• Title/Summary/Keyword: binary solution

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Partial Miscibility of Binary Solution with Specific Interaction of Binomial Distribution (이항분포의 특정 상호작용을 갖는 이성분 용액에서의 부분혼합도)

  • Jung, Hae-Young
    • Journal of the Korean Chemical Society
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    • v.58 no.6
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    • pp.528-534
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    • 2014
  • In some binary solution, closed miscibility loop of temperature-composition phase diagram occurs where both an upper critical solution temperature and a lower critical solution temperature exist. It is known that this phenomena occurs if specific interaction between molecules exists. There are several ways describing the specific interaction. In this work it is assumed that the total number of specific interactions is distributed according to binomial distribution. In this case, exact mathematical conditions for closed miscibility loop phase behavior are derived when the specific interaction is applied to regular solution theory, quasichemical theory and Flory-Huggins lattice theory. And we investigated the effect of parameters on the phase diagram. The phase diagram of water-nicotine is calculated and compared with experimental data.

A comprehensive approach for managing feasible solutions in production planning by an interacting network of Zero-Suppressed Binary Decision Diagrams

  • Takahashi, Keita;Onosato, Masahiko;Tanaka, Fumiki
    • Journal of Computational Design and Engineering
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    • v.2 no.2
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    • pp.105-112
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    • 2015
  • Product Lifecycle Management (PLM) ranges from design concepts of products to disposal. In this paper, we focus on the production planning phase in PLM, which is related to process planning and production scheduling and so on. In this study, key decisions for the creation of production plans are defined as production-planning attributes. Production-planning attributes correlate complexly in production-planning problems. Traditionally, the production-planning problem splits sub-problems based on experiences, because of the complexity. In addition, the orders in which to solve each sub-problem are determined by priorities between sub-problems. However, such approaches make solution space over-restricted and make it difficult to find a better solution. We have proposed a representation of combinations of alternatives in production-planning attributes by using Zero-Suppressed Binary Decision Diagrams. The ZDD represents only feasible combinations of alternatives that satisfy constraints in the production planning. Moreover, we have developed a solution search method that solves production-planning problems with ZDDs. In this paper, we propose an approach for managing solution candidates by ZDDs' network for addressing larger production-planning problems. The network can be created by linkages of ZDDs that express constraints in individual sub-problems and between sub-problems. The benefit of this approach is that it represents solution space, satisfying whole constraints in the production planning. This case study shows that the validity of the proposed approach.

Solvatochromic Fluorescence Behavior of 8-Aminoquinoline-Benzothiazole: A Sensitive Probe for Water Composition in Binary Aqueous Solutions

  • Kim, Young-Hee;Youk, Jin-Soo;Kim, So-Hee;Chang, Suk-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.26 no.1
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    • pp.47-50
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    • 2005
  • Solvatochromic fluorescence behavior of 8-aminoquinoline based benzothiazole derivative in varying solvent systems has been investigated. Benzothiazole appended 8-aminoquinoline 3 showed distinctive fluorescence color changes depending upon the solvent polarities and the fluorescence color changes occurred over relatively wide span in visible region from 486 nm to 598 nm which can be detected with naked eye. Compound 3 also exhibited significant spectral shifts in ${\lambda}_{em}$ as a function of water composition in binary aqueous solvent systems. The changes are due to the specific interaction of 3 by hydrogen bonding with water as well as general solvent effect. The observed solvatochromic fluorescence characteristics of 3 could be used as a new probe for the micro-environmental polarity changes as well as a sensitive sensor for the determination of water composition in binary aqueous solutions.

An Improvement of AdaBoost using Boundary Classifier

  • Lee, Wonju;Cheon, Minkyu;Hyun, Chang-Ho;Park, Mignon
    • Journal of the Korean Institute of Intelligent Systems
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    • v.23 no.2
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    • pp.166-171
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    • 2013
  • The method proposed in this paper can improve the performance of the Boosting algorithm in machine learning. The proposed Boundary AdaBoost algorithm can make up for the weak points of Normal binary classifier using threshold boundary concepts. The new proposed boundary can be located near the threshold of the binary classifier. The proposed algorithm improves classification in areas where Normal binary classifier is weak. Thus, the optimal boundary final classifier can decrease error rates classified with more reasonable features. Finally, this paper derives the new algorithm's optimal solution, and it demonstrates how classifier accuracy can be improved using the proposed Boundary AdaBoost in a simulation experiment of pedestrian detection using 10-fold cross validation.

Thermodynamics on the Mixed Micellar Formation of Dimethyldodecylamine Oxide in Water/n-Propanol (Dimethyldodecylamine Oxide 의 물/n-프로판올 용매에서 혼합미셸 형성에 관한 열역학적 연구)

  • Lee Byung-Hwan
    • Journal of the Korean Chemical Society
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    • v.37 no.6
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    • pp.562-569
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    • 1993
  • The pseudophase separation model is used to describe the effects of pH and n-propanol on the mixed micellar formation of protonated and unprotonated dimethyldodecylamine oxides. Dimethyl-dodecylamine oxide surfactant molecules may exist in aqueous solution in either nonionic (unprotonated) or cationic (protonated) form, and they can be modeled thermodynamically as a binary mixture of cationic and nonionic surfactants. The composition of the binary mixture is varied by adjusting the solution pH. And activities, micellar compositions, and monomeric compositions of two surfactant species can be calculated directly from the experimental titration data by applying pseudophase separation model to the micellar system of DDAO in water/n-propanol. The critical micellar concentrations and the p$K_a$ values of the binary mixture systems are dependent on the micellar composition of the protonated cationic surfactant (X); especially they show the minimum phenomena when they are plotted against the micellar composition of the protonated cationic surfactant (X). The critical micellar concentration of the binary mixed DDAO system is generally decreased when n-propanol is added to the binary mixture system, and the degree of decrease is dependent on the concentration of n-propanol.

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Binary and Ternary Competitive Adsorption of Basic Dyes from Aqueous Solution onto the Conchiolin Layer (수용액에서의 이성분 및 삼성분 염기성 염료의 진주층에 대한 경쟁흡착)

  • Shin, Choon-Hwan;Song, Dong-Ik
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.3
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    • pp.270-275
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    • 2006
  • The cultivated pearls collected for the study were pretreated through the removal of contaminants and the surface bleaching for easy dyeing. Coloring of pearls are necessary after selecting dyes adsorbable to the Conchiolin layer, a kind of hard protein formed in the seawater, covering the surface of the pretreated pearls. Dyes adsorbable to the Conchiolin layers are mostly basic dyes such as Rhodamine 6G(R6G), Rhodamine B(RB), Methylene Blue(MB) etc. and the binary and ternary competitive adsorption were performed by mixing two or three dyes together. The multi-dye adsorption data were compared with the predictions from the ideal adsorbed solution theory(IASI) combined with the single-dye adsorption model, the Langmuir or the Redlich-Peterson(RP) model. The quality of prediction was compared by using determination coefficient($R^2$) and standard deviation(SSE) values. Predictions from the IAST were found to be in good agreement with the data for the R6G/RB binary adsorption to the pearl layers not fractionated with their size, except for the adsorption data for RB at high concentrations. Among the three binary adsorption systems, R6G/RB, R6G/MB, and MB/RB, only the RB sorption data in the R6G/RB binary system was in poor agreement with the IAST prediction. Competitive adsorption data in ternay systems were in good agreement with the predictions from the IAST except for the RB data.

NEW CCD OBSERVATIONS AND THE FIRST PHOTOMETRIC STUDY OF THE CONTACT BINARY AP UMI

  • AWADALLA, N.S.;HANNA, M.A.;ISMAIL, M.N.;HASSAN, I.A.;ELKHAMISY, M.A.
    • Journal of The Korean Astronomical Society
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    • v.49 no.3
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    • pp.65-71
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    • 2016
  • We obtain the first complete CCD light curves (LCs) of the contact binary AP UMi in the VRI bands and analyzed them by means of the PHOEBE code. A spotted model is applied to treat the asymmetry in the LCs. The LC morphology clearly shows the O'Connell effect and the solution shows an influence of star spots on both components. Such effect of star spots is common between the RS CVn and W UMa chromospherically active stars. Based on the obtained solution of the LCs we investigate the evolutionary state of the components and conclude that the system is a pre-intermediate contact binary (f = 0.29) with mass ratio q = 0.38, and it is an A-type W UMa system where the less massive secondary component is cooler than the more massive primary one.

CCD PHOTOMETRY OF CONTACT BINARY WZ Cephei (접촉쌍성 WZ Cephei의 CCD 측광관측)

  • Lee, Woo-Baik;Kang, Young-Woon;Oh, Kyu-Dong
    • Journal of Astronomy and Space Sciences
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    • v.25 no.1
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    • pp.19-24
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    • 2008
  • We present the full BVR light curves and five times of minima of WZ Cep to provides a complete photometric solution and to confirm the long term variation of the light curves. Our light curves show symmetry while previous light curves of Hoffmann (1984) show a high degree of asymmetry (the O'Connell effect). The BVR light curves were analyzed by the method of Wilson-Devinney Differential Correction. Our photometric results show a good agreement with those of Djurasevic et al. (1998).

A Solution of Binary Jamming Message to Source-Wiretapping and Disadvantage of Sharing the Jamming Signal in Physical-Layer Security (물리 계층에서 보안 재밍 신호 공유의 한계점과 이진 재밍 메시지 도청의 해결책)

  • Kong, Hyung-Yun
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.14 no.6
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    • pp.63-67
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    • 2014
  • A distributed zero-beamforming based cooperative jamming technique is useless when an eavesdropper detects the sharing seed. In addition, the currently alternatives are very limited when the eavesdropper is located nearby a source for wiretapping. This letter presents a solution to this extreme case. Relay randomly generates and transmits a binary jamming message to both source and destination in the first phase. When these two receivers securely and correctly decode the message, the source creates and transmits another message based on the use of exclusive-or for its information message and the decoded message. Consequently, the next transmission can avoid the eavesdropping.

Solubility of Mixed Lanthanide Hydroxide and Oxide Solid Solutions

  • Moniruzzaman, Mohammad;Kobayashi, Taishi;Sasaki, Takayuki
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.3
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    • pp.353-366
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    • 2021
  • The solubilities of different multicomponent lanthanide oxide (Ln2O3) solid solutions including binary (Ln1 and Ln2 = La, Nd, Eu, or Tm), ternary (Ln1, Ln2, and Ln3 = La, Nd, Eu, or Tm), and higher systems (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) were studied after aging for four weeks at 60℃. Our recent study revealed that the phase transformations in binary ((La, Nd) and (La, Eu)) and ternary (La, Nd, Eu) systems are responsible for the formation of (La, Nd)(OH)3, (La, Eu)(OH)3, and (La, Nd, Eu)(OH)3 solid solutions, respectively. The variations in the mole fractions of La3+, Nd3+, and Eu3+ in the sample solutions of these hydroxide solid solutions indicated that a thermodynamic equilibrium might account for the apparent La, Nd, and Eu solubilities. Conversely, the binary and ternary systems containing Tm2O3 as the heavy lanthanide oxide retained the oxide-based solid solutions, and their solubility behaviors were dominated by their congruent dissolutions. In the higher multicomponent system, the X-ray diffraction patterns of the solid phases, before and after contact with the aqueous phase indicated the formation of a stable oxide solid solution and their solubility behavior was explained by its congruent dissolution.