• Journal of the Korean Electrochemical Society
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• v.9 no.2
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• pp.64-69
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• 2006

Cathode materials of Al-doped $Li(Ni_{1/3}Co_{1/3}Mn_{1/3-x}Al_x)O_2$ (x=0.0, 0.005, 0.01 0.05) for lithium ion batteries were synthesized with ultra-sonic spray pyrolysis method and single-step heat treatment. No secondary phases were found in all synthesized powders. The intensity ratio of $I_{003}\;to\;I_{104}$, however, slightly decreased and the particle size increased with the Al contents. The cells with bare, 0.5 and 1.0 at% Al-doped powders showed the initial discharge capacities of 182, 180 and $184mAhg^{-1}$ in a voltage range of $3.0\sim4.5V$ at 1C rate, and the capacity retentions of 81, 77 and 78% at the end of 30 cycles, respectively. But in the voltage range of $3.0\sim4.6V$, the Al-doping significantly enhanced the cycle stability. For example, the discharge capacity after 50 cycles was maintained to 70% in the 0.5 at% Al-doped sample compared to only 30% in no doped sample. The improvement of the cycle stability was thought to be due to $Mn^{3+}$ ion decrease as the Al doping from the XPS analysis results.

• Journal of Korean Society of Forest Science
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• v.109 no.3
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• pp.281-290
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• 2020

The purpose of this study was to determine the optimal planting density for Zelokva serrata plantations. The study sites were located in Gyeongsan (GS) and Sunchang (SC), Korea. One-year-old, bare-root seedlings were planted at densities of 3,000; 5,000; 7,000; and 10,000 trees ha^-1 at the end of March 2015. We measured the root collar diameter and height each September from 2015 to 2019, and then calculated the H/D ratio and stem volume. The root collar diameter and height increased with increased planting density, and the stem volume was significantly higher at 10,000 trees ha^-1 than those at the other planting densities. Planting density did not affect the survival rate or H/D ratio. The root collar diameter, height, and stem volume were higher in GS than those in SC five years after planting. This study highlights that early growth performance was improved at increased planting densities at both sites. This study suggests that the initial planting density of 10,000 trees ha^-1 is suitable to improve the early growth performance of Z. serrata plantations, and that the improved growth performance at higher planting densities may be a silvicultural characteristic of Z. serrata.

• The Journal of Korea Institute of Information, Electronics, and Communication Technology
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• v.8 no.1
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• pp.37-44
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• 2015

In this paper, we have investigated a selective assembly method of single-walled carbon nanotubes (SWCNTs) on a silicon substrate using only photolithographic process and then proposed a fabrication method of field effect transistors (FETs) using SWCNT-based patterns. The aminopropylethoxysilane (APTES) patterns, which are formed for positively charged surface molecular patterns, are utilized to assemble and align millions of SWCNTs and we can more effectively assemble on a silicon (Si) surface using this method than assembly processes using only the 1-octadecyltrichlorosilane (OTS). We investigated a selective assembly method of SWCNTs on a Si surface using surface-programmed APTES and OTS patterns and then a fabrication method of FETs. photoresist(PR) patterns were made using photolithographic process on the silicon dioxide (SiO2) grown Si substrate and the substrate was placed in the OTS solution (1:500 v/v in anhydrous hexane) to cover the bare SiO2 regions. After removing the PR, the substrate was placed in APTES solution to backfill the remaining SiO2 area. This surface-programmed substrate was placed into a SWCNT solution dispersed in dichlorobenzene. SWCNTs were attracted toward the positively charged molecular regions, and aligned along the APTES patterns. On the contrary, SWCNT were not assembled on the OTS patterns. In this process, positively charged surface molecular patterns are utilized to direct the assembly of negatively charged SWCNT on SiO2. As a result, the selectively assembled SWCNT channels can be obtained between two electrodes(source and drain electrodes). Finally, we can successfully fabricate SWCNT-based multi-channel FETs by using our self-assembled monolayer method.

• Journal of the Korean Chemical Society
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• v.40 no.7
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• pp.467-473
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• 1996

Although a polypyrrole shows better electrical conductivity, 100∼400 ${\Omega}^{-1}cm^{-1}$, than other organic conducting polymers, its electrical conductivity will be worsen in the presence of the oxygen due to its easy oxidation. On the other hand, polythiophene shows better stability in the air while its electrcal conductivity is poor compared to the polypyrrole. We succeed to develope the mixed polymer electrode that is stable in the air and shows a good redox characteristics. The mixed polymer electrode has been prepared by the electrical polymerization of polypyrrole on the Pt electrode as 1.70 C$cm^{-2}$ and then coating with polythiophene as 0.34 C$cm^{-2}$. The polymerization rate of polythiophene was $3.89{\times}10^{-8}$ at the bare Pt electrode and $6.07{\times}10^{-8}cms^{-1}$ at the mixed polymer electrode. And the standard rate constants of each electrode were $5.16{\times}10^{-6}\;and\;3.94{\times}10^{-4} cms^{-1}$ respectively. Also, the electrocatalytic rate of the polypyrrole polymer electrode was $3.45{\times}10^{-3}cm^3mol^{-1}s^{-1}.$ We found the immobilized layer at the modified electrode acted as an electrocatalyst. Finally, this polymerization process at the Pt electrode was the electron transfer controlled, but that the mixed polymer electrode was the diffusion and charge transfer controlled.

• Journal of the Korean Chemical Society
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• v.41 no.2
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• pp.98-104
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• 1997

A simple, accurate and reproducible capillary electrophoresis(CE) assay has been developed for the determination of berberine, cinnamic acid, and glycyrrhizin which are used in traditional Korean medicinal preparations. Separation of these compounds was performed in 20 mM phosphate buffer(pH 7.5) and acetonitrile(75:25, v/v) using a bare fused silica capillary($57 cm{\times}75 {\mu}m$ i.d.) at 25$^{\circ}C$. With the electric field of 350 V/cm, the time needed for the separation of berberine, cinnamic acid and glycyrrhizin was within 13 min. Calibration curves were linear for 1∼100 ${\mu}g/mL$ berberine, 0.3∼100 ${\mu}g/mL$ cinnamic acid and 2.5∼100 ${\mu}g/mL$ glycyrrhizin. The ranges of relative standard deviations(n=5) for those samples were between 0.96∼2.35%. The limits of detection(S/N=3) for berberine, cinnamic acid and glycyrrhizin were 0.5, 0.1 and 2.0 ${\mu}g/mL$, respectively. The numbers of theoretical plates were 181,000(berberine), 88,000(cinnamic acid) and 169,000(glycyrrhizin), while they were 3,100∼4,800 in HPLC.

• Korean Journal of Environment and Ecology
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• v.19 no.2
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• pp.130-138
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• 2005

The purpose of this study is to analyze the trail deterioration conditions and to obtain the informations for the desirable maintenance and restoration of the trails in Woraksan National Park. To accomplish the purpose, not only trail condition such as altitude, entire width, bare width, maximum depth and slope of trail, but also deterioration types of trail were surveyed at the total 111 points for 13.5km in length on the four access trails to Yeongbong which is the main peak of Woraksan. Furthermore, impact rating class, which could be effective means to check the step and extent of deterioration process, was judged on each points of trail. Results informs us that the deterioration condition of the trail in Woraksan National Park is not reached the lev- el of grave concern yet, but the active counterplan to change over from the safety-centric facility station to the integrated and organized restoration aiming to natural environment conservation is urgently needed.

• Korean Journal of Environment and Ecology
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• v.20 no.4
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• pp.493-502
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• 2006

This study analyzed greenspace structure focused on greenspace areas and vegetation structure for Yanggu, investigated resident attitudes to the greenspace, and explored strategies to improve greenspace functions in a rural region. Woody plant cover was approximately 29% for parks and only 3% for commercial gardens. The amount of planting for Yanggu was poor, as compared with the results of similar studies for urban areas. Trees, of which dbh was below 20cm, accounted for 91% of all trees and the tree-age structure was largely characterized by a young, growing tree population. Based on the analysis of mean importance values (MIV) of woody plant species, only a few were different in dominant species from urban areas. Four species among 10 species with highest MIV in Yanggu were very common species also ranked among 10 in cities. The most dominant species planted in residential and commercial gardens were practical plants such as fruit or edibles. Greenspace covered about 69% of parks, 39% of residential gardens, 37% of institutional gardens, 24% of streets, and 15% of commercial gardens, respectively. Tree planting potential revealed that present woody plant cover can be increased additionally by 6 times in the streets and by 2 times in the residential and commercial gardens. Based on the results of greenspace structure, planting patterns, and questionary investigation, some strategies were suggested to enlarge greenspace including its environmental functions. They included identifying each street section through setting up themes and planting appropriate species, creating multilayered vegetation structures, and promoting planting in bare grounds of gardens and around a buildings for saving energy.

• Korean Journal of Environment and Ecology
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• v.16 no.4
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• pp.465-474
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• 2003

According to rapid increase of visitors to the Baekdudaegan, the most important ecosystem in Korea, fur climbing or outdoor recreation, deterioration of natural environment along the trail on the ridge of Baekdudaegan is becoming more serious. The purpose of this study is to research the deterioration condition of the trail between Manbokdae and Bokseongijae on the Baekdudaegan with intent to prepare the conservational management strategy fur the trail on the ridge of Baekdudaegan. To accomplish the purpose, not only trail condition such as altitude, entire width, bare width, maximum depth and slope of trail, but also deterioration types of trail were surveyed at the total 232 points for 28.4km in length. Furthermore, impact rating class, which could be effective means to check the step and extent of deterioration process, was judged on each points of trail. Putting together these results informs us that the deterioration condition of the trail between Manbokdae and Bokseongijae is not reached the level of grave concern yet, but prompt countermeasure to maintain the existing condition has to be considered with regard for the conditions of location and the increasing amounts of use.

• Journal of Wetlands Research
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• v.11 no.1
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• pp.123-130
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• 2009

Hyporheic zone is an area where hydraulic exchanges occur between surface water and ground water. Such transient area is anticipated to facilitate diverse biogeochemical reactions by providing habitats for various microorganism. However, only a few data are available about microbial properties in hyporheic zone, which would be important in better understanding of biogeochemical reactions in whole streams. The study site is Naesung stream, located in the north Kyoung-Sang Province, of which sediment is sandy with little anthropogenic impacts. Soil samples were collected from a transect placed perpendicular to stream flow. The transect includes upland fringe area dominated by Phragmites japonica, bare soil, and soil adjacent to water. In addition, soil samples were also collected from downwelling and upwelling areas in hyporheic zone within the main channel. Soils were collected from 3 depth in each area, and water content, pH, and DOC were measured. Various microbial properties including extracellular enzyme activities ($\beta$-glucosidase, N-acetylglucosaminidase, phosphatase and arylsulfatase), and microbial community structure using T-RFLP were also determined. The results exhibited a positive correlation between water content and DOC, and between extracellular enzyme activities and DOC. Distinctive patterns were observed in soils adjacent to water and hyporheic zone compared with other soils. Overall results of study provided basic information about microbial properties of hyporheic zone, which appeared to be discernable from other locations in the stream corridor.

• Journal of Cadastre & Land InformatiX
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• v.50 no.1
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• pp.75-85
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• 2020

This study examines machine learning cross-validation to utilized create ROI for classification of land cover. The study area located in Sejong and one KOMPSAT-3A image was used in this analysis: procedure on October 28, 2019. We used four bands(Red, Green, Blue, Near infra-red) for learning cross validation process. In this study, we used K-fold method in cross validation and used SVM kernel type with cross validation result. In addition, we used 4 kernels of SVM(Linear, Polynomial, RBF, Sigmoid) for supervised classification land cover map using extracted ROI. During the cross validation process, 1,813 data extracted from 3,500 data, and the most of the building, road and grass class data were removed about 60% during cross validation process. Based on this, the supervised SVM linear technique showed the highest classification accuracy of 91.77% compared to other kernel methods. The grass' producer accuracy showed 79.43% and identified a large mis-classification in forests. Depending on the results of the study, extraction ROI using cross validation may be effective in forest, water and agriculture areas, but it is deemed necessary to improve the distinction of built-up, grass and bare-soil area.