HNO$_3$) of nitric acid on the Nylon filters, a significant fraction (~10%) of nitric acid could pass through the Nylon filters and be collected on the carbonate impregnated filters. It was concluded that even at the highest sampling flow rate employed (10 sLpm) at the Cary Forest site, nitric acid breakthrough was less than 10% of the total HNO$_3$ collected. However, for a heavily polluted urban airshed or with longer sampling times , higher filter loadings could result in substantial nitric acid breakthrough and HNO$_3$concentrations would be underestimated.

• 공업화학
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• 제10권2호
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• pp.310-318
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• 1999

공기분리 PSA 공정설계에 적용할 물질전달계수를 구하기 위하여 흡착탑을 통과하는 질소와 산소의 농도에 대한 동적파과곡선을 실험적으로 측정하였다. 그 결과를 전산모사에 의한 파과곡선과 비교하여 벌크흐름 중의 물질전달속도를 예측하였다. 전산모사에서 흡착은 coupled Langmuir isotherm을 따른다고 보았으며, 물질전달은 LDF 모델에 의해 표현된다고 가정하였다. 실험과 이론의 비교를 통해 얻은 물질전달계수는 유속에는 거의 영향을 받지 않았으나 압력 조건에 따라 민감한 변화를 보였다. 이를 통해 물질전달저항이 거대기공 확산영역에 있음을 예측할 수 있었으며, 물질전달계수를 압력변화에 대해 지수함수의 형태로 표현하였다. 질소나 산소 단일 성분에 대해서 얻은 물질전달계수는 질소와 산소 혼합 벌크기체의 파과곡선에 적용했을 경우에도 5% 이하의 오차로 잘 일치함을 보여주었다.

• Environmental Analysis Health and Toxicology
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• 제17권2호
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• pp.147-160
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• 2002

Volatile organic compounds (VOCs) are an important public health issue in Korea and many important questions remain to be addressed with respect to assessing exposure to these compounds. Because they are ubiquitous and highly volatile, special techniques must be applied in their analytic determination Valid Personal exposure assessment methods are needed to evaluate exposure frequency, duration and intensity, as well as their relationship to personal exposure characteristics. Biological monitoring is also important since it may contribute significantly in risk assessment by allowing the estimation of effective absorbed doses. This study was on ducted to establish the environmental measurement, personal dosimetry and biological monitoring methods for VOCs. These methods are needed to compare blood, urinary and exhalation breath VOC levels and to provide tools for risk assessment of VOC exposure. Passive monitors (badge type) and a active samplers (trap) for the VOCs collection were used for air sampling. Methods development included determining the minimum detectable amounts of VOCs in each media, as well as evaluating collection methods and developing analytical procedures. Method reliability was assessed by determining breakthrough volumes and comparing results between laboratories and with other methods. A total capacity of trap used in this study was 60ι. Although variable by compound, the average breakthrough was 20％. Also, there was no loss of compounds in trap even if keep for 45 day in -7$0^{\circ}C$. The recovery of active and passive methods was 69％ ~ 126％ and method detection limit was 0.24 $\mu\textrm{g}$/trap and 0.07 $\mu\textrm{g}$/badge. There was no statistical difference (P > 0.05) between active and passive methods.

• 한국지반공학회논문집
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• 제23권7호
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• pp.47-55
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• 2007

본 연구에서는 흙-벤토나이트월과 같은 차단벽체에 대한 전기전도도 모니터링 기법의 적용성을 평가하였다. 벤토나이트 함량, 투수계수 및 중금속 농도에 따른 전기전도도 변화를 파악하기 위하여 투수실험과 주상실험을 실시하였다. 흙-벤토나이트 혼합 다짐시편의 전기전도도는 벤토나이트 함량이 증가함에 따라 선형적으로 증가하는 경향을 나타내었다. 또한 흙-벤토나이트 차단벽체의 투수계수는 벤토나이트 함량과 반비례하는 경향을 나타내었으며, 전기전도도와도 반비례하는 경향을 나타내었다. 주상실험을 통하여 전기전도도 파과곡선과 농도 파과곡선을 동시에 구할 수 있었다. 이 결과는 전기전도도 측정기법이 벽체 내부의 임의 지점에서 중금속의 이동을 감지하고 오염물질의 누출 가능성을 확인하는 유용한 방법으로 활용될 수 있음을 나타낸다. 본 연구결과에 의하면 전기전도도 측정기법이 차단벽체 모니터링에 효과적으로 적용될 수 있을 것으로 기대된다.

• Environmental Analysis Health and Toxicology
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• 제17권1호
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• pp.63-71
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• 2002

The thermal desorption-gas chromatographic (TD-GC) system has been constructed for the measurement of volatile organic compounds. The thermal desortion unit is composed of four major parts: 1) the control part; 2) the thermal desorption part; 3) the focusing part; and 4) the injection part. The peltier element was introduced to the focusing part for the temperature of the focusing tube to reach-35$^{\circ}C$. The system was tested for the linearity of the calibration curves and reproducibility of instrumental analyses using some disinfection by-products (DBPs) and BTXs (benzene, toluene and p-xylene). The coefficients of determination (r$^2$) for all the calibration curves made were higher than 0.998, and the coefficients of variation (CV) for triplicate measurements were all within 10％. The system also has been tested for field applicability. The analysis of field samples showed that there was no breakthrough problem in the sampling system and that the system could be applied to field measurements.