• 제목/요약/키워드: barrier membrane

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The Application of RO Membrane System in Municipal Wastewater Reclamation (RO Membrane System을 이용한 도시하수처리)

  • 이규현;안준수;유제강
    • Membrane Journal
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    • v.1 no.1
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    • pp.78-95
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    • 1991
  • Water factory 21(WF 2) in Orange County California, is a advanced wastewater treatment(AWT) plant designed to reclaim biologically treated munidpal wastewater for injection into a seawater barrier system. Processes included are lime treatment air stripping, filtration, activated carbon adsorption, reverse osmosis(RO), and chlorination. The effectiveness of each treatment process is presented including pretreatment, RO dimineralization. The data collected show that the processes, including RO, used at WF-21 are capable of producing a very high quality water on a reliable basis. Treatment reduced all contaminants, to levels below national primary drinldng water regulation maximum contaminant levels. It was found that lime clarified secondary effluent can be used as feedwater to a RO dimineralizer. Experiments with new low pressure membrane(250psi) show great potential for reducing RO cost.

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Membrane behavior of bentonite-amended compacted clay towards Zn(II) and Pb(II)

  • Tang, Qiang;Katsumi, Takeshi;Inui, Toru;Li, Zhenze
    • Membrane and Water Treatment
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    • v.6 no.5
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    • pp.393-409
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    • 2015
  • Zinc and lead pollution are public environmental issues that have attracted lots of attention for a long time. Landfill leachate contains heavy metals, such as Zn(II) and Pb(II), which are usually related to the pollution of groundwater, especially in developing countries. Bentonite has been proven to be effective in enhancing the membrane property of clay, by which landfill liners can have better barrier performance towards the migration of contaminants. In this study, 5% sodium bentonite amended with locally available Fukakusa clay was utilized to evaluate the membrane behavior towards the heavy metals zinc and lead. The chemico-osmotic efficiency coefficient, ${\omega}$, was obtained through Zn(II) and Pb(II) solutions with different concentrations of 0.5, 1, 5, 10, and 50 mM. According to the results, ${\omega}$ continually decreased as the Zn(II) and Pb(II) concentrations increased, which is consistent with the Gouy-Chapman theory. Compared to normal inorganic ions, the membrane behavior towards heavy metal ions was lower. The migration of heavy metal ions was not observed based on experimental results, which can be attributed to the adsorption or ion exchange reaction. The mechanisms of the membrane performance change were discussed with the assistance of XRD patterns, free swelling results, XRF results, and SEM images.

A study on the safety improvement of above ground membrane LNG storage tank (상지상식 멤브레인 액화천연가스 저장탱크의 안전성 향상 방안)

  • Lee, Seung Rim;Kim, Han Sang
    • Journal of Energy Engineering
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    • v.21 no.4
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    • pp.339-345
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    • 2012
  • RMembrane LNG storage tanks have been recently investigated to replace full-containment LNG storage tanks because of safety and cost aspects. Quantitative Risk Analysis (QRA) and Finite Element Method (FEM) were used to evaluate safety of membrane LNG storage tanks. In this study, structural safety evaluation results via FEM analysis showed that both membrane type and full-containment type cryogenic LNG storage tanks with 140,000 $m^3$ capacity were equivalently safe in terms of strength safety and leakage safety of a storage tank system. Also, Fault Tree Analysis (FTA) was used to improve the safety of membrane LNG storage tanks and membrane LNG tanks were modified by adding three safety equipments: impact absorber structure for the low part of the membrane, the secondary barrier to diminish the thermal stress of the corner part of the outer tank, and a pump catcher in case of falling of a pump. Consequently, the safety of the modified membrane LNG storage tanks were proved to be equivalent to that of full-containment LNG storage tanks.

Evaluation of Mechanical Performance of Membrane Type Secondary Barrier Anisotropic Composites depending on Fiber Direction (멤브레인 형 2차 방벽 이방성 복합재료의 섬유방향에 따른 기계적 성능 평가)

  • Jeong, Yeon-Jae;Kim, Jeong-Dae;Hwang, Byeong-Kwan;Kim, Hee-Tae;Oh, Hoon-Gyu;Kim, Yong-Tai;Park, Seong-Bo;Lee, Jae-Myung
    • Journal of the Society of Naval Architects of Korea
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    • v.57 no.3
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    • pp.168-174
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    • 2020
  • Recently, the size of Liquified Natural Gas (LNG) carriers has been increasing, in turn increasing the load generated during operation. To handle this load, the thickness of LNG Cargo Containment Systems (CCSs) should be increased. Despite increasing the thickness of LNG CCSs, a secondary barrier is still used in conventional thickness. Therefore, the mechanical performance of the existing secondary barrier should be verified. In this study, tensile test of the secondary barrier was performed to evaluate mechanical properties under several low- and cryogenic-temperature conditions considering LNG environment, and in each fiber direction considering that the secondary barrier is composed of anisotropic composite materials depending on the glass fibers. Additionally, the coefficient of thermal expansion was measured by considering the degradation of the mechanical properties of the secondary barrier caused by the generated thermal stress during periodical unloading. As a result, the mechanical performance of secondary barrier in the Machine Direction (MD) was generally found to be superior than that in the Transverse Direction (TD) owing to the warp interlock structure of the glass fibers.

The preparation of skin analogue composition having the liquid crystalline structure and its cosmetic applications

  • Lee, Dong-Kyu;Jeong, Kwan-Young
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.2
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    • pp.215-224
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    • 2013
  • Recently, many cosmetic researchers have been focused on the development of high functional cosmetics including anti-wrinkle and whitening. In these studies, they couldn't afford to pay a deep attention to stable encapsulations for unstable materials and efficient drug deliveries for them. Particularly, in order to show a degree of instant effects as cosmetics, they can't also ignore moisturizing effect enough to satisfy customers just after applying and its maintenance by improving the function of skin barrier as well as above two effects. Therefore, skin analogue systems have attracted considerable attention in the view of structural and compositional similarity to intercellular membrane in stratum corneum. And, some models for skin analogue composition were developed to improve the function of skin barrier, stably encapsulate unstable materials such as retinol, vitamin B, C, E, etc., and control their skin penetration in order to show good effects as cosmetics. In this study, we suggest the new skin analogue model having the compositional similarity as well as conventional structural ones. Our skin analogue membrane(SAM) is mainly composed of ceramide/ cholesterol/phosphatidylcholin/fatty acids and its structural defects are compensated by including cholesterol amphiphile and controlling the ratio of ceramide/cholesterol. It was possible to confirm the formation of skin analogue membrane having highly-densed multilamella structure and compare them according to the change of each ratio with a polarized microscope, X-ray diffraction. More detaily, we observed their structures with a electron microscope(TEM). Finally, we dispersed them in excess of continuous water phase, observed the formation of maltese-cross liquid crystalline and measured the efficiency of drug deliveries and moisturizing effects.

Bacterial attachment and penetration to Tetracycline-treated resorbable and nonresorbable membranes for GTR (테트라싸이클린 처리된 흡수성 및 비흡수성 조직유도재생술용 막에의 세균부착과 침투양상)

  • Lee, Ho-Jae;Chung, Hyun-Ju
    • Journal of Periodontal and Implant Science
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    • v.27 no.1
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    • pp.19-43
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    • 1997
  • The barrier membranes for GTR procedure could be affected bY bacterial contamination after exposure to oral environment. This study was done to evaluate whether the tetracycline impregnated barrier membranes could inhibit bacterial attachment and penetration into membranes. The resorbable membrane(polylactic and polyglycolide copolymer, $Resolute^{(R)}$, W.L Gore and Associates, Inc..USA) and the non-resorbable membrane(e-PTFE; Gore-TexTM, W.L. Gore & Associates, Inc.,USA) were cut into 4mm discs and trated with 5% tridodecylmethylammonium chloride solution in ethanol and dried in air. The membranes were immersed in tetracycline(TC) solution (100mg/ml, pH 8.0) and dried. To the maxillary canine-premolar region in six periodontally healthy volunteers, removable acrylic devices were inserted, on which 8 cylindrical chambers were glued with TC impregnated and non-impregnated discs, the membrane discs were examined for bacterial attachment and penetration, and structural changes under SEM and LM. From the 1st day to the 7th day, membranes showed bacterial plaque formation composed of cocci and rods. Thereafter, filamentous bacteria appeared and the plaque thickness increased. The TC impregnated e-PTFE membranes showed less bacterial attachment and delayed in bacterial plaque maturation than non-treated membranes. As for bacterial penetration, the TC impregnated e-PTFE membranes showed superficial invasion and infrequent presence of bacteria in unexposed inner surface at the 4th week. while the non-treated e-PTFE membranes showed deep bacterial invasion at the 2nd week and frequent presence of internal bacteria at the 4th week. The resorbable membranes started to be resorbed at the 2nd week and were perforated at the 4th week, regardless of TC treatment. In conclusion, bacterial plaque formation and penetration was efficiently delayed in TC impregnated e-PTFE membranes, whereas resorbable membranes were similar in bacterial invasion due to membrane degradation and perforation, regardless of TC treatment.

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Clinical Effect of Guide Bone Regeneration of Mandibular Nonunion in a Geriatric Dog (노령견의 하악골절 불유합 1례에서 골유도재생술의 임상적 효과)

  • Kim, Se-Eun;Shim, Kyung-Mi;Bae, Chun-Sik;Choi, Seok-Hwa;Jeong, Soon-Jeong;Kang, Seong-Soo
    • Journal of Veterinary Clinics
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    • v.30 no.2
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    • pp.127-130
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    • 2013
  • A 13-year-old, 4.2 kg female poodle was referred for failure of first bilateral mandibular surgery at a local animal hospital after pathologic fracture. Surgery was performed with 2.0-mm miniplates/screws and porcine cancellous bone grafts. In addition, because of the large size of the right segmental defect, a barrier absorbable membrane was employed for guide bone regeneration on right mandible. After surgery, follow-ups performed at 1 day, 1, 4, 8, and 12 weeks; there were no signs of dental malocclusion, nonunion or soft tissue infection. However, a 1-year long-term follow-up showed nonunion in the left mandibular fracture site for which a collagen membrane had not been used. It is considered that use of porcine bone graft with barrier absorbable membrane may be effective for the repair of mandibular nonunion in a geriatric dog.

Preparation of pore-filling membranes for polymer electrolyte fuel cells and their cell performances (고분자 연료전지용 세공충진막의 제조 및 연료전지 특성)

  • Choi, Young-Woo;Park, Jin-Soo;Lee, Mi-Soon;Park, Seok-Hee;Yang, Tae-Hyun;Kim, Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.278-281
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    • 2009
  • Proton exchange membrane is the key material for proton exchange membrane fuel cells (PEMFC). Currently widely-used perfluorosulfonic acid membranes have some disadvantages, such as low thermal stability, easy swelling, excessive crossover of methanol and high price etc. Other membranes, including sulfonated polymer, radiation grafted membranes, organic-inorganic hybrids and acid-base blends, do not satisfy the criteria for PEMFC, which set a barrier to the development and commercialization of PEMFC. Pore-filling type proton exchange membrane is a new proton exchange membrane, which is formed by filling porous substrate with electrolytes. Compared with traditional perfluorosulfonic acid membranes, pore-filling type proton exchange membranes have many advantages, such as non- swelling, low methanol permeation, high proton conductivity, low cost and a wide range of materials to choose. In this research, preparation methodology of pore-filling membranes by particularly using all hydrocarbon polymers and fuel cell performances with the membranes are evaluated.

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Perfluorinated Sulfonic Acid Ionomer Membranes for Valued Chemical Production (과불소계 술폰화 이오노머막을 이용한 고부가가치 화학품 제조)

  • Shim, Jae Goo;Park, In Kee;Lee, Chang Hyun
    • Membrane Journal
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    • v.26 no.2
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    • pp.152-158
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    • 2016
  • The Chlor-alkali (CA) membrane cell is a major electrolysis system to produce valued chemicals such as chlorine gas and sodium hydroxide. The CA membrane process has been attracted in the industries, since it has relatively low energy consumption when compared with other CA processes. The key component in CA process is perfluorinated sulfonic acid ionomer membranes, which provide ion-selectivity and barrier properties to produced gases. Unfortunately, there is limited information to determine which factors should be satisfied for CA applications. In this study, the influences of PFSA membranes on CA performances are disclosed. They include ion transport behaviors, gas evolution capability, and chemical/electrochemical resistances under CA operation conditions.

Influence of biodegradable polymer membrane on new bone formation and biodegradation of biphasic bone substitutes: an animal mandibular defect model study

  • Ku, Jeong-Kui;Kim, Young-Kyun;Yun, Pil-Young
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.42
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    • pp.34.1-34.7
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    • 2020
  • Purpose: The purpose of this study was to evaluate the influence of biodegradable polycaprolactone membrane on new bone formation and the biodegradation of biphasic alloplastic bone substitutes using animal models. Materials and methods: In this study, bony defect was formed at the canine mandible of 8 mm in diameter, and the defects were filled with Osteon II. The experimental groups were covered with Osteoguide as barrier membrane, and the control groups were closed without membrane coverage. The proportion of new bone and residual bone graft material was measured histologically and histomorphometrically at postoperative 4 and 8 weeks. Results: At 4 weeks, the new bone proportion was similar between the groups. The proportion of remaining graft volume was 27.58 ± 6.26 and 20.01 ± 4.68% on control and experimental groups, respectively (P < 0.05). There was no significant difference between the two groups in new bone formation and the amount of residual bone graft material at 8 weeks. Conclusion: The biopolymer membrane contributes to early biodegradation of biphasic bone substitutes in the jaw defect but it does not affect the bone formation capacity of the bone graft.