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Fluxless Bonding Method between Sn and In Bumps Using Ag Capping Layer (Ag층을 이용한 Sn과 In의 무 플럭스 접합)

  • Lee Seung-Hyun;Kim Young-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.11 no.2 s.31
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    • pp.23-28
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    • 2004
  • We utilized Ag capping layer for fluxless bonding. To investigate the effect of Ag capping layer, two sets of sample were used. One set was bare In and Sn solders. The other set was In and Sn solders with Ag capping layer. In ($10{\mu}m$) and Sn ($10{\mu}m$) solders were deposited on Cu/Ti/Si substrate using thermal-evaporation, and Ag ($0.1{\mu}m$) capping layers were deposited on In and Sn solders. Solder joints were made by joining two In and Sn deposited specimens at $130^{\circ}C$ for 30 s under 0.8, 1.6, 3.2 MPa using thermal compression bonder. The contact resistance was measured using four-point probe method. The shear strength of the solder joints was measured by the shear test of cross-bar sample in the direction. The microstructure of the solder joints was characterized with SEM and EDS. In and Sn solders without Ag capping layers were only bonded at $130^{\circ}C$ under high bonding pressure. Also the shear strength of the In-Sn solder joints under was lower than that of the Ag/In-Ag/Sn solder joints. The resistance of the solder joints was $2-4\;m{\Omega}$ The solder joints consisted of In-rich phase and Sn-rich phase and the intermixed compounds were found at the interface. As bonding pressure increased, the intermixed compounds formed more.

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Endothermic Forster Energy Transfer from DPVBi to BCzVBi in High Efficient Blue Organic Light-Emitting Diodes (고효율 청색 유기발광다이오드의 DPVBi와 BCzVBi 사이에서 발생하는 흡열 페르스터 에너지전이)

  • Kim, You-Hyun;Lee, Sang-Youn;Song, Wook;Shin, Sung-Sik;Ryu, Dae-Hyun;Wood, Richard;Yatulis, Jay;Kim, Woo-Young
    • Journal of the Korean Chemical Society
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    • v.54 no.3
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    • pp.291-294
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    • 2010
  • In this study, we demonstrated high-efficiency blue organic light-emitting diodes (OLEDs) employing BCzVBi as a blue fluorescent dye doped into blue host material, DPVBi with various concentration. The optimized blue OLED device having high-efficiency was constructed with structure of NPB (500 ${\AA}$) / DPVBi:BCzVBi-6% (150 ${\AA}$)/$Alq_3$(300 ${\AA}$) / Liq (20 ${\AA}$) / Al (1000 ${\AA}$). The maximum luminescence of blue OLED was 13200 cd/$m^2$ at 13.8 V and current density and maximum efficiency were 26.4 mA/$cm^2$ at 1000 cd/$m^2$ and 4.24 cd/A at 3.9 V, respectively. Luminous efficiency shows two times higher than comparing with non-doped BCzVBi blue OLED whereas $CIE_{x,y}$ coordinate was similar with bare DPVBi blue OLED such as (0.16, 0.19). Electroluminescence of BCzVBi-6% doped blue OLED has two major peaks at 445 nm and 470 nm whereas pure DPVBi's blue peak appears at 456 nm and it is happened through endothermic Forster energy transfer by molecule's vibration between LUMO of DPVBi as host material and LUMO of BCzVBi as dopant in device.

Effects of Composite Floor Slab on Seismic Performance of Welded Steel Moment Connections (철골모멘트 용접접합부의 내진성능에 미치는 합성슬래브의 영향)

  • Lee, Cheol Ho;Jung, Jong Hyun;Kim, Jeong Jae
    • Journal of Korean Society of Steel Construction
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    • v.26 no.5
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    • pp.385-396
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    • 2014
  • Traditionally, domestic steel design and construction practice has provided extra shear studs to moment frame beams even when they are designed as non-composite beams. In the 1994 Northridge earthquake, connection damage initiated from the beam bottom flange side was prevalent. The upward moving of the neutral axis due to the composite action between steel beam and floor deck was speculated to be one of the critical causes. In this study, full-scale seismic testing was conducted to investigate the side effects of the composite action in steel seismic moment frames. The specimen PN700-C, designed following the domestic connection and floor deck details, exhibited significant upward shift of the neutral axis under sagging (or positive) moment, thus producing high strain demand on the bottom flange, and showed a poor seismic performance because of brittle fracture of the beam bottom flange at 3% story drift. The specimen DB700-C, designed by using RBS connection and with the details of minimized floor composite action, exhibited superior seismic performance, without experiencing any fracture or concrete crushing, almost identical to the bare steel counterpart (specimen DB700-NC). The results of this study clearly indicate that the beams and connections in seismic steel moment frames should be constructed to minimize the composite action of a floor deck if possible.

On-stream Activity and Surface Chemical Structure of CoO2/TiO2 Catalysts for Continuous Wet TCE Oxidation (습식 TCE 분해반응에서 CoO2/TiO2 촉매의 반응활성 및 표면화학적 구조)

  • Kim Moon Hyeon;Choo Kwang-Ho
    • Journal of Environmental Science International
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    • v.14 no.2
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    • pp.221-230
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    • 2005
  • Catalytic wet oxidation of trichloroethylene (TCE) in water has been conducted using $TiO_2-supported$ cobalt oxides at $36^{\circ}C$ with a weight hourly space velocity of $7,500\;h^{-1}.\;5\%\;CoO_x/TiO_2$, prepared by using an incipient wetness technique, might be the most promising catalyst for the wet oxidation although it exhibited a transient behavior in time on-stream activity. Not only could the bare support be inactive for the wet decomposition reaction, but no TCE removal also occurred by the process of adsorption on $TiO_2$ surface. The catalytic activity was independent of all particle sizes used, thereby representing no mass transfer limitation in intraparticle diffusion. XPS spectra of both fresh and used Co surfaces gave different surface spectral features for each $CoO_x,\;Co\;2P_{3/2}$ binding energy for Co species in the fresh catalyst appeared at 781.3 eV, which is very similar to the chemical states of $CoTiO_x$ such as $CO_2TiO_4\;and\;CoTiO_3$. The used catalyst exhibited a 780.3-eV main peak with a satellite structure at 795.8 eV. Based on XPS spectra of reference Co compound, the TCE-exposed Co surfaces could be assigned to be in the form of mainly $Co_3O_4$. XRD patterns for $5\%\;CoO_x/TiO_2$ catalyst indicated that the phase structure of Co species in the catalyst even before reaction is quite comparable to the diffraction lines of external $Co_3O_4$ standard. A model structure of $CoO_x$ present predominantly on titania surfaces would be $Co_3O_4$, encapsulated in thin-film $CoTiO_x$ species consisting of $Co_2TiO_4$ and $CoTiO_3$, which may be active for the decomposition of TCE in a flow of water.

A Study on Oxygen Evolution Activity of Co3O4 with different morphology prepared by Ultrasonic Spray Pyrolysis for Water Electrolysis (분무열분해로 합성한 수전해용 Co3O4의 입자형태에 따른 산소발생 활성에 관한 연구)

  • Kim, Ingyeom;Nah, In Wook;Park, Sehkyu
    • Korean Chemical Engineering Research
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    • v.54 no.6
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    • pp.854-862
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    • 2016
  • As the demand for a clean energy to replace fossil fuel being depleted increases, hydrogen energy is considered as a promising candidate for future energy source. Water electrolysis which produces hydrogen has high energy efficiency and stability but still has a large overpotential for oxygen evolution reaction (OER). In this study, $Co_3O_4$ catalysts with different morphology were prepared by spray pyrolysis from solutions which contain Co precursor and various organic additives (urea, sucrose, and citric acid), followed by post heat treatment. For the catalysts synthesized, X-ray diffraction (XRD) measurements were performed to identify their crystal structure. Morphology and surface shape of the catalysts were observed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Surface area and pore volume were examined by nitrogen adsortpion & desorption tests and X-ray photoelectron spectroscopy (XPS) was conducted to confirm nitrogen doping. Linear sweep voltammetry (LSV) was carried out to investigate OER activity of $Co_3O_4$ catalysts. As a result, bare-$Co_3O_4$ which has high surface area and small particle size determined by spray pyrolysis showed high activity toward OER.

Effect of Vinyl Ethylene Carbonate on Electrochemical Characteristics for Activated Carbon/Li4Ti5O12 Capacitors (활성탄/리튬티탄산화물 커패시터의 전기화학적 특성에 미치는 비닐에틸렌카보네이트의 영향)

  • Kwon, Yong-Kab;Choi, Ho-Suk;Lee, Joong-Kee
    • Journal of the Korean Electrochemical Society
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    • v.15 no.3
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    • pp.190-197
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    • 2012
  • We employed the vinyl ethylene carbonate (VEC) as an electrolyte additive and investigated the effect of the electrolyte additive on the electrochemical performance in hybrid capacitor. The activated carbon was adopted as cathode material, and the $Li_4Ti_5O_{12}$ oxide was used as anode material. The electrolyte was prepared with the $LiPF_6$ salt in the mixed solvent of ethylene carbonate (EC), dimethyl carbonate (DMC), and ethyl methyl carbonate(EMC). We evaluated the electrochemical performance of the hybrid capacitor with increasing the amount of the VEC electrolyte additive, which is known as the remover of oxygen functional group and the stabilizer of the electrode by reducing the surface of electrode, and obtained the superior performance data especially at the addition of the VEC electrolyte additive of around 0.7 vol%. On the contrary, the addition of the VEC more than 0.7 vol% in the electrolyte leads to the degradation in electrochemical performance of hybrid capacitor, suggesting the increase of the side reaction from the excessive VEC additive. X-ray photoelectron spectroscopy (XPS) revealed that the addition of the VEC suppressed the formation of LiF component, which is known as the insulator, on the surface of electrode. The optimized addition of VEC exhibited the improved capacity retention around 82.7% whereas the bare capacitors without VEC additive showed the 43.2% of capacity retention after 2500 cycling test.

Fundamental Model Development for Rehabilitation of the Roadside Slopes (도로(道路)비탈면의 경관안정(景觀安定)을 위한 기본(基本)모델 설정(設定)에 관한 연구(硏究))

  • Woo, Bo Myeong
    • Journal of Korean Society of Forest Science
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    • v.61 no.1
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    • pp.69-79
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    • 1983
  • To develope the fundamental models suitable for slope stabilization and scenic effect improvement of the roadside slopes, this study has continuously been conducted for last about 10 years through the field survey and observations on the roadside slopes of 100 plots located in the Capital region. The results obtained could be summarized as follows: 1) In general, due to unsuitable treatments and constructions to the man-made bare slope characteristics of the roadsides, the treatment aims for stabilizing and improving the scenic beauty of the slopes have not been successfully reached in the surveyed regions. 2) Particularly, because of insufficiency of the follow-up maintenance techniques to the roadside slopes treated, denudations of slope scenery established as well as the withering of the vegetation planted have been accelerated for the most part of the slopes treated. 3) 6 fundamental models for the roadside slope treatments have been developed and could be edaptable to the nation-wide purposes. The fundamental models are the model of forest scenery match plantation, roadside scenery establishment, denuded land rehabilitation, rock slope greenification, absolute stabilization, and environmental plantation belt establishment, respectively.

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Regional Dynamics of Capitalism in the Greater Mekong Sub-region: The Case of the Rubber Industry in Laos (메콩유역권 내 자본주의의 지역적 역동성: 라오스 고무산업의 사례)

  • Andriesse, Edo
    • Journal of the Korean Geographical Society
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    • v.50 no.1
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    • pp.73-90
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    • 2015
  • This article focuses on geo-institutional differentiation and a multi-scalar analysis of emerging capitalist development in Laos. It discusses the impact of the Greater Mekong Subregion on new institutional economic and economic geographical arrangements. It demonstrates the usefulness of the varieties of Asian capitalism approach. The rubber industry was chosen to unravel emerging but various sub-national institutional arrangements linked to higher scale levels. Rubber is a growing agribusiness industry throughout the country, led by the insatiable demand from China. Overall, this study shows that the capitalist development of the rubber industry features much geo-institutional differentiation, due to the different strategies of Chinese, Thai and Vietnamese investors. Since Laos is still in transition from a state-led economy to something else, it is impossible at this to identify the exact number capitalisms. Yet, the evidence on rubber clearly lays bare the presence of multiple institutional arrangements. Without more inclusiveness, however, the implications for regional development are worrying. Exclusive arrangements will most likely lead to more uneven regional development and higher regional inequality. To refine theories on sub-national varieties of capitalism in developing countries it is instructive to consider more explicitly the notion of regional personal capitalisms and the complex interplay between national and regional states and relationships between capital accumulation and livelihood analyses.

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A Study on Community Classification of Forest Vegetation in Mt. Naeyeon (내연산(內延山) 일대(-帶) 삼림식생(森林植生)의 군락분류(群落分類)에 관(關)한 연구(硏究))

  • Lee, Byung-Chun;Yun, Chung-Weon
    • The Korean Journal of Ecology
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    • v.25 no.3 s.107
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    • pp.153-161
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    • 2002
  • This study was carried out to classify forest vegetation of the Mt. Naeyeon with phytosociological analysis of ZM school and to explain ordination of communities with CCA. The research sites were located between the northern part of Pohang-si area and the southern part of Yeongdeok-gun area. The 70 plots consisted of 253 species were investigated. The forest vegetation was classified into Quercus mongolica community, Q. variabilis community, Pinus densiflora community, Carpinus laxiflora community and Zelkova serrata community. Q. mongolica community was divided into 2 groups such as Rhododendron schlippenbachii group and Euonymus oxyphyllus group and Q. variabilis community was divided into 3 groups such as Syneilesis palmata group, Lespedeza$\times$tomentilia group and Tilia mandshurica group, and Z. serrata community was divided into 2 groups such as Carpinus cordata group and Diospyros lotus group. According to the results of CCA ordination, Q. mongolica community showed high positive correlation to altitude and topography, whereas it showed negative correlation to bare rock. But Z. serrata community showed the opposite tendency to Q. mongolica community, Altitude was considered as the most important factor among 5 environmental variables in the correlation with axes.

Experimental Study on Pressure Loss of Flow Parallel to Rod Bundle with Spacer Grid (지지격자가 있는 봉다발과 축방향으로 평행한 유동의 압력손실에 관한 실험적 연구)

  • Lee, Chi-Young;Shin, Chang-Hwan;Park, Ju-Yong;In, Wang-Kee
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.7
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    • pp.689-695
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    • 2012
  • The friction factor in a rod bundle and the loss coefficient at a spacer grid were examined. As a test section, 25 smooth rods, 9.5 mm in diameter and 2000 mm in length, were prepared and installed in a $5{\times}5$ square array in a square channel. In this case, the P/D (Pitch-to-Diameter ratio) was 1.35. In this work, plain (i.e., no mixing vanes), split-vane, and hybrid-vane spacer grids were tested. In a bare rod bundle (i.e., no spacer grid), the measured friction factors were in good agreement with the previous correlations. Among the spacer grids tested, the hybrid-vane spacer grid presented the largest friction factor in the rod bundle and loss coefficient. This may be because of the flow pattern change induced by large relative plugging of the flow cross section and mixing vane geometry. At Re=$5{\times}10^5$, the predicted loss coefficients of plain, splitvane, and hybrid-vane spacer grids were approximately 0.79, 0.80, and 0.88, respectively.