• 제목/요약/키워드: boiling point

검색결과 331건 처리시간 0.024초

Bi2O3-Al2O3-SiO2 유리의 열물성과 내플라즈마 특성 연구 (A Study on the Thermal Properties and Plasma Resistance of Bi2O3-Al2O3-SiO2 Glass)

  • 변영민;최재호;임원빈;김형준
    • 반도체디스플레이기술학회지
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    • 제22권1호
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    • pp.64-71
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    • 2023
  • In this study, we investigated the effects of BiAlSiO glass composition on its glass forming range, thermal properties, and plasma resistance. The results showed that increasing the Al2O3 content suppressed the tendency for crystallization and hindered glass formation beyond a certain threshold. Bi2O3 was found to increase the content of non-bridging oxygen, resulting in a decrease in glass transition temperature and an increase in thermal expansion coefficient. Furthermore, the etching rate was found to improve with increasing Al2O3 content but decrease with increasing SiO2 content. It was concluded that the boiling point of fluorinated compounds should be considered to 900℃. Therefore, this study is expected to contribute to the understanding of the properties of BiAlSiO glass and its application to low temperature melting PRG compositions.

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EFFECT OF Mg RATIO ON THE EXTRACTION OF Dy FROM (Nd,Dy)-Fe-B PERMANENT MAGNET USING LIQUID Mg

  • SANGMIN PARK;SUN-WOO NAM;JU-YOUNG CHO;SANG-HOON LEE;SEUNG-KEUN HYUN;TAEK-SOO KIM
    • Archives of Metallurgy and Materials
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    • 제65권4호
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    • pp.1281-1285
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    • 2020
  • Recently, since the demand of rare earth permanent magnet for high temperature applications such as an electric motor has increased, dysprosium (Dy), a heavy rare earth element, is becoming important due to severe bias in its production. To fulfill the increasing need of Dy, recycling offers as a promising alternative. In recycling of rare earths, Hydro-metallurgical extraction method is mainly used however it has adverse environmental effects. Liquid metal extraction on the other hand, is an eco-friendly and simple method as far as the reduction of rare earth metal oxide is concerned. Therefore, liquid metal extraction was studied in this research as an alternative to the hydro-metallurgical recycling method. Magnesium (Mg) is selected as solvent metal because it doesn't form intermetallic compounds with Fe, B and has a low melting and low boiling point. Extraction behavior of Dy in (Nd,Dy)-Fe-B magnet is observed and effect of Mg ratio on extraction of Dy is confirmed.

"고사십이집(攷事十二集)"의 조리가공에 관한 분석적 연구(2) (A Study on the Cooking in 'The Kosa-sibi Jip' (2))

  • 김성미
    • 동아시아식생활학회지
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    • 제4권3호
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    • pp.1-19
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    • 1994
  • In this paper, twenty-five kinds of food presented in Sooljip(戌集) 5 and 6 of Food collections of 'Kosa-sibi Jip(攷事十二集)' have been classified into four : Staple food, subsidiary food, Tuck(rice cake) and Han-gwa(Korean confectionery), and Tang-jng and tea. Cooking processes have been examined and scientifically analyzed in terms of cooking, Fourteen kinds of Jook (thick gruel with cereal) as well as Urak-Jook were presented among the methods of making Jook, one of staple foods. Milk and ground rice were boiled together into Urak-Jook, which was nutritious because of carbohydrate, added to milk. Hong-sa Myun was mode of ground shrimps, ground bean, ground rice and flour which were kneaded together. It was a nutritiously balanced food. Nineteen kinds of Kimchi presented in this book were classified by the recipes. The five of Jook-soon Ja, U-so Ja, Tam-bok Ja and Jo-gang were made by adding red malt and cereals(boiled rice or candies). Jo-gang, Jo-ga and Jo-gwa-chae were made by adding salt and rice wine. With salt and fermenters added, eight were made. Chim-jup-jeo-ga was made by adding Jang(soy-bean sauce) and the inner chaff of wheat instead of salt. The four of Ka-za-san, Hwang-gwa-san, Tong-gwa-san and Jo-gang were made by adding salt and vinegar. Jo-gang was made by adding salt, rice wine, residue of rice wine and candies. The four of Kae-mal-ga, Ku-cho-chim-chae, Un-gu-hwa and Suk-hwa-chim-chim-chae were made by adding salt and spices. San-got-Kimchi was made without salt. San-got-Kimchi and Suk-hwa-chim-chae were made originally in Korea. Suk-hwa-chim-chae, in particular, was first classified as a kind of Kimchi in this book and oysters were added, which is notable. Pork could be preserved longer when smoked oven the weak fire of thatch ten days and nights. Dog meat was sauced and placed on the bones in a pot. A porcelain was put on the top of the pot. Flour paste sealed the gap between the porcelain and the pot. Some water was poured into the porcelain, and the meat was steamed, with two or three thatched sacks burned, which was a distilled dry steaming. This process has been in use up to now. Various cooking methods of chicken were presented from in Umsik-dimi-bang to in Chosun Musang Sinsik Yori Jebup. These methods were ever present regardless of ages. Such measuring units as Guin(斤) and Nyang(兩) were most frequently used in cooking processes of this book, except in case of Jang(soy bean sauce), vinegar and liquor. Twenty eight kinds of kitchenware and cookers were used, of which porcelains wee most used and pans and sieves followed. The scientific eight cooking methods were as follows. First, salt was refined through saturated solution. Next, it was recommended Hong-sa Myun containing shrimps should not be taken along with pork, which is thought to be a proper diet in terms of cholesterol contained by shrimps and pork. Third, meat was coated with thin gruel and quickly roasted and cleared of the dried gruel membrane, which prevented nutrients from exuding and helped to make the meat well-done. Fourth, The fruit of paper mulberry trees has the protease which can soften meat. Therefore when meat was boiled with th fruit of paper mulberry trees, it can be softened easily. Fifth, pork was smoked over the weak fire of thatch. Sixth, in cooking dog meat, distilled dry steaming raised the boiling point and made it possible to preserve meat longer. Seventh, in boiling the sole of a bear, lime was added, which made meat tender by making the pH lower or higher than that of raw meat. Finally, in boiling down rice gluten, a porcelain in the pot prevented boiling over the brim, which is applied to pots in which to boil medical herbs.

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가열기구에 따른 조리방법이 돼지고기의 품질특성에 미치는 영향 (Effect of Cooking Methods with Various Heating Apparatus on the Quality Characteristics of Pork)

  • 전기홍;권기현;김은미;김영붕;최윤상;손동인;최진영
    • 한국조리학회지
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    • 제21권1호
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    • pp.1-14
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    • 2015
  • 본 연구에서는 돼지고기 삼겹살과 목살의 가열처리방법에 따른 새로 개발된 PCM 처리와 이중팬을 제작하여 사용하였으며, 기존의 가열조리방법과 비교하여 이화학적 특성과 관능특성을 비교하였다. 돼지고기 삼겹살과 목살의 수분함량은 찌기처리구에서 60.2%, 67.2%로 높게 나타났으며, 조지방은 삼겹살은 숯불처리구에서 33.2%, 목살은 전기그릴처리구에서 16.0%로 가장 높았다(p<0.05). 조단백질의 경우, 삼겹살은 스팀처리구가 18.4%로 높았고, 삶기처리구는 15.4%로 유의적으로 낮았다. 또한, 목살은 전기그릴처리구에서 25.2%로 유의적으로 높게 나타났다(p<0.05). 보수력과 가장 관계가 깊은 가열감량은 삼겹살과 목살 모두에서 숯불구이처리구 40.18%, 36.98%로 유의적으로 높았고, 전단력에서 삼겹살은 오븐처리구에서 $2.76kg/cm^2$으로 목살은 이중 팬처리구에서 $3.67kg/cm^2$으로 가장 낮았다(p<0.05). 육색 시험결과 L값은 삶기처리구에서 65.16, 59.72로 가장 높았고(p<0.05) b 값의 경우, 삼겹살은 삶기처리구에서 2.32로 가장 낮았다(p<0.05). 관능평가 결과 전체적인 기호도 항목에서 삼겹살의 경우, 전기그릴처리구에서 7.56점으로 높았다. 목살은 팬구이처리구에서 7.22점으로 가장 높았으며, 반면, 삶기처리구에서 5.88점으로 가장 낮았다(p<0.05).

테라헤르츠 분광학을 이용한 중수(D2O)와 경수(H2O) 혼합물의 특성연구 (Terahertz Characteristics of D2O and H2O Mixtures)

  • 정중건;손주혁
    • 한국광학회지
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    • 제19권6호
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    • pp.435-438
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    • 2008
  • 중수($D_2O$, 산화중수소)는 수소원자(H)보다 중성자 한 개가 더 많은 수소원자 동위원소(D)로 이루어진 물이다. 중수는 자연 상태의 물 가운데 5만분의 1정도 존재하며 경수($H_2O$)와 매우 비슷한 성질을 가지고 있으나 경수보다 11%정도 무겁고, 특이점은 235 K로 228 K인 경수와 약간의 차이를 가진다. 중수는 중성자를 흡수하여 원자로의 중성자 감속재로 쓰이고 최근 중수 농도에 따라 세포에 미치는 독성효과가 다르게 나타나는 현상이 발견 되어 암 치료에 사용하려는 연구가 진행되고 있다. 우리는 테라헤르츠 시간축 분광학을 이용하여 경수와 중수 혼합물의 농도별 굴절률과 흡수율 변화를 거대 분자간 결합에너지 영역을 포함하는 테라헤르츠 영역 ($0{\sim}2.5\;THz$)에서 측정하여 중수의 비율이 높을수록 굴절률은 감소하고 흡수율 또한 감소하는 결과를 얻었다.

초등학교 급식의 비빔밥 생산과정에 따른 미생물적 품질평가 (Microbiological Quality Assessment of Bibimbap Production Flow in Elementary School Foodservice)

  • 김복란;채순주
    • 대한가정학회지
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    • 제43권2호
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    • pp.19-31
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    • 2005
  • The purpose of this study was to evaluate the microbiological quality and assure the hygienic safety of the Bibimbap production in elementary school foodservice in accordance with the HACCP(Hazzard Analysis Critical Control Point) program. The time-temperature relationship and the microbiological quality(total plate count and coliform bacteria count) were assessed to find the critical control point(CCP) during each of the production phase. In the pre-preparation phase, the risk factors of the raw ingredients exceeded the standard level suggested by Solberg et al. Mungbean starch jelly, egg and Kochujang were satisfactory in that no coliform groups were observed over the standard TPC level. In particular, there was a high the risk of beef from the early stages in terms of the coliform level. In the pre-preparation phase, green pumpkin had more coliform groups than the standard level even after washed, which calls for special attention to washing, sterilization, secondary infection of the handler, and the required time for pre-preparation of raw vegetables. In the cooking phase, the temperature of the soybean sprout and mungbean starch jelly decreased to 42$^{\circ}C$ and 26$^{\circ}C$, respectively, which was within the risk zone. In particular, mungbean starch jelly had a great risk factor even after boiling in hot water. During the storage stage before serving, a lot of ingredients were exposed to poor management of temperature and time and thus exceeded the standard level in the total plate counts. In particular, the microbiological count of beef was five times the standard level. Green pumpkins and soybean sprouts were left at 15-38$^{\circ}C$ that is within the risk zone for a long period of time after they were cooked. It is highly recommended that the time of the storage stage before consumption should be shortened and that proper devices should be used to prevent proliferation of bacteria. The number of TPC of the utensils was satisfactory enough, but the knife used exceeded the standard level and thus was a risk factor of bacteria proliferation.

N,N’-Bis(diphenyl phosphoro)diaminohexane의 합성과 PET 직물에 대한 방염성에 관한 연구 (Studies on Synthesis of N,N’-Bis(diphenyl phosphoro)diaminohexane and Flame Retardancy Effects of BDPDH on PET Fabrics.)

  • 이광우;허만우;윤종호;이창섭;조용석;김삼수;조환
    • 한국염색가공학회지
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    • 제6권2호
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    • pp.55-62
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    • 1994
  • The mend for fabric products has been increased remarkably with increasing population, housings, mutistory buildings,...and etc. during the last two decades. However, since fabrics are highly combustible and can produce toxic gases during the combution, fabric products can result in serious human injury as well as financial damage. Acknowledged by this, a new phosphorus based flame retardant suitable for PET fabric has been synthesized by making use of the reaction of diphenyl chloro phosphate and hexamethylenediamine. Since the starting meterials are relatively cheap and the yield of this reaction is high (more than 90%), this reaction seems to be very effective as wall as very economic. By analyzing various spectrophotometric analysis data such as NMR, FT-IR, and Mass, this new flame retardant is identified to be N,N’-Bis(diphenyl chlorophosphoro)diamino hexane. In the mean time, DSC measurement has shown that the melting point and the boiling point of this material are around 115$^{\circ}C$ and around 40$0^{\circ}C$, respectively. The flame retardancy test done on the PET fabric processed by this flame retardant have shown excellent in times of flame contact, times of flame contact for washable. The most economical finishing condition estimated 10% in concentration of BDPDH, Moreover, it has been also found that the drape stiffness of the PET fiber processed by the flame retartant is changed very litter compared to the unprocessed original PET fabrics. Judging from this, the potential of this new phosphrdus based compond as a flame retardant for PET fabric seems to be high.

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합성피혁제조업에서 취급하는 DMF, MEK, Toluene의 단일과 혼합물질 상태에 따른 물리·화학적 특성 변화 (Changes in Physico-chemical Properties of Single or Mixture State of DMF, MEK and Toluene in Synthetic Leather Factories)

  • 김기웅;원용림;박동진;이정석;한인수;이수희
    • 한국산업보건학회지
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    • 제24권2호
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    • pp.238-245
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    • 2014
  • Objectives: It was known that workers in synthetic leather company are mainly co-exposed to dimethylformamide(DMF) with methyl ethyl ketone(MEK) or toluene(TOL) instead of a single dimethylformamide. This study was examined to the physico-chemical properties in single DMF and binary mixture DMF with MEK or TOL. Materials: Physico-chemical properties were measured by Korean and American Standard Test Methods. Results: Boiling point, specific gravity and flash point in single DMF were significantly higher than binary mixture DMF with MEK or TOL and such difference was dependent on the mixing ratio of MEK and TOL, and low explosion limit in binary mixture DMF with TOL was only significantly lower than single DMF. However, Reid vapor pressure had significantly higher in binary mixture DMF with MEK or TOL compared with single DMF. Conclusions: Our results demonstrate that the binary mixture DMF with MEK or TOL synergistically increases volatilization of DMF. It was concluded that the interaction between DMF and MEK and/or TOL might play a key role in the volatilization process of DMF under environmental conditions of workplace.

개념 변화 수업에서 협동학습 환경이 학생들의 인지적, 정의적 결과에 미치는 효과 (The Effect of Cooperative Learning Environments in Conceptual Change Instruction on Students' Cognitive and Affective Outcomes)

  • 한재영;정은희;노태희
    • 한국과학교육학회지
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    • 제25권5호
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    • pp.555-562
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    • 2005
  • 이 연구에서는 개념 변화 수업에서 협동적 학습 환경의 효과를 개념 이해도, 성취도, 과학 학습 동기, 과학 수업에 대한 태도 및 수업 참여도에 대한 인식 측면에서 조사하였다. 1개 남녀 공학 중학교의 2학년 2개 학급을 비교 집단과 처치 집단으로 각각 배치하고, '물질의 특성' 단원의 밀도, 끓는점, 어는점, 용해도에 대하여 11차시 동안 수업을 실시하였다. 처치집단에서는 협동적 개념 변화 수업을 실시하였고, 비교 집단에서는 개별적 개념 변화 수업을 실시하였다. Mann-Whitney Test 결과, 처치 집단의 개념 검사 점수와 성취도 검사 점수가 비교 집단에 비해 유의미하게 높았으며, 처치 집단의 수업 참여도에 대한 인식이 비교 집단에 비해 더 긍정적인 것으로 나타났다. 이원 공변량 분석 결과, 처치 집단의 학습 동기 검사 점수가 비교 집단에 비해 유의미하게 높았으나, 과학 수업에 대한 태도에서는 두 집단 간에 유의미한 차이가 나타나지 않았다.

Combined Toxic Effects of Polar and Nonpolar Chemicals on Human Hepatocytes (HepG2) Cells by Quantitative Property - Activity Relationship Modeling

  • Kim, Ki-Woong;Won, Yong Lim;Park, Dong Jin;Kim, Young Sun;Jin, Eun Sil;Lee, Sung Kwang
    • Toxicological Research
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    • 제32권4호
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    • pp.337-343
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    • 2016
  • We determined the toxicity of mixtures of ethyl acetate (EA), isopropyl alcohol (IPA), methyl ethyl ketone (MEK), toluene (TOL) and xylene (XYL) with half-maximal effective concentration ($EC_{50}$) values obtained using human hepatocytes cells. According to these data, quantitative property-activity relationships (QPAR) models were successfully proposed to predict the toxicity of mixtures by multiple linear regressions (MLR). The leave-one-out cross validation method was used to find the best subsets of descriptors in the learning methods. Significant differences in physico-chemical properties such as boiling point (BP), specific gravity (SG), Reid vapor pressure (rVP) and flash point (FP) were observed between the single substances and the mixtures. The $EC_{50}$ of the mixture of EA and IPA was significantly lower than that of contained TOL and XYL. The mixture toxicity was related to the mixing ratio of MEK, TOL and XYL (MLR equation $EC_{50}=3.3081-2.5018{\times}TOL-3.2595{\times}XYL-12.6596{\times}MEK{\times}XYL$), as well as to BP, SG, VP and FP (MLR equation $EC_{50}=1.3424+6.2250{\times}FP-7.1198{\times}SG{\times}FP-0.03013{\times}rVP{\times}FP$). These results suggest that QPAR-based models could accurately predict the toxicity of polar and nonpolar mixtures used in rotogravure printing industries.