• Computers and Concrete
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• 제21권3호
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• pp.249-259
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• 2018

The use of recycled aggregate in concrete is gaining much attention due to the growing need for sustainability in construction. In the present study, Self Compacting Concrete (SCC) is made using both natural and recycled aggregate (crushed recycled concrete aggregate from building demolished waste) and performance of recycled aggregate based SCC for the bond behaviour of reinforcement is evaluated. The major factors that influence the bond like concrete compressive strength (Mix-A, B and C), diameter of bar ($D_b=10$, 12 and 16 mm) and embedment length of bar ($L_d=2.5Db$, $5D_b$ and full depth of specimen) are the parameters considered in the present study in addition to type of aggregates (natural and recycled aggregates). The mix proportions of Natural Aggregate SCC (NASCC) are arrived based on the specifications of IS 10262. The mix proportions also satisfy the guidelines of EFNARC. In case of Recycled Aggregate SCC (RASCC), both the natural coarse and fine aggregates are replaced 100% by volume with that of recycled aggregates. These mixes are also evaluated for fresh properties as per EFNARC. The hardened properties like compressive strength, split tensile strength and flexural strength are also determined. The pull-out test is conducted as per the specifications of IS 2770 (Part-1) for determining the bond strength of reinforcement. Bond stress versus slip curves were plotted and a typical comparison of RASCC is made with NASCC. The fracture energy i.e., area under the bond stress slip curve is determined. With the use of recycled aggregates, reduction in maximum bond stress is noticed whereas, the normalised maximum bond stress is higher in case of recycled aggregates. Based on the experimental results, regression analysis is conducted and an equation is proposed to predict the maximum bond stress of RASCC. The equation is in good agreement with the experimental results. The available models in the literature are made use to predict the maximum bond stress and compare the present results.

• 한국건설순환자원학회논문집
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• 제6권3호
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• pp.174-181
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• 2018

본 연구에서는 프린트 층 사이에 부착에 초점을 두고 3D 프린팅 콘크리트의 구조거동 연구를 수행하였다. 3D 프린팅 콘크리트의 부착 및 인장강도 실험을 수행하고 일괄 타설 콘크리트 실험결과와 비교하였다. 실험변수는 콘크리트 층 사이의 프린트 시간차와 철근 보강 여부이다. 콘크리트 층 사이에는 공극이 존재하고 이에 따라, 강도 감소가 발생한다. 층 사이 대부분의 인장부착 강도 감소는 응력 집중과 프린트 시간차에 기인한다. 프린트 시간차가 24시간을 초과할 때 인장부착 강도의 감소는 구조거동에 영향을 미친다. 층 사이 철근 보강은 연성거동 증진에 유용하고 구조물의 갑작스런 파괴를 예방한다. 또한, 공극이 유발한 응력 집중에 기인한 휨 강도 감소는 횡방향 하중을 받는 3D 프린트 벽체 구조물 설계시에 고려되어야 한다.

• Structural Engineering and Mechanics
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• 제64권4호
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• pp.427-436
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• 2017

Concrete technologists have used ultrasonic pulse velocity test for decades to evaluate the properties of concrete. However, the presented research work focuses on the use of ultrasonic pulse velocity test to study the degradation in steel-concrete bond subjected to increasing loading. A detailed experimental investigation was conducted by testing five identical beam specimens under increasing loading. The loading was increased from zero till failure in equal increments. From the experimentation, it was found that as the reinforced concrete beams were stressed from control unloaded condition till complete failure, the propagating ultrasonic wave velocity reduced. This reduction in wave velocity is attributed to the initiation, development, and propagation of internal cracking in the concrete surrounding the steel reinforcement. Using both direct and semidirect methods of testing, results of reduction in wave velocity with evidence of internal cracking at steel-concrete interface are presented. From the presented results and discussion, it can be concluded that the UPV test method can be successfully employed to identify zones of poor bonding along the length of reinforced concrete beam. The information gathered by such testing can be used by engineers for localizing repairs thereby leading to saving of time, labor and cost of repairs. Furthermore, the implementation strategy along with real-world challenges associated with the application of the proposed technique and area of future development have also been presented.

• Macromolecular Research
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• 제17권8호
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• pp.591-596
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• 2009

To trace the plasticizing effects of propylene glycol (PG) on poly(vinyl alcohol) (PVA), the rheological properties of PVA solutions in dimethyl sulfoxide (DMSO) and the physical properties of PVA films were discussed in terms of PG content. Both properties were closely related to the hydrogen bond breaking effects of PG The 6 and 12 wt% PVA solutions containing PG exhibited Bingham behavior, which was more noticeable at lower plasticizer content and higher polymer concentration. The 6 wt% PVA solutions containing more than 30 wt% PG showed a sudden decrease of viscosity over the frequency range of 0.08 and 0.2 rad/s. However, the 12 wt% PYA solutions showed no viscosity reduction even at a PG content up to 40 wt%. The glass transition temperature of the PVA/PG films was almost linearly decreased with increasing PG content but an abrupt reduction was observed at a plasticizer content 30 wt%, suggesting that the hydrogen bond breaking effects of PG on PVA became dominant between 20 and 30 wt%. This effect was further supported by the similar tendency of the tensile properties.

• 한국전기전자재료학회논문지
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• 제35권4호
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• pp.366-371
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• 2022

Recently many efforts have been made to develop a novel class of non-fullerene electron acceptor materials for high-performance organic solar cells. In this work, anthraquinone derivatives, TMAQ and THAQ, were prepared and their availability as electron acceptor materials for organic solar cells were investigated in terms of optical, thermal, electrochemical properties, and solar cell devices. Compared to TMAQ, a significant bathochromic shift of absorption band was observed for THAQ owing to intramolecular hydrogen-bond-assisted CT interactions. Thanks to the fused aromatic ring structure and benzoquinone unit, both TMAQ and THAQ exhibited a high thermal stability and an efficient electron reduction process. In particular, the intramolecular O-H---O=C hydrogen bond of THAQ plays an important role in improving the thermal stability and electron reduction properties. In the P3HT:acceptor solar cell system, THAQ-based devices had more than ca. 6 times higher power conversion efficiency than TMAQ -based devices. These results serve as a guide for developing high-efficient anthraquinone-based electron acceptor materials.

• Restorative Dentistry and Endodontics
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• 제20권1호
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• pp.351-361
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• 1995

The purpose of this study was to evaluate the shear bond strength of the composite resin bonded on the bleached enamel surface according to its surface treatment. 90 extracted human premolars were divided into six groups. : enamel unbleached (control group) and enamel bleached with 15% carbamide peroxide for 2 weeks (experimental groups: 1, 2, 3, 4 and 5). The surface of bleached enamel in all experimental groups was treated by following manners. Experimental group 1 : catalase immersion for 3 mimutes. Experimental group 2 : catalase immersion for 15 mimutes. Experimental group 3 : artificial saliva immersion for 1 hour. Experimental group 4 : artificial saliva immersion for 48 hours. Experimental group 5: surface reduction of the bleached enamel about 0.5mm-1mm with superfine diamond bur. Composite resin molds(3mm height, 3mm diameter) were bonded to the untreated enamel and treated. The shear bond strengths of composite resin bonded to enamel of each specimen were tested with universal testing machine at a crosshead speed of 5mm/min and 500Kg in full scale and analyzed statistically. The following results were obtained : 1. Control group had the highest shear bond strength with $19.92{\pm}5.14$ MPa and experimental group 5 had the lowest shear bond strength with $11.15{\pm}4.23$ MPa. 2. Control group showed significant differences in shear bond strength with experimental group 1(P<0.05). 3. Control group showed significant differences in shear bond strength with experimental group 5(P<0.05). 4. Experimental group 4 showed significant differences in shear bond strength with experimental group 5(P<0.05). 5. Experimental group 3 showed no significant differences in shear bond strength with experimental group 4(P<0.05).

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 봄학술 발표회 논문집(I)
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• pp.387-390
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• 2005

Reinforcement corrosion is the principal cause of deterioration of reinforced concrete. It is to be expected that loss of bond between concrete and tension reinforcement would lead to a reduction in shear strength of RC beams designed to fail in shear. This paper presents results of a FE analysis study to evaluate the shear strength of RC beams with exposed reinforcement represented the limiting condition of bond loss.

• 대한치과교정학회지
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• 제44권1호
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• pp.44-49
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• 2014

Objective: To evaluate the effects of ultrasonic instrumentation with different scaler-tip angulations on the shear bond strength (SBS) and bond failure mode of metallic orthodontic brackets. Methods: Adhesive pre-coated metallic brackets were bonded to 72 extracted human premolars embedded in autopolymerizing acrylic resin. The teeth were randomly divided into 3 groups (n = 24 each) to undergo no treatment (control group) or ultrasonic instrumentation with a scaler-tip angulation of $45^{\circ}$ ($45^{\circ}$-angulation group) or $0^{\circ}$ ($0^{\circ}$-angulation group). SBS was tested in a universal testing machine, and adhesive remnant index (ARI) scores were recorded. The Kruskal-Wallis test and Mann-Whitney U-test were used for statistical analysis. Results: The control group had a significantly higher mean SBS value than the treated groups, which showed no significant differences in their mean SBS values. The ARI scores were not significantly different among the groups. Conclusions: Ultrasonic instrumentation around the bracket base reduces the SBS of metallic orthodontic brackets, emphasizing the need for caution during professional oral hygiene procedures in orthodontic patients. The scaler-tip angulation does not influence the SBS reduction and bond failure mode of such brackets.

• Restorative Dentistry and Endodontics
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• 제37권4호
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• pp.207-214
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• 2012

Objectives: This study evaluated the influence of chlorhexidine (CHX) on the microtensile bonds strength (${\mu}TBS$) of resin core with two adhesive systems to dentin in endodontic cavities. Materials and Methods: Flat dentinal surfaces in 40 molar endodontic cavities were treated with self-etch adhesive system, Contax (DMG) and total-etch adhesive system, Adper Single Bond 2 (3M ESPE) after the following surface treatments: (1) Priming only (Contax), (2) CHX for 15 sec + rinsing + priming (Contax), (3) Etching with priming (Adper Single Bond 2), (4) Etching + CHX for 15 sec + rinsing + priming (Adper Single Bond 2). Resin composite build-ups were made with LuxaCore (DMG) using a bulk method and polymerized for 40 sec. For each condition, half of specimens were submitted to ${\mu}TBS$ after 24 hr storage and half of them were submitted to thermocycling of 10,000 cycles between $5^{\circ}C$ and $55^{\circ}C$ before testing. The data were analyzed using ANOVA and independent t-test at a significance level of 95%. Results: CHX pre-treatment did not affect the bond strength of specimens tested at the immediate testing period, regardless of dentin surface treatments. However, after 10,000 thermocycling, all groups showed reduced bond strength. The amount of reduction was greater in groups without CHX treatments than groups with CHX treatment. These characteristics were the same in both self-etch adhesive system and total-etch adhesive system. Conclusions: 2% CHX application for 15 sec proved to alleviate the decrease of bond strength of dentin bonding systems. No significant difference was shown in ${\mu}TBS$ between total-etching system and self-etching system.

• 한국구조물진단유지관리공학회 논문집
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• 제17권6호
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• pp.112-121
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• 2013

FRP 보강근을 사용한 경량콘크리트 구조체는 부식방지 및 자중감소의 효과를 동시에 기할 수 있는 이점이 있어서 추후 그 활용이 기대될 수 있다. 그러나 경량콘크리트와 FRP 보강근을 사용하여 보강근의 내부슬립 없이 외력에 저항할 수 있는 구조체를 만들기 위해서는 경량콘크리트와 FRP 보강근 사이의 부착특성을 파악하는 것이 대단히 중요하다. 그동안 보통콘크리트와 FRP 보강근 사이의 부착거동에 대하여는 많은 연구가 있어 왔으나 경량콘크리트와 FRP 보강근 사이의 부착거동에 대하여는 현재까지 연구결과가 대단히 부족한 실정이다. 따라서 본 연구에서는 경량콘크리트와 보강근 표면에 나선형태의 이형을 갖는 GFRP 보강근 사이의 부착특성을 조사하였다. 비교목적으로 보강근 종류, 콘크리트 종류, 경량콘크리트 강도종류의 실험변수를 고려하여 인발실험체들을 제작하고 실험을 행하였다. 실험분석 결과, 보통콘크리트와 철근을 사용한 실험체의 부착강도를 1.0으로 하였을 때 경량콘크리트와 나선형태의 이형을 갖는 GFRP 보강근을 사용한 실험체의 부착강도는 0.49로 나타났다.