• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.189.2-189.2
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• 2014

The most stable adsorption structures and energies of four tautomerized forms (keto-1, enol-1, keto-2, and enol-2) of 3-methyl 5-pyrazolone (MP) adsorbed on Ge(100) surfaces have been investigated by Density Functional Theory (DFT) calculation method. Among its four tautomerized forms, we confirmed three tautomerized forms except keto-1 form show the stable adsorption structures when they adsorbed on the Ge(100)-$2{\times}1$ surface as we calculate the respective stable adsorption structures, activation barrier, transition state energy, and reaction pathways. Moreover, among three possible adsorption structures, we acquired that enol-2 form has most stable adsorption structure with O-H dissociated N-H dissociation bonding structure.

• Journal of Surface Science and Engineering
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• v.41 no.6
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• pp.274-278
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• 2008

3-dimensional numerical analysis for a rectangular magnetron cathode model is done to predict cooling characteristics of high power sputtering system for ZnO deposition. It includes cooling channel design, heat transfer analysis of a target, bonding layer and backing plate. In order to model erosion profiles of a target, ion current density distribution from 3D Monte Carlo simulation is used to distribute total sputtering power to 5 discrete regions. At 3 kW of sputtering power and cooling water flow of 1 liter/min at $10^{\circ}C$, the maximum surface temperature was $45.8^{\circ}C$ for a flat new target and $156^{\circ}C$ for a target eroded by 1/3 of its thickness, respectively.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.280-280
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• 2012

We examined ammonia diffusion on the surface of amorphous ice film through the measurement of decreasing residual quantity of $NH_3$ molecules compared to $H_2O$. The populations of $NH_3$ molecules on the surface of amorphous ice were monitored by using the techniques of temperature programmed reactive ion scattering (TPRIS) method. The ratio of intensity between ammonia and water was examined as a function of time at controlled temperature. When ammonia molecules were externally added onto an ice film at a temperature of 80 K, ammonia coverage with regard to ice was 0.12-0.16 ML. The intensity of ammonia molecules on the surface of ice decreased as time increased and the extent of decreased intensity of ammonia increased as controlled temperature increased. Moreover, energy barrier was estimated to be $51kJmol^{-1}$ on amorphous ice film. The results of the experiment indicate that ammonia molecules have a property of vertical diffusion into amorphous ice and the energy barrier of ammonia diffusion into bulk of ice is higher than that of hydrogen bonding.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2015.11a
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• pp.347-348
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• 2015

Ni 도금 및 표면 거칠기에 따른 열전모듈의 접합강도 특성을 알아보기 위해 Bi-Te 소재 위에 Sand-blasting 방법을 사용하여 표면 거칠기를 조절하고, Ni-P 무전해 도금을 수행하였다. 접합강도 측정 및 표면 성분을 분석하기 위해 전단응력 측정기, FE-SEM을 이용하였다. Sand-blasting과 Ni 도금을 실시한 시편이 sand-blasting과 도금을 미실시한 대조군보다 전단응력이 높았고, 큰 방 수의 sand로 sand-blasting 한 시편일수록 전단응력이 더 높은 경향성을 보였다.

• Journal of Surface Science and Engineering
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• v.22 no.1
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• pp.26-42
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• 1989

It has between investigated that the optimum spaying conditions, such as, spraying distance, fusing temperature and fusing time, ect, in a Ni-cr base self fluxing alloy sprayed on the mild steel substrate by oxygen-acetylenc flame spraying. Sprayed specimens on various conditions were fuused in a vacuum furnace and the results were as follows. The optimum spraying condition for excellent coating layer are obtained under spraying distances, fusing temperature and fusing and time ; 180~240mm,1050~110$0^{\circ}C$and 15~30min, respectively. The adhesive strength and surface hurface hardness of the as sprayed specimens were very low by mechanical bonding becaus of the diffusion layer during process. The carbides and borides and formed in the sprayed coating layer and densification of the layer was resulted from the elimination of pores and oxides. The hardness of sprayed coating layer, particularly in the high temperature, was superior to ordinary tool steels.

• Journal of Surface Science and Engineering
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• v.5 no.1
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• pp.1-7
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• 1972

Copper -clad laminate(CCL) was fabricated and evaluated by bonding 35${\pm}$5${\mu}$ thick electroplated copper foils with a suitable adhesive to an insulating base such as phenolic resin laminate. In this study, electroplating methods and conditions were studied to produced good quality copper foils for printed circuit board applications. The electroplating bath solutions used were a copper-sulfate solution and a concentrated copper fluoborate solution. A surface roughening treatment that improved the adhesive strength of copper foils with an insulating laminate was also developed . A conventional copper sulfate solution containing sulfuric acid was used for the roughening treatment.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2018.05a
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• pp.283-284
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• 2018

The rear side surface of tiles act have protrusions that helps secure the adhesion between the tile and the mortar for tile setting. Conventional height of the rear side usually ranges between 1 to 1.5 mm, and the molding method is classified in between press type and compression type during the manufacturing process, with most tiles being produced by the former method. In sites where adhesion failures were observed, tiles were taken to examine the cause of defect. It was determined that height was irregular at the rear side surface. Based on these findings, an experiment was conducted to determine the correlation between the rear surface and the bonding strength of tiles.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2000.11a
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• pp.71-74
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• 2000

In this study, the optimal condition of surface treatment for aluminum panel was determined by measuring the contact angle and T-peel strength. The contact angle was measured for various mixture ratios of acetylene gas and nitrogen gas. The mixture (acetylene gas to nitrogen gas) ratios used were 1:9, 3:7, 5:5, 7:3, and 9:1. The contact angle was also measured as a function of time of surface treatment. The results showed that the contact angle was a minimum for mixture ratio of 5:5. T-peel strength was a maximum for the treatment time of 30 second.

• Journal of the Korean Magnetics Society
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• v.9 no.5
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• pp.263-270
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• 1999

The characteristics of lubricant for computer hard disk was investigated by surface analysis technique. The bonding state between carbon and lubricant is analysed to indentify the origin of adhesion. It is found that the thickness of lubricant is increased as pulling-up speed becomes faster and lubricant concentration is increased. The dominant surface contaminants on carbon overcoat are identified with C-OH and CO. The bond strength between carbon and lubricant is enhanced with heat treatment.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2003.10a
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• pp.59-59
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• 2003

In recent, various functional coatings on artificial tooth implants have been conducted to enhance the bonding strength between implants and bones. Despite of these efforts, some previous reports argued that an adhesion strength between titanium implant and the final coatings like hydroxyapatite(HA) is weaker than the strength between coating and bone. In order to increase the adhesion force between the final coating and implant surface, TiN/DLC based functionally graded coating, which has higher mechanical strength than the titanium implant, was applied as a middle layer between titanium implant and final coating. Particularly we finally coated a biocompatible hydroxyapatite film on the DLC layer and examined the mechanical properties. As a result, TiN/DLC based functionally graded coating showed the higher adhesion strength compared with hydroxyapatite single layer coating on the titanium implant.