• Title/Summary/Keyword: bio materials

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Mesoporous Assembly of Layered Titanate with Well-Dispersed Pt Cocatalyst

  • Jung, Tae-Sung;Kim, Tae-Woo;Hwang, Seong-Ju
    • Bulletin of the Korean Chemical Society
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    • v.30 no.2
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    • pp.449-453
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    • 2009
  • A mesoporous assembly of layered titanate with well-dispersed Pt cocatalysts has been synthesized via a restacking of exfoliated titanate nanosheets and a simultaneous adsorption of Pt nanoparticles. According to powder X-ray diffraction analysis, the obtained mesoporous assembly shows amorphous structure corresponding to the disordered stacking of layered titanate crystallites. Field emission-scanning electron microscopy and $N_2$ adsorption-desorption isotherm measurement clearly demonstrate the formation of mesoporous structure with expanded surface area due to the house-of-cards type stacking of the titanate crystallites. From high resolution-transmission electron microscopy and elemental mapping analyses, it is found that Pt nanoparticles with the size of ~2.5 nm are homogeneously dispersed in the mesoporous assembly of layered titanate. In comparison with the protonated titanate, the present mesoporous assembly of layered titanate exhibits better photocatalytic activity for the photodegradation of organic molecules. This finding underscores that the restacking of exfoliated nanosheets is quite useful not only in creating mesoporous structure but also in improving the photocatalytic activity of titanium oxide.

Adhesion Properties of UV-curable Pressure Sensitive Adhesives for Dicing Tape (다이싱 테이프용 자외선 경화형 점착제의 접착 물성)

  • Do, Hyun-Sung;Kim, Sung-Eun;Kim, Hyun-Joong
    • Journal of Adhesion and Interface
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    • v.5 no.4
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    • pp.1-8
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    • 2004
  • UV-curable pressure sensitive adhesives were prepared by blending acrylic copolymer, copolymerized with butyl acrylate, acrylic acid and methyl methacrylate by solution polymerization, and trimethylolpropane triacrylate. The PSAs were evaluated by adhesion strength with varying UV dose, and also glass transition temperature ($T_g$) of PSAs were measured. When exposed on UV irradiation, the PSAs showed the decreased adhesion strength and increased $T_g$. And following UV irradiation, the PSAs did not leave any residue on wafer after peel off PSA.

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Histomorphometric evaluation of bone healing with natural calcium carbonate-derived bone substitutes in rat calvarial defect (백서두개골 결손부에서 천연물유래 탄산칼슘염 골대체의 골치유에 관한 조직계측학적 평가)

  • Lee, Chung-Ho;Jang, Je-Hee;Lee, Jae-Mok;Suh, Jo-Young;Park, Jin-Woo
    • Journal of Periodontal and Implant Science
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    • v.38 no.1
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    • pp.83-90
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    • 2008
  • Purpose: This study investigated the osteoconductivity of natural calcium carbonate-derived bone substitutes, hen eggshell (ES), and compared with those of commercial bone substitutes. Materials and Methods: Osseous defects created in the rat calvaria were filled with particulated ES(ES-1), ES with calcium-deficient hydroxyapatite surface layer (ES-2), Biocoral(Inoteb, France), and Bio-Oss(Geistlich Pharma, Wolhusen, Switzerland). After 4 and 8 weeks of healing, histomorphometic analysis was performed to evaluate the amount of newly formed mineralized bone area (NB%). Results: Histologic and histomorphometric analysis showed new bone formation and direct bony contact with the grafted materials in all groups. At 4 weeks, Biocoral group showed greater NB% compared to Bio-Oss and ES-1 groups (P<0.05). At 8 weeks, Biocoral and ES-2 groups showed significantly greater NB% compared to Bio-Oss group (P<0.05). Conclusion: These results indicate that natural calcium carbonate-derived bone substitutes with microporous calcium-deficient hydroxyapatite surface layer may be an effective materials treating osseous defects.

Development of Environmentally Friendly Semi-Structure Poly(Ethylene/Butylene) Rubber-based Pressure Sensitive Adhesive (친환경적인 준구조용 Poly(Ethylene/Butylene) 고무수지계 점착제의 개발)

  • Hong, Soungtaek;Park, Young-Jun;Kim, Hyun-Joong;Dilger, K.
    • Journal of Adhesion and Interface
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    • v.7 no.2
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    • pp.12-18
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    • 2006
  • Recently, as industries and technologies are increased, superior adhesives having more and more developed functions and properties have been demanded. In this article, to use the merits and viscoelastic properties of poly(ethylene/butylene) rubber resin and to supplement the demerits, semi-structure pressure sensitive adhesives (PSAs) are developed. Aslo, it can be said environmentally friendly PSAs because of not use the organic solvent and not emit volatile organic compounds (VOCs).

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Use of Calcium Carbonate for Improving Solid Content of KOCC Wet Web (탄산칼슘 적용에 의한 KOCC 지필의 고형분 증대)

  • Hwang, In-Young;Ji, Sung-Gil;Seo, Yung-Bum
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.6
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    • pp.1-9
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    • 2013
  • For the manufacture of linerboard with 100% KOCC, we tried to increase the solid content of wet web by employing GCC (grounded calcium carbonate) in the fiber furnish to save drying energy. Three different diameters of GCC, namely, 5, 10, and $35{\mu}m$, were used. To complement the strength loss by the addition of GCC, cationic starch and refining treatment were tried. It was found that the addition of $10-35{\mu}m$ dia. GCC to KOCC for $180g/m^2$ basis weight sheets increased the solid content of the furnish about 1-1.5% with better bulk and drainage properties. The loss of strength properties were compensated by the application of cationic starch and/or refining process to the KOCC furnish. The dia. of GCC of $35{\mu}m$ was, however, too large to make smooth surface of the sample sheet. So, the optimization process was required before implementing the results to the mill by selecting proper diameter and shape of the calcium carbonate.

A Study of Transparent Liquid Crystal Gel with High Oil Content from Fatty Acid Soap (지방산 솝을 이용한 고오일 함유 투명젤 생성에 관한 연구)

  • Lee, Jung-No;Kim, Hyuk-Hwa;Yu, Kang-Yeol
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.4
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    • pp.431-437
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    • 2011
  • Transparent liquid crystal gels with high oil content by fatty acid soap were investigated. The solubilization efficiency of the mineral oil was dependent on the process. The process of dropping water part into the solution of oil and surfactant was more efficient than the process of dropping water part into the surfactant solution and after that dropping oil. The fatty acid soap could not solubilize the high oil content, but under the certain range, addition of CDE (Coconut Diethanolamide), Arlacel 165 (Glyceryl Stearate/PEG-100 Stearate) and cetostearyl alcohol helped solubilize the high content oil. Also, the glycerin and water content had influence on the solubilization. Especially, higher oil content gel showed elastic feature.

The Synthesis and Evaluation of Squarylium Dyes Based On the NIR Spectra Region

  • Park, Soo-Youl;Shin, Seung-Rim;Shin, Joung-Il;An, Kyoung-Lyong;Jun, Kun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.10a
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    • pp.131-132
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    • 2008
  • Several squarylium dyes, derived from benzothiazole and indoles, were synthesized as a potential NIR dyes with absorption in the 700-900 nm region. These chromophores were induced much more bathochromic shift in the absorption maximum of the compound relative to the neutral parent squarylium dyes which we were described before. The squaryliums offer a convenient way of linking the dye to functional substrates and may be an advantage to be potential chromophores for NIR-absorbing, NIR-Cut-off filter, PDT(Photo Dynamic Therapy) materials.

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Research and Development of Marine Bio-Organisms - Introduction and Its prospect -

  • Han, Sangtae;Kim, Jong-Man
    • Journal of Marine Bioscience and Biotechnology
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    • v.2 no.2
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    • pp.73-76
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    • 2007
  • A large number of natural products were worldwidely discovered from maine organisms. There are many secondary metabolites produced by maine organisms which showed very strong bio-activities and distinct bio-active mechanisms. In korea, about 350 secondary metabolites including more than 280 novel compounds have been isolated and structually defined. Many researches for developing products such as cosmetics, functional food materials, anti-fouling substances are being performed using distinct activities of marine organisms. Although the research on marine natural products has been remained at its initial or developing stage of drug development, significant progress has been made for isolation, structure determination and bioassay of secondary metabolites.

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The End User Computing Strategy of Using Excel VBA in Promoting Nursing Informatics in Taiwan

  • Chang, Polun;Hsu, Chiao-Ling;Hou, I-Ching;Tu, Ming Hsiang;Liu, Che-Wei
    • Perspectives in Nursing Science
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    • v.5 no.1
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    • pp.45-58
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    • 2008
  • The nursing informatics has been booming in Taiwan since 2003 when we started to use the end user computing strategy to promote it. We used Excel 2003, which was well known and used by our clinical nurses, as well as the embedded VBA to teach them how simple information applications could and should be built to meet their information management needs in order to support their professional responsibility. Many cost-effective projects were successfully done and the importance and potentials of nursing informatics started to be noticed. Our training strategy and materials are introduced in this paper.

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Preparation and Characterization of Homogeneous Hydroxyapatite Sphere (균일한 Hydroxyapatite Sphere 제조 및 특성분석)

  • Lee, Kang Huk;Shin, Dong Geun;Kwon, Woo Teck;Kim, Hyungsun;Kim, Hee Rae;Kim, Younghee;Kim, Soo Ryong
    • Journal of the Korean Ceramic Society
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    • v.51 no.3
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    • pp.145-149
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    • 2014
  • A hydroxyapatite microsphere was prepared using a spray-drying method. The change in the shape as a function of the slurry concentration and the change in the degree of shrinkage according to the heat-treatment temperatures were observed. To obtain biomaterials with improved bio-stability, $CaHPO_4{\cdot}2H_2O$ and $Ca(OH)_2$ were mixed at a ratio of 6 : 4 and then ball-milled to synthesize hydroxyapatite. The hydroxyapatite microsphere was prepared using 30 wt% ~ 80 wt% hydroxyapatite slurry by a spray-drying method. For concentrations lower than 50 wt% or higher than 80 wt%, doughnut-shaped microspheres were produced. However, perfect microspheres were produced when using slurry concentrations of 50 wt% ~ 70 wt%. A dense microstructure was observed after a heat treatment at temperatures higher than $1100^{\circ}C$ and the size was reduced by 24.3% at these temperatures.