• Title/Summary/Keyword: boron analysis

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Try out and Analytical Researches on Quenching Process of Coupled Torsion Beam Axle using Boron Steel Tube (보론강을 이용한 CTBA의 후열처리 공정 실험 및 해석)

  • Yoon, S.J.;Park, J.K.;Kim, Y.S.;Suh, C.H.;Lee, K.H.;Kim, R.Y.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.10a
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    • pp.181-184
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    • 2009
  • The hot press farming process, which is the press hardening of steel parts using cold dies, can utilize both ease of shaping and high strength due to the hardening effect of rapid quenching during the pressing. In this study, a thermo-elastoplastic analysis of the hot press forming process using the finite element method was performed in order to investigate the deformation behavior and temperature history during the process and the mechanical properties of the pressed parts.

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Fabrication of Reverse Osmosis Membrane with Enhanced Boron Rejection Using Surface Modification (표면개질을 이용하여 붕소 제거율이 향상된 역삼투막의 제조)

  • Lee, Deok-Ro;Kim, Jong Hak;Kwon, Sei;Lee, Hye-Jin;Kim, In-Chul
    • Membrane Journal
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    • v.28 no.2
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    • pp.96-104
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    • 2018
  • With the rapid increase in seawater desalination, the importance of boron rejection is rising. This study was conducted to investigate the effect of hydrophilic compounds on surface modification to maximize water flux and increase boron rejection. First, polyamide active layer was fabricated by interfacial polymerization of polysulfone ultrafiltration membrane with M-phenylenediamine (MPD) and trimesoyl chloride (TMC) to obtain Control polyamide membrane. Next, D-gluconic acid (DGCA) and D-gluconic acid sodium salt (DGCA-Na) were synthesized with glutaraldehyde (GA) and hydrochloric acid (HCl) by modifying the surface of Control polyamide membrane. XPS analysis was carried out for the surface analysis of the synthesized membrane, and it was confirmed that the reaction of surface with DGCA and DGCA-Na compounds was performed. Also, FE-SEM and AFM analysis were performed for morphology measurement, and polyamide active layer formation and surface roughness were confirmed. In the case of water flux, the membrane fabricated by the surface modification had a value of 10 GFD or less. However, the boron rejection of the membranes synthesized with DGCA and DGCA-Na compounds were 94.38% and 94.64%, respectively, which were 12.03 %p and 12.29 %p larger than the Control polyamide membrane, respectively.

Study on Determination of Boron using the PGAA Facility at HANARO Research Reactor (하나로의 즉발감마선 방사화분석 장치를 이용한 붕소의 정량에 대한 연구)

  • Chung, Young-Sam;Cho, Hyun-Jae;Moon, Jong-Hwa;Kim, Sun-Ha;Kim, Young-Jin
    • Analytical Science and Technology
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    • v.16 no.5
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    • pp.391-398
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    • 2003
  • Basic research for the determination of boron content in biological sample has been carried out using the PGAA facility of the 24MW research reactor(HANARO). For investigation of characteristics for the measurement condition, neutron flux and its homogeneity were measured at irradiating geometry. The size of thermal neutron beam collimated from beam guide is $2{\times}2cm^2$ at the sample position. The neutron flux measured was the range of $1.0{\sim}6.5{\times}10^7n{\cdot}cm^{-2}{\cdot}s^{-1}$, and flux distribution from center within the radius of 4.5 mm and 9.0 mm was $5.77{\pm}0.71{\times}10^7n{\cdot}cm^{-2}{\cdot}s^{-1}$ and $4.68{\pm}1.64{\times}10^7n{\cdot}cm^{-2}{\cdot}s^{-1}$, respectively. Accordingly, sample size is adjusted within 10 mm for a homogeneous irradiation of high quality. Measurement system is designed to reduce the background source by Compton scattering and to improve the analytical sensitivity. To investigate the energy calibration and Compton suppression effect of gamma-ray counting system, the background conditions on both of Compton and single-mode were measured using NaCl standard. On the other hand, degree of spectral interference for sodium 472 keV peak as a matrix effect in the sample is established for an accurate boron analysis, and then boron content in three certified reference materials (NIST SRM 1570a, 1547, 1573a) was measured by using two modes and the results were compared with each other.

Prediction of Jominy Hardness Curves Using Multiple Regression Analysis, and Effect of Alloying Elements on the Hardenability (다중 회귀 분석을 이용한 보론강의 조미니 경도 곡선 예측 및 합금 원소가 경화능에 미치는 영향)

  • Wi, Dong-Yeol;Kim, Kyu-Sik;Jung, Byoung-In;Lee, Kee-Ahn
    • Korean Journal of Materials Research
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    • v.29 no.12
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    • pp.781-789
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    • 2019
  • The prediction of Jominy hardness curves and the effect of alloying elements on the hardenability of boron steels (19 different steels) are investigated using multiple regression analysis. To evaluate the hardenability of boron steels, Jominy end quenching tests are performed. Regardless of the alloy type, lath martensite structure is observed at the quenching end, and ferrite and pearlite structures are detected in the core. Some bainite microstructure also appears in areas where hardness is sharply reduced. Through multiple regression analysis method, the average multiplying factor (regression coefficient) for each alloying element is derived. As a result, B is found to be 6308.6, C is 71.5, Si is 59.4, Mn is 25.5, Ti is 13.8, and Cr is 24.5. The valid concentration ranges of the main alloying elements are 19 ppm < B < 28 ppm, 0.17 < C < 0.27 wt%, 0.19 < Si < 0.30 wt%, 0.75 < Mn < 1.15 wt%, 0.15 < Cr < 0.82 wt%, and 3 < N < 7 ppm. It is possible to predict changes of hardenability and hardness curves based on the above method. In the validation results of the multiple regression analysis, it is confirmed that the measured hardness values are within the error range of the predicted curves, regardless of alloy type.

Effects of Hafnium, Boron and Zirconium on the Ductility of Ni$_3$(Al, Fe) Intermetallic Compounds

  • Lim, S.H.;No, J.Y.;No, K.S.;Wee, D.M.
    • Korean Journal of Materials Research
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    • v.2 no.4
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    • pp.306-310
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    • 1992
  • Effects of hafnium, boron and zirconium on the ductility of Ni$_3$(Al, Fe) intermetallic compounds were studied using tensile test and SIMS analysis. Ni$_3$(Al, Fe) alloy with 0.1 at.% Hf, 0.05 at.% B and 0.1 at.% Zr additions showed maximum elongations of about 30% at 300K, 10% at 300K and 14% at 473K, respectively. The fracture mode of the alloy without the additive was the mixture of intergranular and transgranular fractures, but the addition of Hf, Zr or B changed the fracture mode to transgranular only. SIMS analysis showed that the beneficial effects of Hf, Zr or B segregation on the grain boundary strength are consistent with the grain boundary cohesion theory.

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Core Follow Analysis for Yonggwang Unit 3 Cycle 1

  • Baek, Byung-Chan;Lee, Chang-Kue;Lee, Chung-Chan;Zee, Sung-Quun
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05a
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    • pp.538-544
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    • 1996
  • This paper presents the results of the core follow analysis for Yonggwang Unit 3 Cycle 1. The values of peaking factors (Fxy, Fq, Fr anf Fz) and core power distribution measured and processed by CECOR code[1] are compared with those predicted by ROCS code[2], The measured boron rundown is also compared with the predicted values. As results, the comparison of peaking factors, radial and axial power distributions and boron rundown between the measured and the predicted show good agreement throughout the cycle. Additionally, assembly burnup differences between CECOR and ROCS at EOC1 (13650 MWD/MTD are within 5% of core average burnup.

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