• Bulletin of the Korean Chemical Society
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• 제33권2호
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• pp.703-706
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• 2012

• 한국세라믹학회지
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• 제51권1호
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• pp.7-10
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• 2014

Abalone shell is composed of 95 wt% $CaCO_3$ platelets and 5 wt% of a protein-rich organic matrix which acts as an adhesive layer, connecting aragonite tablets, thus maintaining the structural integrity of the composite. By mimicking abalone shell, we prepared a silicate plate/polymer nanocomposite by infiltrating PMMA between silicate layers and warm-pressing them at $200^{\circ}C$ for 1 h under 15 tons to make organic-inorganic composite materials. To examine the organic-inorganic composite materials after the warm-pressing procedure, the composite sample was analyzed with FE-SEM and TG. The bending strengths and densities of the composites prepared by a silicate plate and PMMA after the warm-pressing process were ~140 MPa and 1.5, respectively.

• Journal of the Korean Wood Science and Technology
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• 제36권2호
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• pp.46-55
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• 2008

This study assesses the formaldehyde and TVOC emissions from bio-composites with attached fancy veneer manufactured using wood flour and polypropylene (PP) measured using the Field and Laboratory Emission Cell (FLEC) method and 20 L small chamber method. To determine and compare the effects of the adhesive, samples were prepared with different manufacturing methods. In the FLEC result, the formaldehyde emission level of the bio-composites with attached veneer by hot-press was the lowest than pure bio-composite and bio-composite attached veneer using adhesive. The TVOC emission levels are similar to the formaldehyde emission. The TVOC emission level is very low in all of the samples except fancy veneer that is attached with bio-composites using adhesive. The TVOC emission varies depending on how attaching fancy veneer. The results of the 20 L small chamber method were very similar to those obtained with the FLEC, but the correlation was not perfect. However, the FLEC method requires a shorter time than the 20 L small chamber method to measure the formaldehyde and TVOC emissions. The internal bonding strength exceeded the minimum value of $0.4N/mm^2$ specified by the KS standard. All of the bio-composites with attached veneer satisfied the KS standard.

• Elastomers and Composites
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• 제52권4호
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• pp.280-286
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• 2017

The mechanical and dynamic properties according to the content of filler, plasticizer, and crosslinking agent of rubber composites for Lipseal were measured in this study. The mechanical properties of the composite including the silane coupling agent and silica were found to be superior to those of the composite containing carbon black. It was found that the rebound resilience characteristics were influenced by the crosslink density of sulfur rather than the filler or plasticizer. In the case of recovery, it was confirmed that the elastic restoring force improved in the compression deformation condition and recovery increased as the crosslinking density increased. The rubber composite for Lipseal of this study is expected to improve the manufacturing technology of the rubber composite which can implement the optimum function for recognizing the performance such as oil resistance, durability and compression set.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.359-359
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• 2006

This study deals with development of new bio-based polymeric materials from epoxidized soybean oil (ESO). The curing of ESO in the presence of organophilic montmorillonite produced an oil polymer-clay nanocomposite ("green nanocomposite") showing flexible property. A green nanocomposite (oil polymer-silica nanocomposite) coatings were synthesized by an acidcatalyzed curing of ESO with 3-glycidoxypropyltrimethoxysilane. The curing of ESO in the presence of a biodegradable plastic, poly(caprolactone), produced a composite with semi-IPN structure. The mechanical properties of the composite was much superior to those of polyESO. These new oil-based materials have large potential for applications in various fields.

• Elastomers and Composites
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• 제50권4호
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• pp.258-264
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• 2015

Rubber composites were prepared by precured CIIR pulverized at knead shear force in order to research the effects of the BR/PCP composites. The particle size of domain in BR/CIIR composites was decreased and homogeneously dispersed by the precured CIIR pulverized. However, it was difficult to use the product when the content is 40 phr and precured of 40%. BR/PCP composites have improved mechanical properies as compared that of the addition of simply cut chip composite.

• 한국농업기계학회:학술대회논문집
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• 한국농업기계학회 2017년도 춘계공동학술대회
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• pp.108-108
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• 2017

In this study, biocomposite filaments with agricultural by-products can be used in extrusion-based 3D (Three-dimensional) printing. Extrusion-based 3D printing stands as a promising technique owing to its versatility. We hypothesized that bio-filament composite consisted of something derived from agricultural by-products could be used as 3D printing materials that could overcome the drawbacks of PCL (poly-caprolactone). Bio-filament mixed with PCL and agricultural by-products was defined as r-PCL in this study. In order to find it out the optimal mixing ratio of filaments, we had investigated PCL, r-PCL 10%, r-PCL 20%, r-PCL 50% separately. The morphological and chemical characteristics of the filaments were analyzed by FE-SEM (Field emission scanning electron microscope) and EDX (Energy-dispersive X-Ray spectroscopy), and the mechanical properties were evaluated by stress-strain curve, water contact angle, and cytotoxicity analysis. Results of this study have been shown as a promising way to produce eco-friendly bio-filaments composite for FDM (Fused deposition modeling) method based 3D printing technology. Thus, we could establish biomimetic scaffolds based on bio-printer filaments mixed with agricultural by-product.

• 공업화학
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• 제31권3호
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• pp.237-257
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• 2020

The role of nano bio-composites precursor to chitosan are innumerable and are known for having different applications in various branches of physical sciences. The application to the sensor development is relatively new, where only few literature works are available to address the specific and critical analysis of nanocomposites in the subject area. The bio-composites are potential and having greater affinity towards the heavy metals and several micro-pollutants hence, perhaps are having wider implications in the low or even trace level detection of the pollutants. The nano-composites could show good selectivity and suitability for the detection of the pollutants as they are found in the complex matrix. However, the greater challenges are associated using the bio-composites, since the biomaterials are prone to be oxidized or reduced at an applied potential and found to be a hinderance for the detection of target pollutants. In addition, the materials could proceed with a series of electrochemical reactions, which could produce different by-products in analytical applications, resulting in several complex phenomena in electrochemical processes. Therefore, this review addresses critically various aspects of an evaluation of nano bio-composite materials in the electrochemical detection of heavy metals and micro-pollutants from aqueous solutions.

• Elastomers and Composites
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• 제46권4호
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• pp.318-323
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• 2011

폐타이어고무분말을 재활용하기 위하여 방수시트용 고무분말 복합체를 제조하였으며, 수지 종류와 가교제의 함량이 복합체의 기계적 특성에 미치는 영향을 고찰하였다. EPDM이 부가됨에 따라 고무분말 PE 복합체의 신장율이 3배 이상 증가하는 현상을 나타내었다. 고무분말 충전 복합체에 가교제의 농도가 증가함에 따라 복합체의 강도가 증가하였으며, 특히 재생 폴리프로필렌을 사용한 경우 3배 이상 인장강도가 현저하게 높게 나타났다. 따라서 폴리프로필렌 블렌드물로 고무분말 복합체를 제조하는 경우 신재 폴리프로필렌을 사용하는 것 보다 재생 폴리프로필렌을 사용하는 것이 기계적 특성면에서 효과적인 것으로 나타났다.

• 구강회복응용과학지
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• 제22권2호
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• pp.149-159
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• 2006

Statement of problem. Porcelain repair mainly involves replacement with composite resin, but the bond strength between composite resin and all-ceramic coping materials has not been studies extensively. Purpose. The objective of this study was to investigate the influence of composite resin and ceramic etching pattern on shear bond strength of Empress2 ceramic and observe the change of microstructure of ceramic according to etching methods. Material and methods. Eighty-five cylinder shape ceramic specimens (diameter 5mm, IPS Empress 2 core materials) embeded by acrylic resin were used for this study. The ceramic were specimens divided into sixteen experimental groups with 5 specimens in each group and were etched with phosphoric acid(37%, 65%) & hydrofluoric acid (4%, 9%) according to different etching times(30s, 60s, 120s 180s). All etched ceramic surfaces were examined morphologically using SEM(scanning electron microscopy). Etched surfaces of ceramic specimens were coated with silane (Monobond-S) & adhesive(Heliobond) and built up composite resin using Teflon mold. Accomplished specimens were tested under shear loading until fracture on universal testing machine at a crosshead speed 1mm/min; the maximum load at fracture(kg) was recorded. Shear bond strength data were analyzed with one way ANOVA and Duncan tests.(P<.05) Results. Maximum shear bond strength was $30.07{\pm}2.41(kg)$ when the ceramic was etched with 4% hydrofluoric acid at 120s. No significant difference was found between phosphoric etchant group and control group with respect to shear bond strength. Conclusion. Empress 2 ceramic surface was not etched by phosphoric acid, but etched by hydrofluoric acid.