• Title/Summary/Keyword: bentonite recycling

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Removal of Ammonia from Aqueous Solutions with Zeolite and Bentonite (제오라이트 및 벤토나이트에 의한 수용액중 암모니아의 제거)

  • 이화영;오종기;김성규;고현백
    • Resources Recycling
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    • v.11 no.3
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    • pp.3-9
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    • 2002
  • Relnoval of ammonia from aqueous solutions has been studied with zeolite and bentonite minerals. Zeolite and bentonite powder were supplied by a domestic company and used as delivered without further purification. The aqueous pH was found to increase by addition of zeolite or bentonite up to pH 8.5 from initial pH of 5.5∼5.7. From the C.E.C. measurement by ammonium acetate leaching method, the values of C.E.C. of zeolite and bentonite sample were observed to be 129.7 meq/100 gr and 65.1 meq/100 gr, respectively and Na+ ion accounted for the major part of total C.E.C. in both cases. In the removal of ammonia with zeolite and bentonite, physical adsorption of ammonium ion onto minerals was believed to contribute to the removal of it as well as the intrinsic cation exchange reaction. Finally, zeolite was found to be superior to bentonite in the removal of ammonia from aqueous solutions.

Efficient recycling strategies for slurry TBM excavated soil

  • Sung-Min Nam;Joon-Shik Moon;Junyoung Ko;Hyoungseok Oh
    • Geomechanics and Engineering
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    • v.38 no.6
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    • pp.603-609
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    • 2024
  • In downtown subway project most of excavated soil is discarded externally, whereas in road construction excavated soil is used as filling material and management of surplus soil becomes important factor for success of the project. Excavated materials from slurry shield TBM are discharged through discharge pipe to slurry treatment plant and excavated soil mixed with bentonite are separated in separation plant by grain size. Fine material has been discarded together in filter cake without recycling. Its volume can vary according to geologic condition but statistically fine material as filter cake is about 5%~30% out of overall excavated volume. However, filter cake is non-toxic and can be recycled when mixed in the appropriate proportions with coarse aggregate. Therefore, in this study, utilization of excavated soil from a slurry shield TBM were examined and lab tests were conducted to find the proper way for mixing filter cake and aggregate to be recycled as fill material for road construction.

Adsorption characteristics of synthetic heavy metals ($Zn^{2+}$, $Ni^{2+}$, $Cd^{2+}$, $Cu^{2+}$, and $Pb^{2+}$) by bentonite (벤토나이트에 의한 혼합 중금속($Zn^{2+}$, $Ni^{2+}$, $Cd^{2+}$, $Cu^{2+}$$Pb^{2+}$) 수용액상에서의 중금속 흡착 특성)

  • Shin, Woo-Seok;Kim, Young-Kee
    • Journal of the Korea Organic Resources Recycling Association
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    • v.22 no.2
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    • pp.17-26
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    • 2014
  • In this study, the adsorption efficiency of mixed heavy metals from an aqueous solution was examined using bentonite. The physical and chemical properties of bentonite was analyzed via scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR), Further, heavy metal adsorption was characterized using Freundlich and Langmuir equations. Equilibrium adsorption data were fitted well to the Langmuir model for bentonite. The adsorption uptake of heavy metals was high and followed the order $Pb^{2+}$ > $Cu^{2+}$ > $Cd^{2+}$ > $$Zn^{2+}{\sim_=}Ni^{2+}$$. The results also showed that adsorption uptake slightly increased as increasing pH from 6 to 10. The bentonite surface was observed viay SEM and FT-IR; Si-O and Si-O-Al were found to be the main functional groups by FT-IR analysis. From these results, the adsorption mechanisms of heavy metal were not only surface adsorption and ion exchange, but also surface precipitation. Thus, bentonite could be a useful adsorbent for treating heavy metal in aqueous solution.

A study for recycling plan of excavated soil and filter cake of slurry shield TBM for road construction (도로공사 이수식 쉴드 TBM 굴착토 및 필터케이크 재활용방안 연구)

  • Nam, Sung-min;Park, Seo-young;Ahn, Byung-cheol
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.24 no.6
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    • pp.599-615
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    • 2022
  • In order to excavate underground tunnel most safely such as Han river, the slurry shield TBM method is applied to cope with face of high water pressure for many metro projects. In downtown subway project most of excavated soil is discharged externally whereas in road construction excavated soil is used as filling materials so it becomes important factor for success of the project. After excavated soil, weathered rock and soft rock are discharged with bentonite through discharge pipe to slurry treatment plant then those soils are separated in separation plant according to those size. Fine grained soil has been discarded together with filter cake but it is not toxic and can be mixed with coarse aggregate in proper ratio so this study is performed to find use of qualified filling material to meet quality standard. Therefore, in this study, legal standards and quality standards for the utilization of excavated soil of the slurry shield TBM method were examined and test was conducted to derive recycling way for filter cake and aggregate. And a plan for using it as a filling material for road construction was derived. Because bentonite is a clay composed of montmorillonite, and the excavated soil in the tunnel is also non-toxic, disposal of this material can waste social cost so it is expected to be helpful in the underground space development project that carries out the TBM project by recycling it as a valuable resource.

Waterproof Characteristic for Environmental Water Flows in Small Streams (소규모 하천 친환경 물흐름을 위한 차수특성)

  • Park, Min-Cheol;Kim, Seong-Goo;Lee, Song
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.09b
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    • pp.192-199
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    • 2010
  • This research produced internal model tester ($2.0m{\times}2.0m{\times}1.0m$) to evaluate the field application of Paju Unjeong District water recycling system for small streams eco-friendly river bed disparity method for the first time in Korea and conducted comparative analysis of the Paju Unjeong District water recycling system field test results and infiltration rate result of internal tests by each rainfall intensity following surface material. Infiltration rate result of internal tests concrete pavement by rainfall intensity following surface material, asphalt pavement, bentonite mate, stabilized soil construction and mixed soil construction manifested low infiltration rate. On the contrary, compaction soil, grassland and water permeable packaging materials resulted in significant amount of infiltration rate. As for the field permeability test results, they were manifested similar tendency as indoor permeability test results and they satisfied the standard for standard of water permeability of domestic disparity facility (less than $1.0{\times}10-7cm$/sec). As compaction rate increased, unconfined compression strength increased as well while coefficient of water permeability decreased.

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Study on the reuse and recycling of the used foundry sands (폐주물사의 재활용 활성화 방안에 관한 연구)

  • Kim, Young-Jun;Chung, Myung-Hee
    • Journal of the Korea Organic Resources Recycling Association
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    • v.18 no.4
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    • pp.38-44
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    • 2010
  • Foundry sands are made up of silica and some coking agents, such as bentonite or resin, and used as templates for the production of various casting products. Foundry sands, which are repeatedly used, were finally transformed into the waste materials by heat, losing their proper functions. The used foundry sands have been treated as general wastes according to the contents of coking agents used. Silica, however, can be recycled through the proper treatment due to its physical property not to changed by heat. In this study, we have identified and investigated at the occurrence, treatment and recycling status of the used foundry sands, as well as for the regime and inhibitory factors of the recycling of them in domestic and foreign cases.

A Study on the Strength. Chemical Resistance and Absorption of Polymer concrete with Recycling PET (재활용 PET수지를 이용한 폴리머 콘크리트의 강도, 내화학성, 흡수율에 관한 실험적 연구)

  • 조병완;서석구;태기호;박승국;류성희
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.805-810
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    • 2003
  • It is the real circumstance in the country that not only the data and special books but also people who have an expert knowledge are short of the field of the study about plastic wastes, so that to build the Database carrying out gathering info of that is the present question obviously. The business on recycling plastic, for some reason or other, is one of the best ways as called bright prospect industry to prevent environmental pollution and obtain economical outcome by using limited resources. Plastic wastes with construction industry especially using Polymer may have a good effect on the environment and human beings and have a fine view to produce functional and Eco-friendly concrete as well. In this study, Chemical resistance and Water Absorption test in Polymer concrete using bentonite as a shrinkage control agent was made an experiment by comparing with influence on concrete strength and used to offer some valuable data about Polymer concrete.

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Preparation and Characteristics of Soda Lime for Carbon Dioxide Absorption (이산화탄소 흡수를 위한 소다라임 제조 및 특성)

  • Young-Jin Kim;Seok-Je Kwon;Jun-Hyung Seo;Yang-Soo Kim;Kye-Hong Cho;Jin-Sang Cho
    • Resources Recycling
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    • v.32 no.2
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    • pp.52-58
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    • 2023
  • In this study, soda lime was prepared from slaked lime to expand the scope of limestone use. To evaluate carbon dioxide absorption, an extruder-type and disc-type pelletizers were used to make the soda lime using bentonite as an additive. Regardless of the pelletizing process, the peak of CaCO3 was confirmed in soda lime due to its reaction with carbon dioxide. Furthermore, it was confirmed that both calcite and aragonite were present together. The soda lime prepared using the disc-type pelletizer showed a larger specific surface area than that prepared using the extruder-type pelletizer did, and the specific surface area improved on adding bentonite. The carbon dioxide absorption rate increased under the sample condition with an enhanced specific surface area.

Preparation of Formed Ceramic materials by Recycling of Aluminium Dross (알루미늄 드로스를 이용한 무기 발포재 제조)

  • 박제신;박형규;장대규
    • Resources Recycling
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    • v.10 no.4
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    • pp.42-47
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    • 2001
  • Recycling of aluminum dross is a significant issue in domestic aluminum industry. In this study, formed ceramic materials were prepared using aluminum dross mixed with feldspar powders to investigate its application as industrial materials and utilization of aluminum dross. In the prepared sample, feldspar was melted at the sintered temperature, and its phase was trans-formed into amorphous, and spinel ($MgA1_2$$O_4$) phase in the dross was remained clearly. Density of the test specimen Increased from 0.91 to 0.65 gr/㎤ and water absorbance decreased from 2.5 to 1.7f% with increasing of sintered time at the sintered temperature $1220^{\circ}C$ with composition of feldspar 55 wt%, dross 40wt% and bentonite 5 wt%. At the same experimental conditions, bending strength of the test specimen was 10.8 MPa, and heat conductivity was 0.34 W/m.K with sintered time 30 minutes.

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Comparative Analysis of Various Industrial By-Products Pozzolanic Activity (다양한 산업부산물들의 포졸란 반응성 비교분석)

  • Choi, Ik-Je;Kim, Ji-Hyun;Chung, Chul-Woo;Lee, Soo-Yong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.32-33
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    • 2016
  • In this work, pozzolanic activities of various waste materials were compared with those of well-known pozzolanic materials. Uncondensed and densified silica fume, two ASTM class F fly ashes with different calcium contents, and bentonite powder, ceramic powder obtained from wash basin, and waste glass wool, which can possibly possess pozzolanic property were chosen for comparison. Drop in electrical conductivity at 40℃ saturated lime solution was measured for each materials. The amount of Ca(OH)2 decomposed from cement paste at 450~500℃ was also measured used to evaluate pozzolanic activity. The 28 day compressive strength were used to observe the mechanical property enhanced by various waste materials.

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