• Title/Summary/Keyword: blending effect

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Mechanical Property Enhancement of Water Soluble Polymer Pouch for Ground Reinforcement (지반함몰 긴급복구용 수용성 폴리머 파우치의 기계적 물성강화)

  • Jung, Dongho;Chung, Dasom;You, Seung-Kyong;Kim, Joo-Hyun;Han, Jung-Geun
    • Journal of the Korean Geosynthetics Society
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    • v.16 no.4
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    • pp.221-230
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    • 2017
  • We developed a polymer pouch using PVP that is water soluble in the precedent study. Yet melt viscosity was so low that it was not possible to produce hemispheric type which is essential for mass production, therefore we used another material to make the polymer pouch. It enabled to figure out a water-soluble transition and mechanic physical property of PEG that is newly chosen, and to blend the PEG with LLDPE and TALC followed by result. So, we could implement an evaluating property on blended proportion. It is important to find out a proper blending ratio throughout an experiment since its property is different or varied followed by each proportion as a water soluble character is conflict to a solid character. With the blending technique we were able to produce the polymer pouch enhanced for a tensile force and an impact intensity maintaining a water soluble character. We could identify a ground solidity effect of the polymer pouch as a result of a direct shear test using the product developed.

Adhesion Properties of Rubber Composite with Direct Blending Technique and Adhesive Composition (직접블렌딩 기술과 접착제 조성이 고무복합체 물성에 미치는 영향)

  • Lee, Seong-Jae;Chang, Young-Wook;Chung, Kyung-Ho
    • Elastomers and Composites
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    • v.34 no.3
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    • pp.253-261
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    • 1999
  • The cure properties of rubber compounds containing different adhesive compositions were examined. As the amounts of tannin were increased in the adhesive composition, the scorch time was increased and cure rate was decreased due to the size and shape of tannin molecules. Also, the effect of adhesive composition on the adhesion between rubber and fiber was examined by TCAT(Tire Cord Adhesion Test), The reinforcing cords used in this study were mon ofilaments of nylon 610 and nylon 66. According to the results, the optimum adhesion strength between rubber and fiber could be obtained with adhesives whose molar ratios of formaldehyde/resorcinol were above 5/1 in the recipes. Although the level of dip pick-up(DPU) on the reinforcing cord affects the adhesion strength, the DPU of nylon 610 monofilament did not affect the adhesion strength because the level of DPU was constant regardless of the adhesive compositions. In this case, the adhesion strength with the adhesive composition could be explained with the behavior of tannin in the adhesive.

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Characteristics of Pitch Production of Pyrolyzed Fuel Oil/Coal-tar Blending Feedstock by Thermal Polymerization Reaction (Pyrolyzed Fuel Oil/Coal-tar 혼합원료의 열중합 반응에 따른 Pitch 제조 특성)

  • Lee, Eunbyul;Kim, Hyeong Gi
    • Applied Chemistry for Engineering
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    • v.31 no.3
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    • pp.328-333
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    • 2020
  • In this study, blended feedstock derived pyrolyzed fuel oil (PFO) and coal-tar was prepared to produce a pitch by thermal polymerization reaction for manufacturing artificial graphite materials. The aromaticity value of 0.355 and 0.818 was obtained for PFO and coal-tar, respectively. In addition, PFO and coal-tar exhibited the difference tendency of weight loss curve for thermogravimetric analysis, which is related to the structural stability depending on the aromaticity and functional groups. The production characteristics confirmed that the pitch derived PFO showed lower production yield and higher softening point than that using blended feedstock. In particular, when comparing P360 (138.5 ℃) and B420 (141.4 ℃) having similar softening points, the production yields of both pitches exhibited 29.89 and 49.03 wt%, respectively. This is mainly due to the blending of PFO and coal-tar having high pitch polymerization reactivity including a large amount of alkyl groups and coal-tar having high thermal stability. This phenomenon indicated that the increased production yield is because of a synergic effect of both the high reactivity of PFO and thermal stability of coal-tar.

Effects of the repetitive tasting of different blending types of coffee on teeth stain during home bleaching (자가 미백 처치 기간 중 커피 종류별 적용이 치아 착색에 미치는 영향)

  • Kim, Eun-Hee;Lee, Dong-Hyun;Oh, Hye-Seung
    • Journal of Korean society of Dental Hygiene
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    • v.10 no.6
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    • pp.955-963
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    • 2010
  • Objectives : The purpose of this study was to examine effect of the application of different types of coffee on teeth stain during home bleaching. Methods : Twenty five premolars that were extracted within the past month and healthy without any signs of dental caries or restorations were collected and divided into five groups. The teeth of a control group were bleached everyday for two weeks, and the teeth of four experimental groups were bleached everyday for two weeks and then deposited respectively in four different types of coffee solution: brewed coffee, black coffee, coffee with sugar, and coffee with sugar and cream. Afterwards, the color of the teeth of the four experimental groups was checked by a shade pilot. Results : As a result, there were significant differences in the change of lightness and color according to the blending type with the lapse of time during home bleaching. Concerning changes in lightness and hue, there were the largest differences in the control group and the experimental group deposited in coffee with sugar and cream, followed by coffee with sugar, black coffee and brewed coffee. When the extent of change in lightness and hue was investigated after home bleaching, the experimental group deposited in coffee with sugar and cream was stained the least, and the experimental group deposited in brewed coffee was stained the most. Conclusions : In conclusion, the intake of coffee that is the cause of stain should be reduced during bleaching, and in case of having a cup of coffee, it's advisable to have coffee with cream.

The Effect of Polymer Blending and Extension Conditions on the Properties of Separator Prepared by Wet Process for Li-ion Secondary Battery (고분자 블렌딩 및 연신조건이 리튬 이온전지용 습식 Separator의 물성에 미치는 영향)

  • 문성인;손영수;김순식;김진열
    • Polymer(Korea)
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    • v.26 no.1
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    • pp.45-52
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    • 2002
  • The separator made from the blends of high density polyethylene (HDPE) and ultrahigh molecular weight polyethylene (UHMWPE) was prepared by wet processing to use as Li-ion secondary battery. We investigated effects of the blending of the polymers and the film extension on the mechanical properties of the separator. The mechanical strength of separator increased with increasing molecular weights and contents of UHMWPE, for instance about $1000 kg/\textrm{cm}^2$ with the five times extended film of 6 wt% UHMWPE. The pores of the separator were very uniform with the size of 0.1~$0.12\mu\textrm{m}$. The shut-down characteristic quickly increased at around $130^{\circ}C$ and the fusion temperature was $160^{\circ}C$, so it could be applied to the lithium ion secondary battery.

EVA/Clay Nanocomposite by Solution Blending: Effect of Aluminosilicate Layers on Mechanical and Thermal Properties

  • Pramanik, M.;Srivastava, S.K.;Samantaray, B.K.;Bhowmick, A.K.
    • Macromolecular Research
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    • v.11 no.4
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    • pp.260-266
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    • 2003
  • Ethylene vinyl acetate (EVA)/clay nanocomposites were synthesized by blending a solution of ethylene vinyl acetate copolymer containing 12% vinyl acetate abbreviated as EVA-12 in toluene and dispersion of dodecyl ammonium ion intercalated montmorillonite (l2Me-MMT) in N,N-dimethyl acetamide (DMAc). X-ray patterns of sodium montmorillonite ($Na^+$-MMT) and 12Me-MMT exhibited $d_{001}$ peak at $2{\theta}=7.4^{\circ}$ and $2{\theta}=5.6^{\circ}$ respectively; that is, the interlayer spacing of MMT increased by about 0.39 nm due to intercalation of dodecyl ammonium ions. The XRD trace of EVA showed no peak in the angular range of $3-10^{\circ}(2{\theta})$. In the XRD patterns of EVA/clay hybrids with clay content up to 6 wt% the basal reflection peak of 12Me-MMT was absent. leading to the formation of delaminated configuration of the composites. When the 12Me-MMT content was 8 wt% in the EVA-12 matrix, the hybrid revealed a peak at about $2{\theta}=5.6^{\circ}$, owing to the aggregation of aluminosilicate layers. Transmission electron microscopic photograph exhibited that an average size of 12-15 nm clay layers were randomly and homogeneously dispersed in the polymer matrix, which led to the formation of nanocomposite with delaminated configuration. The formation of delaminated nanocomposites was manifested through the enhancement of mechanical properties and thermal stability, e.g. tensile strength of an hybrid containing only 2 wt% 12Me-MMT was enhanced by about 36% as compared with neat EVA-12.

Comparison study of the effect of blending method on PVDF/PPTA blend membrane structure and performance

  • Li, Hongbin;Shi, Wenying;Zhang, Yufeng;Zhou, Rong
    • Membrane and Water Treatment
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    • v.6 no.3
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    • pp.205-224
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    • 2015
  • A novel hydrophilic poly (vinylidene fluoride)/poly (p-phenylene terephthalamide) (PVDF/PPTA) blend membrane was prepared by in situ polycondensation of p-phenylene diamine (PPD) and terephthaloyl chloride (TPC) in PVDF solution with subsequent nonsolvent induced phase separation (NIPS) process. For comparison, conventional solution blend membrane was prepared directly by adding PVDF powder into PPTA polycondensation solution. Blend membranes were characterized by means of viscometry, X-ray photoelectron spectroscopy (XPS), Field Emission Scanning Electron Microscopy (FESEM). The effects of different blending methods on membrane performance including water contact angle (WCA), mechanical strength, anti-fouling and anti-compression properties were investigated and compared. Stronger interactions between PVDF and PPTA in in situ blend membranes were verified by viscosity and XPS analysis. The incorporation of PPTA accelerated the demixing rate and caused the formation of a more porous structure in blend membranes. In situ blend membranes exhibited better hydrophilicity and higher tensile strength. The optimal values of WCA and tensile strength were $65^{\circ}$ and 34.1 MPa, which were reduced by 26.1% and increased by 26.3% compared with pure PVDF membrane. Additionally, antifouling properties of in situ blend membranes were greatly improved than pure PVDF membrane with an increasing of flux recovery ratio by 25%. Excellent anti-compression properties were obtained in in situ blend membranes with a stable pore morphology. The correlations among membrane formation mechanism, structure and performance were also discussed.

Physical Properties of Rigid Polyurethane Foams Prepared by Co-Blowing Agents (Co-blowing agent에 따른 경질 폴리우레탄 폼의 물성 변화 연구)

  • Kim Sang Bum;Koh Sung Ho
    • Journal of the Korean Institute of Gas
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    • v.8 no.2 s.23
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    • pp.1-7
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    • 2004
  • The physical properties of rigid polyurethane foam(PUF) synthesized using various types of blowing agents such as water, HFC-365mfc, HFC-245fa, HCFC-l4lb, CFC-11 and n-pentane were studied. The blending effect of blowing agents were also studied. The thermal conductivity, reaction rate, and cell morphology of the PUF with various blending ratio of blowing agents were investigated. The PUF blown by water shows the highest compressive strength among other single blowing agents. The thermal conductivity of PUFs blown by HFC-245fa and HFC-365mfc are close to that of PUFs blown by CFC-11. When HFC-365mfc was mixed with HFC-245fa(30mo1e$\%$) as coblowing agent, the mechanical property shows the highest value among other coblowing agents. It is that the thermal conductivity of PUFs depends on cell size of PUFs as well as thermal conductivity of blowing agent in gaseous form.

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Physicochemical Properties of Root Zone Soil Based on Sand Blending with Coconut Coir and Peat Moss (코코넛 코이어와 피트모스 혼합 모래 토양의 물리·화학적 특성)

  • Kim, Young-Sun;Bae, Eun-Ji;Choi, Mun-Jin;Kim, Tae-Wooung;Lee, Geung-Joo
    • Korean Journal of Environmental Agriculture
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    • v.41 no.2
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    • pp.101-107
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    • 2022
  • BACKGROUND: Soil amendment was necessary applied for the sand that had been used to root zone of green ground in golf course because of its low water retention power and cation exchangeable capacity. This study was conducted to evaluate the effect of the mixed ratio of peat moss and coconut coir as soil amendment materials on the soil physicochemical properties applied to rootzone based on sand. METHODS AND RESULTS: The soil amendments were blended at 0, 3, 5, 7 and 10% by soil volume. The pH in the peat moss treatment was lower than that of control (0% soil amendment), and pH and electrical conductivity (EC) in the coconut coir were higher. The blending ratio of peat moss was negatively correlated with pH of rootzone soil (p<0.01), and that of coconut coir positively with EC (p<0.01). As compared with control, capillary porosity, the physical factors such as air-filled porosity, total porosity, and hydraulic conductivity of rootzone soil were increased by applying peat moss and coconut coir. For correlation coefficients between percentage of soil amendments and soil physical factors, peat moss and coconut coir were positively correlated with porosity and hydraulic conductivity (p<0.01). CONCLUSION(S): These results indicated that the application of peat moss and coconut coir affected on the change of physicochemical properties of rootzone soil, and improved soil porosity and hydraulic conductivity.

Assessment of flexural performance of hybrid fiber reinforced concrete. (하이브리드 섬유보강 콘크리트의 휨성능 평가)

  • Kim, Hag-Youn;Kim, Nam-Ho;Park, Choon-Gun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.337-340
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    • 2005
  • In this study, an effect of fiber blending on material property of Hybrid Fiber Reinforced Concrete (HFRC) was evaluated. Also, Compare and evaluates collating and mechanical property by the mixing rate of fiber for HFRC was determine. Modulus of rupture and strength effectiveness of Hybrid Fiber Reinforced Concrete mixed with macro-fiber(steel fiber) and micro-fiber(glass fiber, carbon fiber, cellulose fiber). Test result shows, in the case of mono fiber reinforced concrete. As the steel fiber mixing rate increases to 1.5$\%$, the strength effectiveness promotion rate rises. However, when is 2.0$\%$, strength decreases. In the case of hybrid fiber reinforcement concrete, synergy effect of micro fiber and macro fiber happens and higher Modulus of rupture and strength effectiveness appears than mono-fiber reinforcement concrete. Use of hybrid fiber reinforcement in concrete caused a significant influence on its fracture behavior; consequently, caused increase by mixing rate of steel fiber + carbon fiber and contributed by steel fiber + glass fiber, steel fiber + celluloid fiber in reinforcement effect in order. And was expose that steel fiber(1.5$\%$) + carbon fiber(0.5$\%$) is most suitable association.

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