• Title/Summary/Keyword: beryllium

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Fabrication and Characterization of Red OLED on the Plastic Substrate (플라스틱 기판상에 적색 OLED 제작과 특성 연구)

  • Jeong, Jin-Cheol;Kim, Hyeong-Seok;Kim, Won-Ki;Jang, Ji-Geun
    • Journal of the Semiconductor & Display Technology
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    • v.8 no.4
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    • pp.15-19
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    • 2009
  • A high efficient organic red light emitting device with structure of DNTPD/TAPC/$Bebq_2$ :[$(pq)_2Ir(acac)$, SFC-411]/SFC-137 was fabricated on the plastic substrate, which can be applied in the fields of flexible display and illumination. In the device structure, N,N'-diphenyl-N,N'-bis-[4-(phenyl-m-tolylamino)-phenyl]-biphenyl-4,4'-diamine[DNTPD] as a hole injection layer and 1,1-bis-(di-4-tolylaminophenyl) cyclohexane [TAPC] as a hole transport were used. Bis(10-hydroxybenzo[h]quinolinato) beryllium complex [$Bebq_2$] was used as a light emitting host material. The host material, $Bebq_2$ was doubly doped with volume ratio of 7% iridium(III)bis-(2-phenylquinoline)acetylacetonate[$(pq)_2$Ir(acac)] and 3% SFC-411[red phosphor dye coded by the proprietary company]. And then, SFC-137 was used as an electron transport layer. The luminous intensity and current efficiency of the fabricated device were $22,780\;cd/m^2$ at 9V and 17.3 cd/A under $10,000\;cd/m^2$, respectively. The maximum current efficiency of the device was 22.4cd/A under $580\;cd/m^2$.

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Exposure Characteristics of Chemical Hazards in Metalworking Operations using an Employee Exposure Assessment Database (작업환경측정 자료를 이용한 CNC공정의 유해물질 노출 특성)

  • Lee, Jaehwan;Park, Donguk;Ha, Kwonchul
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.28 no.2
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    • pp.230-239
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    • 2018
  • Objective: The purpose of this study is to identify the kinds and exposure levels of health hazards in the metalworking process in relation to acute poisoning accidents caused by methanol in 2016. Methods: The number of industries, workplaces, exposed workers, regional distribution, and exposure level of health hazards in metalworking process were investigated based on employee exposure assessment database provided by KOSHA (the Korea Occupational Safety and Health Agency), which was collected from workplace hazard evaluation programs in Korea. Exposure metrics for methanol were assessed by RCR (risk characterization ratio). Results: The numbers of processes, workplaces, and exposed workers of metalworking, which include CNC (computer numerical control) were 25, 14,405, and 169,102 respectively. The numbers of samples of chemical hazards including methanol were 91,325, and it was found that workers in metalworking were exposed to 249 kinds of chemical hazards. There were 16 kinds of special controlled substances including beryllium. It is estimated that the number of workplaces involving CNC process was 2,537, and the number of exposed workers was 27,976. In CNC process, the total number of workplaces handling methanol was 36, and 298 workers were estimated to be exposed. There was no exceeded that surpassed the OEL and 49% of samples were below the limit of detection. Methanol exposure concentrations in Gyeonggido Province were statistically significantly higher than in other areas (p <0.0001). Conclusions: In the metalworking process including CNC, there is exposure to a wide variety of health hazards. There was no sample exceeding the OEL for methanol. Therefore, it is necessary to recognize the limits of the employee exposure assessment system and urgently improve measures to prevent the occurrence of events like methanol poisoning.

Radiation-induced transformation of Hafnium composition

  • Ulybkin, Alexander;Rybka, Alexander;Kovtun, Konstantin;Kutny, Vladimir;Voyevodin, Victor;Pudov, Alexey;Azhazha, Roman
    • Nuclear Engineering and Technology
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    • v.51 no.8
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    • pp.1964-1969
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    • 2019
  • The safety and efficiency of nuclear reactors largely depend on the monitoring and control of nuclear radiation. Due to the unique nuclear-physical characteristics, Hf is one of the most promising materials for the manufacturing of the control rods and the emitters of neutron detectors. It is proposed to use the Compton neutron detector with the emitter made of Hf in the In-core Instrumentation System (ICIS) for monitoring the neutron field. The main advantages of such a detector in comparison the conventional β-emission sensors are the possibility of reaching of a higher cumulative radiation dose and the absence of signal delays. The response time of the detection is extremely important when a nuclear reactor is operating near its critical operational parameters. Taking Hf as an example, the general principles for calculating the chains of materials transformation under neutron irradiation are reported. The influence of 179m1Hf on the Hf composition changing dynamics and the process of transmutants' (Ta, W) generation were determined. The effect of these processes on the absorbing properties of Hf, which inevitably predetermine the lifetime of the detector and its ability to generate a signal, is estimated.

A Study on the Development of Porcelain Bonded Ni-Cr Dental Alloy (도재소부용 Ni-Cr 보철합금 개발에 관한 연구)

  • Lee, Gyu-Hwan;Sin, Myeong-Cheol;Choe, Bu-Byeong
    • Journal of Biomedical Engineering Research
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    • v.6 no.1
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    • pp.37-46
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    • 1985
  • Development of a dental Ni-Cr alloy system for porcelain veneering crown and bridge was studied in this research. The principles of alloy design were a) It should not contain toxic beryllium. b) It should have low melting Point. c) It should be easily ground and polished. d) It should possess an adequate strength to resist the deformational force In the mouth. e) It should be bondable Ivith porcelain by chemically. After investigating the effect of minor elements such as boron and rare earth metals on the mechanical properties of the Ni-Cr alloy system, the compromised ideal composition for dental use was determined. The composition was l9.6%, Cr, 5.6% Mo, 3.4% Si, 1, 0% Fe, 0.01% Ti, 0.5-1.0% B, 0.2-0.6% misch metal, balance Ni. To compare the performance of experimental alloy with commercially available alloys, the properties such as strength, melting point, and bond strength were measured. The results Ivere as follows: a) Boron increases the strength of the alloy but reduces the elongation. b) Misch metal increases the strength when the boron content is low, but does not increase the strength when boron content is high. And it reduces the elongation drastically, c) Mechanical strength of the experimental alloy was not superior to commercially available Be containing alloy, but handling performance such as castability, ease of granting and polishing, and cuttability were superior to the Be containing alloy.

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Pulmonary Foreign Body Granulomatosis in Dental Technician

  • Chung, Sung Jun;Koo, Gun Woo;Park, Dong Won;Kwak, Hyun Jung;Yhi, Ji Young;Moon, Ji-Yong;Kim, Sang-Heon;Sohn, Jang Won;Yoon, Ho Joo;Shin, Dong Ho;Park, Sung Soo;Pyo, Ju Yeon;Oh, Young-Ha;Kim, Tae-Hyung
    • Tuberculosis and Respiratory Diseases
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    • v.78 no.4
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    • pp.445-449
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    • 2015
  • Occupational lung diseases are caused by several toxic substances including heavy metals; however, the exact pathologic mechanisms remain unknown. In the workplace, dental technicians are often exposed to heavy metals such as cobalt, nickel, or beryllium and occasionally develop occupational lung diseases. We described a case of occupational lung disease in a patient who was employed as a dental technician for over a decade. A 31-year-old, non-smoking woman presented with productive cough and shortness of breath of several weeks duration. Chest computed tomography revealed a large number of scattered, bilateral small pulmonary nodules throughout the lung field, and multiple mediastinal lymph nodes enlargement. Percutaneous needle biopsy showed multifocal small granulomas with foreign body type giant cells suggestive of heavy metals inhalation. The patient's condition improved on simple avoidance strategy for several months. This case highlighted the importance of proper workplace safety.

A design of transmission-type multi-target X-ray tube based on electric field modulation

  • Zhao, Lei;Jia, Wenbao;Jin, Limin;Shan, Qing;Cheng, Can;Zhu, Hongkui;Hei, Daqian
    • Nuclear Engineering and Technology
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    • v.53 no.9
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    • pp.3026-3034
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    • 2021
  • Multi-target X-ray tube is a new type X-ray source, and can be applied in many fields such as sensitive X-ray fluorescence analysis and medical imaging. In this work, we report an electric field modulation multi-target X-ray tube, which contains four targets (Cr, Ni, Au, Mo) coated on a Beryllium (Be) window. A four-valve electric field deflector was developed to deflect the electron beam to bombard the corresponding targets. Particle dynamics analysis software was employed to simulate the particle tracking of electron beam. The results show that the 30 keV electron beam could get a 6.7 mm displacement on the target plane by 105 V/m electric field. The focus areas are about 2 mm × 5 mm and 4 mm × 2.5 mm after deflection in two directions. Thermal behavior calculated by ANSYS shows that the designed target assembly could withstand a 10 W continuous power. The optimum target thicknesses and emission spectra were obtained by Geant4 when the thickness of Be window was 300 mm and the electron beam incident angle was 0.141 rad. The results indicate that this multi-target X-ray tube could provide different X-ray sources effectively.

Bragg-curve simulation of carbon-ion beams for particle-therapy applications: A study with the GEANT4 toolkit

  • Hamad, Morad Kh.
    • Nuclear Engineering and Technology
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    • v.53 no.8
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    • pp.2767-2773
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    • 2021
  • We used the GEANT4 Monte Carlo MC Toolkit to simulate carbon ion beams incident on water, tissue, and bone, taking into account nuclear fragmentation reactions. Upon increasing the energy of the primary beam, the position of the Bragg-Peak transfers to a location deeper inside the phantom. For different materials, the peak is located at a shallower depth along the beam direction and becomes sharper with increasing electron density NZ. Subsequently, the generated depth dose of the Bragg curve is then benchmarked with experimental data from GSI in Germany. The results exhibit a reasonable correlation with GSI experimental data with an accuracy of between 0.02 and 0.08 cm, thus establishing the basis to adopt MC in heavy-ion treatment planning. The Kolmogorov-Smirnov K-S test further ascertained from a statistical point of view that the simulation data matched the experimentally measured data very well. The two-dimensional isodose contours at the entrance were compared to those around the peak position and in the tail region beyond the peak, showing that bone produces more dose, in comparison to both water and tissue, due to secondary doses. In the water, the results show that the maximum energy deposited per fragment is mainly attributed to secondary carbon ions, followed by secondary boron and beryllium. Furthermore, the number of protons produced is the highest, thus making the maximum contribution to the total dose deposition in the tail region. Finally, the associated spectra of neutrons and photons were analyzed. The mean neutron energy value was found to be 16.29 MeV, and 1.03 MeV for the secondary gamma. However, the neutron dose was found to be negligible as compared to the total dose due to their longer range.

Evaluating Activation for 50 MeV Cyclotron Irradiation Service using Monte Carlo Method and Inventory Code (50 MeV 사이클로트론 조사 서비스로 인한 방사화 평가)

  • Kim, Sangrok;Kim, Gi-sub;Heo, Jaeseung;Ahn, Yunjin
    • Journal of the Korean Society of Radiology
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    • v.15 no.4
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    • pp.415-427
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    • 2021
  • Korea Institute of Radiological and Medical Sciences has provided various beam irradiation services to researchers using a 50 MeV cyclotron beam line. In particular, since the neutron beam service uses the nuclear reaction between protons and beryllium, the possibility of activation of the irradiated sample increases by using a high current. In this study, MCNP 6.2 and FISPACT-II 4.0 were used to evaluate the possible activation during the 35 MeV 20 ㎂ neutron beam service, which is preferred by the researchers. As a result of the calculation, if the iron, copper, and tungsten samples were irradiated for more than 1 hour, long-lived radioisotopes were produced and their radioactivity exceeded the standard level for self-disposal. Under the conditions of 2 hours of daily irradiation, no activation occurred in the building materials, and the internal exposure of workers due to air activation inside the irradiation room was very insignificant. And when this air was discharged to environment, the radioactivity including this air was also satisfied the emission standard.

Ceramic color differences of dental Ni-Cr alloy by compositional change (치과용 Ni-Cr 합금의 조성에 따른 세라믹의 색차 분석)

  • Kim, Sa-Im;Kim, Tae-Yeon;Kim, Se-Ha;Kang, Jeong-Gyu;Lee, Jung-Hwan
    • Journal of Technologic Dentistry
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    • v.43 no.4
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    • pp.168-174
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    • 2021
  • Purpose: This study was conducted to investigate alloys spectrophotometrically including yttrium of nickel-chromium (Ni-Cr) alloys, which are used as substitutes for the regulation of beryllium and provide helpful improvements in Ni-Cr alloys. Methods: Four groups of specimens (ZN, ZY, SN and EM) were prepared for analysis. Color parameters were measured with a spectrophotometer, and color difference (∆E*) was calculated. The t-test and one-way analysis of variance test were used to determine significant difference, and the Tukey test was used to identify where the differences were. To measure the spectroscopic reflectivity, the spectroscopic reflectance was measured and converted into CIE L*, a*, b* color system. Results: The ∆E* value of each metal ceramic group after opaque firing of Ni-Cr alloy with and without yttrium was <2, and the total group color difference (∆E*) was below 1 in the dentin ceramic all experimental group. However, the a* and b* values of the metal ceramic groups were higher than that in the lithium disilicate all ceramic group, and the chroma was higher than the natural tooth. The brightness of all experimental groups was similar to that of the shade guide sample. Conclusion: Yttrium added to Ni-Cr alloys showed similar CIE L*, a*, b* values to Ni-Cr alloys that did not contain yttrium, indicating that yttrium had no effect on color in metallic ceramic systems.

Analysis of the first core of the Indonesian multipurpose research reactor RSG-GAS using the Serpent Monte Carlo code and the ENDF/B-VIII.0 nuclear data library

  • Hartanto, Donny;Liem, Peng Hong
    • Nuclear Engineering and Technology
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    • v.52 no.12
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    • pp.2725-2732
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    • 2020
  • This paper presents the neutronics benchmark analysis of the first core of the Indonesian multipurpose research reactor RSG-GAS (Reaktor Serba Guna G.A. Siwabessy) calculated by the Serpent Monte Carlo code and the newly released ENDF/B-VIII.0 nuclear data library. RSG-GAS is a 30 MWth pool-type material testing research reactor loaded with plate-type low-enriched uranium fuel using light water as a coolant and moderator and beryllium as a reflector. Two groups of critical benchmark problems are derived on the basis of the criticality and control rod calibration experiments of the first core of RSG-GAS. The calculated results, such as the neutron effective multiplication factor (k) value and the control rod worth are compared with the experimental data. Moreover, additional calculated results, including the neutron spectra in the core, fission rate distribution, burnup calculation, sensitivity coefficients, and kinetics parameters of the first core will be compared with the previous nuclear data libraries (interlibrary comparison) such as ENDF/B-VII.1 and JENDL-4.0. The C/E values of ENDF/B-VIII.0 tend to be slightly higher compared with other nuclear data libraries. Furthermore, the neutron reaction cross-sections of 16O, 9Be, 235U, 238U, and S(𝛼,𝛽) of 1H in H2O from ENDF/B-VIII.0 have substantial updates; hence, the k sensitivities against these cross-section changes are relatively higher than other isotopes in RSG-GAS. Other important neutronics parameters such as kinetics parameters, control rod worth, and fission rate distribution are similar and consistent among the nuclear data libraries.