• 제목/요약/키워드: binary mixture

검색결과 366건 처리시간 0.025초

A New Distance Measure for a Variable-Sized Acoustic Model Based on MDL Technique

  • Cho, Hoon-Young;Kim, Sang-Hun
    • ETRI Journal
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    • 제32권5호
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    • pp.795-800
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    • 2010
  • Embedding a large vocabulary speech recognition system in mobile devices requires a reduced acoustic model obtained by eliminating redundant model parameters. In conventional optimization methods based on the minimum description length (MDL) criterion, a binary Gaussian tree is built at each state of a hidden Markov model by iteratively finding and merging similar mixture components. An optimal subset of the tree nodes is then selected to generate a downsized acoustic model. To obtain a better binary Gaussian tree by improving the process of finding the most similar Gaussian components, this paper proposes a new distance measure that exploits the difference in likelihood values for cases before and after two components are combined. The mixture weight of Gaussian components is also introduced in the component merging step. Experimental results show that the proposed method outperforms MDL-based optimization using either a Kullback-Leibler (KL) divergence or weighted KL divergence measure. The proposed method could also reduce the acoustic model size by 50% with less than a 1.5% increase in error rate compared to a baseline system.

이성분 혼합액의 방향성 응고에서 자연 대류 (Natural Convection During Directional Solidification of a Binary Mixture)

  • 황인국;최창균
    • Korean Chemical Engineering Research
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    • 제47권2호
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    • pp.174-178
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    • 2009
  • 이성분 혼합물의 응고중에 수지상 결정으로 이루어진 mush 층이 형성될 수 있다. 본 연구진이 개발한 전파이론으로 mush 층에서 성분적 대류의 발생을 해석하였다. Emms와 Fowler의 모델로부터 유도한 자기유사 안정성 방정식을 사용하여 대류 발생에 대한 임계 Rayleigh 수를 수치방법으로 계산하였다. 과열량이 아주 크거나 mush 층의 성장률이 아주 작은 극한의 경우에 본 연구 결과는 준정적 안정성 해석 결과와 같아진다.

이성분혼합물의 응고과정중 이중확산대류의 가시화 (Visualization of double-diffusive convection during solidification processes of a binary mixture)

  • 정우호;정재동;유호선;이준식
    • 대한기계학회논문집B
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    • 제22권4호
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    • pp.440-451
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    • 1998
  • An experimental study has been conducted to investigate solidification of NH$_{4}$CI-H$_{2}$0 mixtures inside a vertical rectangular enclosure. Solidification process is visualized by the shadowgraph method. Emphasis is placed on the effect of solidification parameters such as the aspect ratio, cooling wall temperature and initial composition. The aspect ratio shows a dominant effect on the number and developing time of the double diffusive layers which reveals the relative strength of solutal convection to thermal convection. Similar flow pattern is observed when the concentration difference between interdendritic liquid and the pure liquid which drives solutal convection is the same regardless of the different cooling wall temperature and initial concentration.

상전이 온도 근처에서 관찰되는 MEEP-물로 구성된 두 종류 섞임체의 유전상수 비정상성 (Dielectric Constant Anomaly near the Consolute Point of a binary Mixture of MEEP and water)

  • 조창호;서영석;김세창;김영백
    • 자연과학논문집
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    • 제8권1호
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    • pp.17-22
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    • 1995
  • Poly[bis(methoxyethoxyethoxy)phosphazene] : MEEP와 물로 구성된 두 종류 섞임체의 유전 상수를 임계온도 근처에서 측정하고 유전상수의 비정상성이 일어나는 온도와 농도를 사용하여 공존곡선을 얻었다. 공존곡선으로부터 얻어진 MEEP-물의 임계온도와 임계농도는 각각 $71^{\circ}C$, 5.5%이었다. 상전이 온도 근처에서 유전상수의 임계지수, $\theta$는 0.85였다. 유전상수의 주파수 의존도인 Maxwell-Wagnetr효과에 대해서 논의한다.

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Monte Carlo Simulation for Vapor-Liquid Equilibrium of Binary Mixtures CO2/CH3OHCO2/C2 H5OH, and CO2/CH3CH2CH2OH

  • Moon, Sung-Doo
    • Bulletin of the Korean Chemical Society
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    • 제23권6호
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    • pp.811-817
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    • 2002
  • Gibbs ensemble Monte Carlo simulations were performed to calculate the vapor-liquid coexistence properties for the binary mixtures $CO_2/CH_3OH$, $CO_2/C_2H_5OH$, and $CO_2/CH_3CH_2CH_2OH.$ The configurational bias Monte Carlo method was used in the simulation of alcohol. Density of the mixture, composition of the mixture, the pressure-composition diagram, and the radial distribution function were calculated at vapor-liquid equilibrium. The composition and the density of both vapor and liquid from simulation agree considerably well with the experimental values over a wide range of pressures. The radial distribution functions in the liquid mixtures show that $CO_2$ molecules interact more stogly with methyl group than methylene group of $C_2H_5OH$ and $CH_3CH_2CH_2OH$ due to the steric effects of the alcohol molecules.

이성분 액체 혼합물의 통계열역학적 연구 (Transient State Theory of Significant Liquid Structure applied to Binary Mixture, Benzene-Cyclohexane)

  • 안운선
    • 대한화학회지
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    • 제10권3호
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    • pp.136-142
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    • 1966
  • 벤젠-시클로핵산 이성분 용액에다 Transient State Theory of Significant Liquid Structure를 확장 적용시켰다. 상태함을 구하고 이것으로부터 계의 전체압, 부분압, 몰부피 그리고 과량의 엔트로피와 같은 열역학적 양을 $303.15^{\circ},\;\313.15^{\circ}$$343.15^{\circ}K$에서 계산하였다. 이와 같이 구한 계산치들은 실측치와 대단히 잘 맞았다.

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수평관에서 이원 혼합냉매의 응축 열전달계수 (Condensation Heat Transfer Coefficients of Binary Refrigerant Mixtures on a Horizontal Smooth Tube)

  • 김경기;서강태;정동수
    • 설비공학논문집
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    • 제12권12호
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    • pp.1049-1056
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    • 2000
  • In this study, condensation heat transfer coefficients(HTCs) of 2 nonazeotropic refrigerant mixtures of HFC32/HFC134a and HFC134a/HCFC123 at various compositions were measured on a horizontal smooth tube. All data were taken at the vapor temperature of 39$^{\circ}C$ with a wall subcooling of 3~8K. Test results showed that HTCs of tested mixtures were 11.0~85.0% lower than the ideal values calculated by the mass fraction weighting of the pure components HTCs. Thermal resistance due to the diffusion vapor film was partly responsible for the significant reduction of HTCs with these nonazeotropic mixtures. The measured data were compared against the predicted ones by Colburn and Drew\`s film model and a good agreement was observed.

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The Measurement and Prediction of Minimum Flash Point Behaviour for Flammable Binarry Solution Using Pensky-Martens Closed Cup Tester

  • Ha, Dong-Myeong;Choi, Yong-Chan;Lee, Sung-Jin
    • International Journal of Safety
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    • 제9권2호
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    • pp.6-10
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    • 2010
  • The flash point of liquid solution is one of the most important flammability properties that used in hazard and risk assessments. Minimum flash point behaviour (MFPB) is showed when the flash point of a liquid mixture is below the flash points of the individual components. In this paper, the lower flash points for the flammable binary system, n-decane+n-octanol, were measured by Pensky-Martens closed cup tester. This binary mixture exhibited MFPB. The measured flash points were compared with the values calculated by the Raoult's law and the optimization method using van Laar and UNIQUAC equations. The optimization method were found to be better than those based on the Raoult's law, and successfully estimated MFPB. The opimization method based on the van Laar equation described the experimentally-derived data more effectively than was the case when the prediction model was based upon the UNIQUAC.

Analysis of Electron Transport Coefficients in Binary Mixtures of TEOS Gas with Kr, Xe, He and Ne Gases for Using in Plasma Assisted Thin-film Deposition

  • Tuan, Do Anh
    • Journal of Electrical Engineering and Technology
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    • 제11권2호
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    • pp.455-462
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    • 2016
  • The electron transport coefficients in not only pure atoms and molecules but also in the binary gas mixtures are necessary, especially on understanding quantitatively plasma phenomena and ionized gases. Electron transport coefficients (electron drift velocity, density-normalized longitudinal diffusion coefficient, and density-normalized effective ionization coefficient) in binary mixtures of TEOS gas with buffer gases such as Kr, Xe, He, and Ne gases, therefore, was analyzed and calculated by a two-term approximation of the Boltzmann equation in the E/N range (ratio of the electric field E to the neutral number density N) of 0.1 - 1000 Td (1 Td = 10−17 V.cm2). These binary gas mixtures can be considered to use as the silicon sources in many industrial applications depending on mixture ratio and particular application of gas, especially on plasma assisted thin-film deposition.

Approximate Nonrandom Two-Fluid Lattice-Hole Theory. Thermodynamic Properties of Real Mixtures

  • 유기풍;신훈용;이철수
    • Bulletin of the Korean Chemical Society
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    • 제18권8호
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    • pp.841-850
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    • 1997
  • A simple molecular theory of mixtures is formulated based on the nonrandom two-fluid lattice-hole theory of fluids. The model is applicable to mixtures over a density range from zero to liquid density. Pure fluids can be completely characterized with only two molecular parameters and an additional binary interaction energy is required for a binary mixture. The thermodynamic properties of ternary and higher order mixtures are completely defined in terms of the pure fluid parameters and the binary interaction energies. The Quantitative prediction of vapor-liquid, and solid-vapor equilibria of various mixtures are demonstrated. The model is useful, in particular, for mixtures whose molecules differ greatly in size. For real mixtures, satisfactory agreements are resulted from experiment. Also, the equation of state (EOS) is characterized well, even the liquid-liquid equilibria behaviors of organic mixtures and polymer solutions with a temperature-dependent binary interaction energy parameter.