• Title/Summary/Keyword: boron trifluoride

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Study for an BF3 Specialty Gas Production (BF3 생산에 관한 연구)

  • Lee, Taeck-Hong;Kim, Jae-Young
    • Journal of the Korean Institute of Gas
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    • v.15 no.3
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    • pp.74-78
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    • 2011
  • $BF_3$ gas has been used for semiconductor manufacturing process and applied in plasma etching, chemical vapor deposition, chamber cleaning processes etc,. $BF_3$ provides Boron and acts as a p-type doping in electrode in semiconductor. In this study, we investigate thermaldecomposition of alkali-boron complexes and suggest a simple way to produce $BF_3$ from $NaBF_4$ and $KBF_4$.

Stereocontrolled Preparation of 2,6-Disubstituted 4-Methylenetetrahydropyrans by Lewis Acid Promoted Allylsilane-Acetal Cyclization

  • 성태명;곽우영;강경태
    • Bulletin of the Korean Chemical Society
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    • v.19 no.8
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    • pp.862-868
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    • 1998
  • The Lewis acid mediated intramolecular additions of allylsilanes to acetal substrates are described. Excellent regio- and diastereoselectivity are achieved by boron trifluoride promoted cyclization of allysilane-acetals 5 and 8 derived from hydroxy allysilances 3. Cyclizations occur in moderate to high yields, providing directr routes to cis-2, 6-disubstituted 4-methylenetetrahydropyrans 6 and 9.

Synthesis of New BF2-Chelate Compounds (새로운 BF2-Chelate 화합물들의 합성)

  • Kim, Jung-Hwan;Kim, Yeung-Eun
    • Journal of the Korean Chemical Society
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    • v.48 no.4
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    • pp.379-384
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    • 2004
  • 4-pyrimidylideneacetonitrile derivatives containing $BF_2$-chelate have been synthesized from H-chelates of 4-pyrimidylideneacetonitrile derivatives and boron trifluoride diethyl etherate. These H-chelates were prepared by the electrophilic substitution of 2-cyanomethylpyridine derivatives with electrophiles such as 4,6-dichloropyrimidine, 4,6-dichloro-2-methylpyrimidine, 4,6-dichloro-2-heptadecylpyrimidine, 4,6-dichloro-2-phenylpyrimidine, 4,6-dichloro-5-phenylpyrimidine and 4,6-dichloro-2,5-diphenylpyrimidine. Structures of the target molecules were identified by spectra methods.

Assessment of the Implementation of a Neutron Measurement System During the Commissioning of the Jordan Research and Training Reactor

  • Bae, Sanghoon;Suh, Sangmun;Cha, Hanju
    • Nuclear Engineering and Technology
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    • v.49 no.3
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    • pp.504-516
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    • 2017
  • The Jordan Research and Training Reactor (JRTR) is the first research reactor in Jordan, the commissioning of which is ongoing. The reactor is a 5-MWth, open-pool type, light-water-moderated, and cooled reactor with a heavy water reflector system. The neutron measurement system (NMS) applied to the JRTR employs a wide-range fission chamber that can cover from source range to power range. A high-sensitivity boron trifluoride counter was added to obtain more accurate measurements of the neutron signals and to calibrate the log power signals; the NMS has a major role in the entire commissioning stage. However, few case studies exist concerning the application of the NMS to a research reactor. This study introduces the features of the NMS and the boron trifluoride counter in the JRTR and shares valuable experiences from lessons learned from the system installation to its early commissioning. In particular, the background noise relative to the signal-to-noise ratio and the NMS signal interlock are elaborated. The results of the count rates with the neutron source and the effects of the discriminator threshold are summarized.

Cationic Polyemrization of tort-Butyl Vinyl Ether (tert-Butyl Vinyl Ether의 양이온중합)

  • 권순홍;전현정;한규찬;마석일
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.9-12
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    • 2003
  • 요오드 2분자가 양이온(I$^{+}$)과 음이온(I$_3$$^{-}$)로 해리되어 이 매 생성된 양이온에 의한 비닐 에테르류의 양이온 중합에 관한 연구는 보고된 바 있으나$^{1)}$ 요오드를 개시제로 사용한 삼차부틸 에테르의 양이온 중합에 관한 결과가 발표된 것은 별로 눈에 뜨이지 않는다. 삼차 부틸 에테르는 단량체의 활성이 크고 중합거동이 타 비닐 에테르류와 매우 다르기 때문에$^{3),4)}$ boron trifluoride diethyl etherate를 개시제로 하고, n-햅탄 이나 톨루엔과 같은 비극성용매를 사용하여 저온에서 중합을 행한 결과만이 보고되고 있다.$^{2)-5)}$ (중략)

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New Synthetic Method of Perfluoro-Silanes for the Stable Electrolyte of Lithium Ion Battery Application

  • Koh, Kyungkuk;Sohn, Honglae
    • Journal of Integrative Natural Science
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    • v.10 no.3
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    • pp.171-174
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    • 2017
  • Non-hydrolyzable fluorinated organosilicon compounds as an eletrolyte for the application of lithium-ion batteries (LIB) are synthesized. New synthetic method for the perfluorinated organosilicon compound containing spacer such as ethyl and propyl group with cyano moiety instead of ethylene glycol to prevent hydrolysis and to promote conductivity are developed in one pot reaction with moderately high yield. Air-sensitive boron trifluoride etherate is no longer required in this reaction. The products are characterized by spectroscopic analysis.