• 제목/요약/키워드: base-metal

검색결과 1,591건 처리시간 0.032초

희토류가 수소화 촉매에 미치는 영향 (Effect of Rare Earth Metal on Catalyst for Hydrogenation Reaction)

  • 안재용;전종기
    • 한국응용과학기술학회지
    • /
    • 제35권1호
    • /
    • pp.151-156
    • /
    • 2018
  • 산업과 의학이 발전되면서 많은 인구는 삶의 질에 관심을 가지게 되었다. 건강에 대한 시각이 높아지면서 육류보다 채식 또는 식물성 오일을 선호하게 되었다. 오늘날 주로 니켈 촉매를 사용한 공정이 개발되면서 식물성 오일의 보존기간이 늘어나고 이동성이 편리해졌다. 현재 유지경화용 니켈 촉매는 외국기업이 세계시장을 장악하고 있다. 한편, 국내 니켈 촉매의 대량 생산 기술은 퇴보 되어 전량 외국에서 수입하고 있는 실정이다. 따라서 활발한 기초연구가 필요하고 국내에서 상용화 할 수 있는 촉매개발이 필요하다. 본 연구는 수소화 반응으로부터 유지경화에 기반이 되는 니켈을 주 활성 촉매제로 사용하였고, 희토류가 촉매의 활성에 주는 영향을 알아보았다. 일정량의 희토류는 니켈의 분산을 유도하여 효율을 증가시키고 조촉매로써 사용이 가능하였다.

W92-Ni-Fe 소결툴을 이용한 Cu-Ni 합금의 용접부미세조직과 경도 특성 (Investigation for Microstructure and Hardness of Welded Zone of Cu-Ni Alloy using W92-Ni-Fe Sintering Tool)

  • 윤태진;박상원;강명창;노중석;정성욱;강정윤
    • 한국분말재료학회지
    • /
    • 제22권3호
    • /
    • pp.181-186
    • /
    • 2015
  • In this study, the effect of the friction stir welding (FSW) was compared with that of the gas tungsten arc welding (GTAW) on the microstructure and microhardness of Cu-Ni alloy weldment. The weldment of 10 mm thickness was fabricated by FSW and GTAW, respectively. Both weldments were compared with each other by optical microstructure, microhardness test and grain size measurement. Results of this study suggest that the microhardness decreased from the base metal (BM) to the heat affected zone (HAZ) and increased at fusion zone (FZ) of GTAW and stir zone (SZ) of FSW. the minimum Hv value of both weldment was obtained at HAZ, respectively, which represents the softening zone, whereas Hv value of FSW weldment was little higher than that of GTAW weldment. These phenomena can be explained by the grain size difference between HAZs of each weldment. Grain size was increased at the HAZ during FSW and GTAW. Because FSW is a solid-state joining process obtaining the lower heat-input generated by rotating shoulder than heat generated in the arc of GTAW.

Relationship Between Manganese Nodule Abundance and Geologici/Topographic Factors of the Southern KODOS Area in the Northeastern Equatorial Pacific Using GIS and Probability Method

  • Ko, Young-Tak;Min, Kyung-Duck;Park, Cheong-Kee;Kang, Jung-Keuk;Kim, Ki-Hyune;Lee, Tae-Gook;Kim, Hyun-Sub
    • Ocean and Polar Research
    • /
    • 제26권2호
    • /
    • pp.219-230
    • /
    • 2004
  • The aims of this study are to construct database using geostatistics and Geographic Information System (GIS), and to derive the spatial relationships between manganese nodule abundance and each factor affecting nodule abundance, such as metal grade, slope, aspect, water depth, topography, and acoustic characteristics of the subbottom using the GIS and probability methods. The greater is the copper and nickel grade, the higher is the rating. The distribution pattern of nickel grade is similar to that of copper grade. The slopes are generally less than $3^{\circ}$, excluding seamounts and cliff areas. There is no increment in the rating with increasing slope. The rating is highest for slopes between 2.5 and $3.5^{\circ}$ in block B2 and between 3 and $6^{\circ}$ in block C1. The topography is classified into five groups: seamount, hill crest, hill slant, hill base or plain, and seafloor basin or valley. The ratings prove lowest for seamount and hill crest. The results of the study show a decrease in the rating with an increase in water depth in the study area. There was a poor relationship between manganese nodule abundance and the thickness of the upper transparent layer in block C1. Using GIS, it is possible to analyze a large amount of data efficiently, and to maximize the practical application, to increase specialization, and to enhance the accuracy of the analyses.

Cloning, Purification, and Characterization of a New DNA Polymerase from a Hyperthermophilic Archaeon, Thermococcus sp. NA1

  • Kim, Yun-Jae;Lee, Hyun-Sook;Bae, Seung-Seob;Jeon, Jeong-Ho;Lim, Jae-Kyu;Cho, Yon-A;Nam, Ki-Hoon;Kang, Sung-Gyun;Kim, Sang-Jin;Kwon, Suk-Tae;Lee, Jung-Hyun
    • Journal of Microbiology and Biotechnology
    • /
    • 제17권7호
    • /
    • pp.1090-1097
    • /
    • 2007
  • Genomic analysis of Thermococcus sp. NA1 revealed the presence of a 3,927-base-pair (bp) family B-type DNA polymerase gene, TNA1_pol. TNA1_pol, without its intein, was overexpressed in Escherichia coli, purified using metal affinity chromatography, and characterized. TNA1_pol activity was optimal at pH 7.5 and $75^{\circ}C$. TNA1_pol was highly thermostable, with a half-life of 3.5h at $100^{\circ}C$ and 12.5h at $95^{\circ}C$. Polymerase chain reaction parameters of TNA1_pol such as error-rate, processivity, and extension rate were measured in comparison with rTaq, Pfu, and KOD DNA polymerases. TNA1_pol averaged one incorrect bp every 4.45 kilobases (kb), and had a processivity of 150 nucleotides (nt) and an extension rate of 60 bases/s. Thus, TNA1_pol has a much faster elongation rate than Pfu DNA polymerase with 7-fold higher fidelity than that of rTaq.

고장력볼트 T-인장이음의 정적내력에 관한 실험적 연구 (An Experimental Study on the Static Load Capacity of T-Type Tension Joints with High Tension Bolt)

  • 이승용;최준혁;김경태
    • 한국강구조학회 논문집
    • /
    • 제27권1호
    • /
    • pp.53-61
    • /
    • 2015
  • 인장이음은 고장력 볼트의 체결력과 모재 그리고 고장력 볼트의 내력을 직접적으로 활용하고, 볼트구멍의 가공수나 체결개소의 감소, 피로저항성 등에 있어 유리하며 때문에 역학적으로 매우 효율적인 연결이다. 이러한 인장이음은 교량의 거더와 가로보의 이음, 주탑의 수평이음, 보-기둥 연결부, 바닥판 단부 2차부재 연결부, 브라켓 등에 적용될 수 있다. 본 연구에서는 인장이음의 역학적 거동을 파악하기 위해서 T-인장이음에 대한 정적실험을 수행하였다. 시험변수는 고장력 볼트의 직경, 플렌지 두께 및 체결력 감소이며, 인장이음의 파괴양상과 내력, 플랜지 두께와 고장력 볼트의 직경의 영향, 체결력의 영향에 대해 분석하였다.

파이프의 가스메탈아크 용접에 있어 센서 시스템을 이용한 용융지 제어 및 용접선 추적에 관한 연구 (A Study on control of weld pool and torch position in GMA welding of steel pipe by using sensing systems)

  • 배강열;이지형;정수원
    • Journal of Welding and Joining
    • /
    • 제16권5호
    • /
    • pp.119-133
    • /
    • 1998
  • To implement full automation in pipe welding, it si most important to develop special sensors and their related systems which act like human operator when detecting irregular groove conditions. In this study, an automatic pipe Gas Metal Arc Welding (GMAW) system was proposed to full control pipe welding procedure with intelligent sensor systems. A five-axes manipulator was proposed for welding torch to automatically access to exact welding position when pipe size and welding angle were given. Pool status and torch position were measured by using a weld-pool image monitoring and processing technique in root-pass welding for weld seam tracking and weld pool control. To overcome the intensive arc light, pool image was captured at the instance of short circuit of welding power loop. Captured image was processed to determine weld pool shape. For weld seam tracking, the relative distance of a torch position from the pool center was calculated in the extracted pool shape to move torch just onto the groove center. To control penetration of root pas, gap was calculated in the extracted pool image, and then weld conditions were controlled for obtaining appropriate penetration. welding speed was determined with a fuzzy logic, and welding current and voltage were determined from a data base to correspond to the gap. For automatic fill-pass welding, the function of human operator of real time weld seam control can be substituted by a sensor system. In this study, an arc sensor system was proposed based on a fuzzy control logic. Using the proposed automatic system, root-pass welding of pipe which had gap variation was assured to be appropriately controlled in welding conditions and in torch position by showing sound welding result and good seam tracking capability. Fill-pass welding by the proposed system also showed very successful result by tracking along the offset welding line without any control of human operator.

  • PDF

V-Ti계 수소저장합금의 전극특성 (Characteristics of electrodes using V-Ti based hydrogen storage alloys)

  • 김주완;이성만;백홍구
    • 한국결정성장학회지
    • /
    • 제7권2호
    • /
    • pp.284-291
    • /
    • 1997
  • V-Ti(V-rich) 수소저장합금을 기초(base)로 하여 2가지 타입(type)의 전극을 제조하였다. 첫째로 V-Ti 합금에 Ni 분말을 혼합하여 성형한 후 급속가열방법으로 소결하여 전극을 제조하였다. 둘째로 Ni을 V-Ti 합금과 합금화한 V-Ti-Ni 3원계 수소저장합금에 Ni, PTFE 분말을 혼합하여 냉간압축으로 성형하여 전극을 제조하였다. 이와같이 제조된 전극으로 싸이클에따른 충/방전 실험을 한 결과, 모든 전극에 있어 10싸이클 이내에 퇴화(degradation)가 일어났다. 충방전 실험후 전해질내의 조성분석결과 Ti에 비해 V이 많이 전해질 내에 용해되었으며 합금원소의 용해에 의한 표면 형상의 변화가 관찰되었고, 전극표면에 매우 passive 한 Ti-oxide($TiO_2$)가 형성되었다. Ti-oxide($TiO_2$)는 전기전도도가 매우 낮고, 수소에대한 확산계수(diffusivity)도 낮기때문에 전극표면에 형성된 $TiO_2$층은 충/방전 싸이클동안 방전용량을 크게 감소시키는 것으로 나타났다.

  • PDF

Evaluation of Grooving Corrosion and Electrochemical Properties of H2S Containing Oil/Gas Transportation Pipes Manufactured by Electric Resistance Welding

  • Rahman, Maksudur;Murugan, Siva Prasad;Ji, Changwook;Cho, Yong Jin;Cheon, Joo-Yong;Park, Yeong-Do
    • Corrosion Science and Technology
    • /
    • 제17권3호
    • /
    • pp.109-115
    • /
    • 2018
  • Electrical Resistance Welding (ERW) on a longitudinal seam-welded pipe has been extensively used in oil and gas pipelines. It is well known that the weld zone commonly suffers from grooving corrosion in ERW pipes. In this paper, the grooving corrosion performances of API X65 grade non-sour service (steel-A) and API X70 grade sour gas resistant (steel-B) steel electrical resistance welding pipelines were evaluated. The microstructure of the bondline is composed of coarse polygonal ferrite grains and several elongated pearlites. The elongated pattern is mainly concentrated in the center of the welded area. The grooving corrosion test and electrochemical polarization test were conducted to study the corrosion behavior of the given materials. A V-shaped corrosion groove was found at the center of the fusion zone in both the steel-A and steel-B ERW pipes, as the corrosion rate of the bondlines is higher than that of the base metal. Furthermore, the higher volume fraction of pearlite at the bondline was responsible for the higher corrosion rate at the bondline of both types of steel.

치과기공사국가시험 문항개발기준안연구 (Research for the Standard Model of the Items of the National Qualification Examination for the Dental Technician)

  • 이덕혜;정인성;한창식
    • 대한치과기공학회지
    • /
    • 제23권2호
    • /
    • pp.75-93
    • /
    • 2002
  • This research was preformed for the purpose of preparing the items of standard model of the national dental technician test base on the duty analysis of the dental technician. The results of the duty analysis for the dental technician follows. 1. The dental technician is a profession to make the oral function smooth through the dental supplement and equipment in a scientific method and the skilled technique. 2. The duty of the dental technician are determined as A. preparation for manufacture B. manufacture C. management of the place of the dental technology D. self-development. A. The field of "the preparation for manufacture" are determined as 1. to confirm work authorization 2. To confirm the working model, B. The field of "In manufacture" are determined as 1. to manufacture the temporary crown 2. to manufacture the inlay and crown & bridge prosthesis 3. to manufacture the porcelain fused metal crown prosthesis 4. to manufacture the all ceramic crown prosthesis 5. to manufacture the temporary denture prosthesis 6. to manufacture the partial denture prosthesis 7. to manufacture the complete denture prosthesis 8. to manufacture the attachment prosthesis 9. to manufacture implant prosthesis 10. to manufacture the removable orthodontic device, 11. to manufacture the fixed orthodontic device, 12. to manufacture the orthodontic study cast C. The field of "in management of the dental lab." are determined as 1. management 2. to control the dental lab. D. The field of "In the self-development" are determined as 1. to improve the professionalism 2. self-control. 3. The developing items selected under the duty evaluation of the dental technician are l7s in the manufacture preparation, 1,011s in the manufacture, 7s in the management for the dental technology, 5s in self-development, and in all together 1,040s

  • PDF

납착 인기재료가 분할 주조체의 변형에 미치는 영향 (THE EFFECT OF SOLDERING INDICES FOR THE DISTORTION OF SPLIT CAST)

  • 이동욱;임장섭;정창모;전영찬
    • 대한치과보철학회지
    • /
    • 제38권1호
    • /
    • pp.26-37
    • /
    • 2000
  • The purpose of this study was to investigate the effect that three resin indexing materials had on the distortion of split cast in the procedures of solder indexing and block fabrication. The specimen had two cylinders and connecting bar Two cylinders were a reference cylinder and a test cylinder that were machined precisely and placed on metal base. The total of specimens were 30 and they were divided into 3 groups according to the resin indexing materials : Acrylic $solder^{(R)}$, G-C Pattern $resin^{(R)},\;Z-100^{(R)}$. The relative coordinates (X, Y, Z) of centroids of both cylinders were measured by using 3-D cool dinates measuring machine. The value of indexing distortion was obtained after application of indexing material, and the value of the block distortion was obtained after fabrication of soldering block, and the value of total distortion was a value sum of indexing distortion and block distortion. Intercentroidal linear distortion ${(\sqrt{X^{'2}+Y^{'2}+Z^{'2}}-{\sqrt{X^2+Y^2+Z^2)}$ and global distortion $(\sqrt{{(X^'-X)}^2+{(Y^'-Y)}^2+{(Z^'-Z)}^2}$ were calculated from data of coordinates of centroids at each measuring stages. The results of this study were as belows ; 1. The intercentroidal distance between the split casts was reduced by indexing distortion and increased by block distortion. 2. The indexing global distortion between the split casts was smaller than block global distortion. 3. The intercentroidal linear distortion and the global distortion were no significant difference between indexing materials.

  • PDF