• Bulletin of the Korean Chemical Society
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• 제14권4호
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• pp.457-461
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• 1993

Bioconcentration factors (BCF) in fish of organic nonelectrolytes are well correlated by a linear solvation energy relationship (LSER) of the form : log BCF= -0.95 + 4.74 $V_I/100 - 4.39{\beta} + 0.88{\alpha}$ where $V_I$ is the intrinsic solute molecular volume and ${\beta}$ and ${\alpha}$ are the solvatochromic parameters that measure hydrogen bond acceptor basicity and donor acidity of the compound. The LSER model can not only correlate the property with an accuracy comparable to molecular connectivity model but also provide a quantitative informationon on the nature and relative strength of solute-target system interactions affecting the property of interest. Such an information can hardly be obtained from molecular connectivity model.

• 한국정밀공학회지
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• 제16권8호
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• pp.149-154
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• 1999

FRMLs(Fiber Reinforced Metal Laminates) is a new type of hybrid materials. FRMLs consists of high strength metal and fiber which are laminated using a structural adhesive bond(epoxy resin). The effect of resin mixture ratios on the fatigue crack propagation behavior and mechanical property of Aramid fiber reinforced aluminum composites was investigated. The epoxy, diglycidylether of bisphenol A(DGEBA) was cured with methylene dianiline(MDA) with or without accelerator(K-54). Eight kinds of resin mixture ratio were tested for the experiment ; five kinds of FRMLs(1))epoxy & curing agent) and three kinds of FRMLs(2)(epoxy & curing agent & accelerator). FRMLs(2) have a more effective characteristics on the fatigue crack propagation behavior and mechanical property than FRMLs(1)

• 접착 및 계면
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• 제11권1호
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• pp.26-34
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• 2010

가열에 의해 해체가 가능한 열적특성을 갖는 폴리우레탄 접착제를 합성하였으며 열팽창비드를 혼합하여 해체성 접착제를 제조하였다. Dynamic mechanical thermal analyzer (DMA)를 사용하여 폴리우레탄의 열적특성을 확인하였고 접착강도와 열팽창비드의 함량, 가열 trigger의 종류와 처리조건에 따른 해체특성을 연구하였다. 열풍과 microwave 처리에 의해서 해체성 폴리우레탄 접착제의 부피팽창에 따른 접착된 시편의 해체가 가능하였으며, 열팽창비드의 함량이 증가될수록 접착된 피착재가 더 쉽게 분리되었다. 해체성 접착제에서 접착력과 해체특성 모두를 만족시킬 수 있는 가장 적합한 열팽창비드 사용량은 40%이였으며, 가열 trigger로 열풍을 사용한 경우에는 $160^{\circ}C$, 30 min의 조건에서, 가열 trigger로 microwave를 사용한 경우에는 조사시간 4 min의 조건에서 접착되어 있는 피착재가 완전히 해체되었다.

• The Journal of Advanced Prosthodontics
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• 제12권3호
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• pp.157-166
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• 2020

PURPOSE. The aim of this study was to evaluate the clinical performance and reliability of plasma sprayed nanostructured zirconia (NSZ) coating. MATERIALS AND METHODS. This study consisted of three areas of analysis: (1) Mechanical property: surface roughness of NSZ coating and bond strength between NSZ coating and titanium specimens were measured, and the microstructure of bonding interface was also observed by scanning election microscope (SEM). (2) Biocompatibility: hemolysis tests, cell proliferation tests, and rat subcutaneous implant test were conducted to evaluate the biocompatibility of NSZ coating. (3) Mechanical compatibility: fracture and artificial aging tests were performed to measure the mechanical compatibility of NSZ-coated titanium abutments. RESULTS. In the mechanical study, 400 ㎛ thick NSZ coatings had the highest bond strength (71.22 ± 1.02 MPa), and a compact transition layer could be observed. In addition, NSZ coating showed excellent biocompatibility in both hemolysis tests and cell proliferation tests. In subcutaneous implant test, NSZ-coated plates showed similar inflammation elimination and fibrous tissue formation processes with that of titanium specimens. Regarding fatigue tests, all NSZ-coated abutments survived in the five-year fatigue test and showed sufficient fracture strength (407.65-663.7 N) for incisor teeth. CONCLUSION. In this study, the plasmasprayed NSZ-coated titanium abutments presented sufficient fracture strength and biocompatibility, and it was demonstrated that plasma spray was a reliable method to prepare high-quality zirconia coating.

• 한국분말재료학회지
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• 제11권5호
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• pp.412-420
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• 2004

The purpose of the present study is to determine an optimum composition using cheaper powders keeping with high performance of hard rock cutting diamond saw blade. With 50Fe-20(Cu . Sn)-30Co specimen, a part of Co was replaced by Ni(5%, 10%, and 15%, respectively). These specimens were hot pressed and sintered for predetermined time at various temperature. Sintering is performed by two different methods of temperature controlled method and specimen dimension controlled method. In order to determine the property of the sintered diamond saw blade, 3 point bending tester, X-ray diffractometer, and SEM were used. As the Co in the bond alloy was replaced by Ni, the hardness of the specimen increased. Thus the 50Fe-20(CuㆍSn)-15Co-15Ni specimen showed the maximum hardness of 104(HRB). The results of 3 point bending test showed that flexure strength decreased along with increase in Ni content. This is attributed to the formation of intermetallic compound(Ni$_{x}$Sn) determined by X-ray diffraction. The fracture surface after 3 point bending test showed that diamond was fractured in the specimen containing 0%, 5%, and 10%Ni, and the fracture occurred at the interface between diamond and matrix in the specimen containing 15%Ni. The cutting ability test showed that the abrasive property was not changed in the specimen containing 0%, 5%, and 10%Ni. The optimum composition determined in this study is 50Fe-20(CuㆍSn)-20Co-10Ni.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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• pp.109-112
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• 2008

본 연구에서는 설계강도 40${\sim}$120MPa인 3성분계 콘크리트를 대상으로 부착실험을 수행하여 혼화재 (고로슬래그)대체율과 부착파괴강도와의 관계와 콘크리트 강도와 철근의 부착응력 변화관계를 평가하였다. 부착시험체의 제작과 실험은 ASTM C-234에 준하여 수행하였으며, 혼화재인 고로슬래그 대체율이 각 시험체에 대하여 각각 0, 12, 25%이고 콘크리트 압축강도가 40${\sim}$100MPa인 경우에 대한 철근-콘크리트의 부착성능을 조사 하였다. 부착실험 결과, 압축강도가 40MPa 시험체(B-40계열)만 뽑힘파괴가 발생하였고, 나머지 시험체 (B-60${\sim}$B-120)에서 쪼갬파괴가 발생하였다. B-40 계열의 경우, UCB/EERC-83에서 제시된 부착강도 평가식의 영향 변수(${\beta}$)가 2/3 일 때 콘크리트의 압축강도의 변화에 따른 철근의 부착응력을 수렴하고 있음을 알 수 있었다. 쪼갬이 발생한 시점의 균열강도는 콘크리트 압축강도와 비례하였으며, B-60 시리즈를 제외한 각각의 압축강도 시리즈에서 고로슬래그 시멘트 대체율이 12% 이었을 경우, 그 값이 가장 크게 나타났다. 최대부착응력은 압축강도 40MPa이하일 경우 그 대체율이 12%일 때 가장 크며, 압축강도 80MPa일 경우 그 대체율이 25%일 때 가장 큰 것으로 나타났다.

• Journal of Welding and Joining
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• 제11권4호
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• pp.91-102
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• 1993

The plasma sprayed $Cr_3C_2$-NiCr coatings are widely used as wear-resistant and corrosion-resistant materials. The mechanical and wear properties of the plasma sprayed $Cr_3C_2$-NiCr coating on steel plate were examined in this study. The pore in the coatings could be classified into two types, the one is the intrinsic pore originated from the spraying powder, the other is the extrinsic pore formed during spraying. During the tensile adhesion test, the fracture occured at the interface of top coating and bond coating. It is though that the compressive residual stress increases with the increase of the top coating thickness. From the wear test, it was found that the wear rate increased with the increase of the sliding velocity regardless of the temperature. It is thought that the fracture toughness reduces with the increase of the sliding velocity at $30^{\circ}C$ and that the adhesion amount increases with the increase of the sliding velocity at $400^{\circ}C$ It is concluded that the wear mechanism at $30^{\circ}C$ is the fracture and pull-out of the carbide particles due to the fatigue on sliding surface, while the wear mechanism at $400^{\circ}C$ is the adhesion of the smeared layer formed during wear process.

• 한국염색가공학회지
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• 제17권1호
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• pp.30-37
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• 2005

The tensile properties, acetic acid solubility and degree of swelling in distilled water of cellulose/chitosan and sericin/chitosan film blended by mixing chitosan acetic acid solution with cellulose solution or sericin solution were investigated and the effect of crosslinking agent on solubility and degree of swelling were also considered. From the experimental results, the model of intermolecular bond is proposed. Tensile modulus of 100% cellulose film is high but the tensile strength and elongation are low. The elongation of 100% chitosan film is high but tensile modulus and strength is low. But it is possible to make film having same or higher tensile strength and modulus compared to that of 100% cellulose film by mixing cellulose and chitosan or by mixing sericin and chitosan. Chitosan is solved in 5vol % acetic acid solution but cellulose and sericin are not solved. Degree of swelling of chitosan in distilled water is higher than that of cellulose and sericin. Lower than 40wt% chitosan content, the solubility of cellulose/chitosan film in 5vol % acetic acid solution shows lower expected value but higher in case of sericin/chitosan film.

• Reproductive and Developmental Biology
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• 제34권3호
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• pp.117-122
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• 2010

To search the potent pig pheromonal odorants through receptor-based approach methods, molecular dockings between 680 Flavomets as substrate molecule and pig odorants binding proteins OBP (1HQP) and PBP (1GM6) as receptor, and QSPR (quantitative structure-property relationship) analyses from physico-chemical parameters of Flavomets and their docking scores (DS) were performed and discussed quantitatively. From the basis on the findings, the optimal value $(MSA)_{opt.}=407.595\;{\AA}^2$ of MSA (molecular surface area; ${\AA}$), and RB (number of rotational bond) had the Flavomets will be able to increase DS. Therefore, it is expected that the stearyl alcohol from DS and H-bond type between substrate and receptor would be shows the character as potent pig pheromonal odorant.

• Geomechanics and Engineering
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• 제20권6호
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• pp.517-525
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• 2020

The long-term stability of rock engineering is significantly affected by the time-dependent deformation behavior of rock, which is an important mechanical property of rock for engineering design. Although the hard rocks show small creep deformation, it cannot be ignored under high-stress condition during deep excavation. The inner mechanism of creep is complicated, therefore, it is necessary to investigate the relationship between microscopic creep mechanism and the macro creep behavior of rock. Microscopic numerical modeling of sandstone creep was performed in the investigation. A numerical sandstone sample was generated and Parallel Bond contact and Burger's contact model were assigned to the contacts between particles in DEM simulation. Sensitivity analysis of the microscopic creep parameters was conducted to explore how microscopic parameters affect the macroscopic creep deformation. The results show that the microscopic creep parameters have linear correlations with the corresponding macroscopic creep parameters, whereas the friction coefficient shows power function with peak strength and Young's modulus, respectively. Moreover, the microscopic parameters were calibrated. The creep modeling curve is in good agreement with the verification test result. Finally, the creep curves under one-step loading and multi-step loading were compared. This investigation can act as a helpful reference for modeling rock creep behavior from a microscopic mechanism perspective.