• Title/Summary/Keyword: band energy

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Photocurrent Study on the Splitting of the Valence Band and Growth of $CdIn_2Te_4$ Single Crystal by Bridgman method (Bridgman법에 의해 성장된 $CdIn_2Te_4$ 단결정의 가전자 갈라짐에 대한 광전류 연구)

  • Baek, Seung-Nam;Hong, Kwang-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.347-351
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    • 2003
  • A p-$CdIn_2Te_4$ single crystal has been grown by the Bridgman method without a seed crystal in a tree-stage vertical electric furnace. From photocurrent measurements, it was found that three peaks, A, B, and C, corresponded to an intrinsic transition due to the band-to-band transition from the valence band states ${\Gamma}_7(A),\;{\Gamma}_6(B),\;and\;{\Gamma}_7(C)$ to the conduction band state ${\Gamma}_6$, respectively. Also, the valence band splitting of the $CdIn_2Te_4$ crystal has been confirmed by photocurrent spectroscopy. The crystal field splitting and the spin orbit splitting were obtained to be 0.2360 and 0.1119 eV, respectively. Also, the temperature dependence of the band gap energy of the $CdIn_2Te_4$ crystal has been driven as the following equation of $E_g(T)\;=E_g(0)\;-\;(9.43\;{\times}\;10^{-3})T^2/(2676\;+\;T)$. In this equation, the Eg(0) was estimated to be 1.4750, 1.7110, and 1.8229 eV at the valence band state A, B, and C, respectively. The band gap energy of the p-$CdIn_2Te_4$ at room temperature was determined to be 1.2023 eV.

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Multi-Band RF Energy Harvesting System Using Buck-Boost DC-DC Converter (Buck-Boost DC-DC Converter를 이용한 다중 대역 RF 에너지 수집 시스템)

  • Cho, Choon Sik
    • Journal of Satellite, Information and Communications
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    • v.12 no.2
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    • pp.89-93
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    • 2017
  • This paper introduces an energy harvesting system that generates energy by collecting multi-band RF signals using buck-boost DC-DC converter. In an environment where the resistance of load using the collected electric energy is constantly changing, a buck-boost DC-DC converter is used in which the input resistance of the DC-DC converter does not change even if the load resistance changes. Since the frequency band of the input RF signal varies, the rectifier is designed for each band so that multiple bands can be processed, and a matching circuit is added to each band in front of the rectifier. For a rectifier to collect very small RF signals, a circuit is designed so that a constant voltage is obtained according to a very small input signal by devising a method of continuously accumulating the voltages collected and generated in each band. It is confirmed that the output efficiency can reach up to 20% even for the RF signal having the input of -20 dBm.

Growth and photocurrent properties for the $AgInS_{2}$ epilayers by hot wall ep itaxy (Hot wall epitaxy 방법에 의한 $AgInS_{2}$ 박막의 성장과 광전류특성)

  • Hong, K.J.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.08a
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    • pp.92-96
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    • 2002
  • A silver indium sulfide $(AgInS_{2})$ epilayer was grown by the hot wall epitaxy method, which has not been reported in the literature. The grown $AgInS_{2}$ epilayer has found to be a chalcopyrite structure and evaluated to be high quality crystal. From the photocurrent measurement in the temperature range from 30 K to 300 K, the two peaks of A and B were only observed, whereas the three peaks of A, B, and C were seen in the PC spectrum of 10 K. These peaks are ascribed to the band-ta-band transition. The valence band splitting of $AgInS_{2}$ was investigated by means of the photocurrent measurement. The crystal field splitting, $\Delta_{cr}$, and the spin orbit splitting, $\Delta_{so.}$ have been obtained to be 0.150 eV and 0.009 eV at 10 K, respectively. And, the energy band gap at room temperature has been determined to be 1.868 eV. Also, the temperature dependence of the energy band gap, $E_{g}(T)$, was determined.

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Band-gap energy (Eo) measurements of semi-insulating GaAs by photoreflectance (Photoreflectance에 의한 반절연성 GaAs의 띠간격 에너지(Eo)측정)

  • 배인호;김말문;이정열;김인수;김기홍
    • Electrical & Electronic Materials
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    • v.7 no.6
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    • pp.490-495
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    • 1994
  • We investigated photoreflectance of semi-insulating GaAs with respect to modulation sources, that is, modulation beam intensity, modulation frequency, temperature, and thickness of sample. PR spectra by each modulation source turned out to be signals of low electric field third differential, and band gap values of sample were fitted by least square root method for Aspnes' theoretical equation.

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Radial deformation and band-gap modulation of pressurized carbon nanotubes

  • Taira, Hisao;Shima, Hiroyuki;Umeno, Yoshitaka;Sato, Motohiro
    • Coupled systems mechanics
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    • v.2 no.2
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    • pp.147-157
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    • 2013
  • We numerically investigate the electronic band structure of carbon nanotubes (CNTs) under radial corrugation. Hydrostatic pressure application to CNTs leads to a circumferential wave-like deformation of their initially circular cross-sections, called radial corrugations. Tight-binding calculation was performed to determine the band gap energy as a function of the amplitude of the radial corrugation. We found that the band gap increased with increasing radial corrugation amplitude; then, the gap started to decline at a critical amplitude and finally vanished. This non-monotonic gap variation indicated the metal-semiconductor-metal transition of CNTs with increasing corrugation amplitude. Our results provide a better insight into the structure-property relation of CNTs, thus advancing the CNT-based device development.

Platinum(Ⅱ) Complexes of 2,2$^\prime$-Diaminobinaphthyl

  • Jun Moo-Jin;Choi Sung Rack
    • Bulletin of the Korean Chemical Society
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    • v.6 no.4
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    • pp.214-217
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    • 1985
  • Platinum(II) complexes of R-2,2'-diaminobinaphthyl (R-dabn), [Pt(R-dabn)(H2O)2]Cl2, [Pt(R-dabn)(R-Pn)]Cl2, [Pt(R-dabn)(R-bn)]Cl2, and platinum(II) complexes of S-2,2'-diaminobinaphthyl (S-dabn), [Pt(S-dabn)(H2O)2]Cl2, [Pt(S-dabn)(S-Pn)]Cl2, and [(Pt(S-dabn)(S-bn)]Cl2 have been prepared. (R-Pn and S-Pn are, respectively R- and S isomer of 2,3-diaminobutane). R-Pn and S-bn are, respectively R and S isomer of 2,3-diaminopropane). In the vicinity of the B-absorption band region of dabn, the circular dichroism spectra of platinum(Ⅱ) complexes of R-dabn series show a positive B-band followed by a negative higher energy A-band, which is generally understood as the splitting pattern for a ${\lambda}$ conformation, while the circular dichroism spectra of platinum(Ⅱ) complexes of S-dabn series show a negative B-band followed by a positive higher energy A-band in the long-axis polarized absorption region as expected for a $\delta$ conformation.

Energy Dissipation and Transfer among Wave Components during Directional Breaking Processes (다방향 쇄파 발생 전후의 파랑 성분간 에너지 전이 및 소산)

  • 홍기용;에스똘히오메자
    • Journal of Ocean Engineering and Technology
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    • v.17 no.6
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    • pp.1-6
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    • 2003
  • Wave energy dissipation and energy transfer between wave components, during the directional wave breakings, are investigated. Directional incipient and plunging breakers were generated by focusing the multi-frequency and multi-directional wave components at a designed location, based on a constant wave amplitude and a constant wave steepness frequency spectrum. The time series of surface wave elevation was measured at 9 different locations around the wave focusing point, using a wave gauge array. In order to examine the variation of the directional spreading function, the horizontal velocity of fluid motion was also measured. By comparing energy spectrums, before and after the breaking, the characteristics of energy dissipation and energy transfer, caused by wave breaking, are investigated. Their dependencies on directionality, as well as frequency, are analyzed. The breakings significantly dissipate wave energy, through energy transfer, in the upper region of the peak-frequency band, while enhancing wave energy in the low-frequency band.

Prediction of hysteretic energy demands in steel frames using vector-valued IMs

  • Bojorquez, Eden;Astorga, Laura;Reyes-Salazar, Alfredo;Teran-Gilmore, Amador;Velazquez, Juan;Bojorquez, Juan;Rivera, Luz
    • Steel and Composite Structures
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    • v.19 no.3
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    • pp.697-711
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    • 2015
  • It is well known the importance of considering hysteretic energy demands for the seismic assessment and design of structures. In such a way that it is necessary to establish new parameters of the earthquake ground motion potential able to predict energy demands in structures. In this paper, several alternative vector-valued ground motion intensity measures (IMs) are used to estimate hysteretic energy demands in steel framed buildings under long duration narrow-band ground motions. The vectors are based on the spectral acceleration at first mode of the structure Sa($T_1$) as first component. As the second component, IMs related to peak, integral and spectral shape parameters are selected. The aim of the study is to provide new parameters or vector-valued ground motion intensities with the capacity of predicting energy demands in structures. It is concluded that spectral-shape-based vector-valued IMs have the best relation with hysteretic energy demands in steel frames subjected to narrow-band earthquake ground motions.

The Calculation of the Energy Band Gaps of Zincblende InAs1-X NX on Temperature and Composition (온도 및 조성비 변화에 따른 질화물계 화합물 반도체 InAs1-X NX의 에너지 밴드갭 계산)

  • Chung, Ho-Yong;Kim, Dae-Ik
    • The Journal of the Korea institute of electronic communication sciences
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    • v.11 no.12
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    • pp.1165-1174
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    • 2016
  • The energy band gaps and the bowing parameters of zincblende InAs1-xN are determined by using an empirical pseudopotential method(EPM) within the improved virtual crystal approximation(VCA), which includes the disorder effect. The direct-band-gap bowing parameter calculated by using the EPM is 4.1eV for InAs1-xNx ($0{\leq}x{\leq}0.05$). The dependences of the band gaps of N-dilute InAs1-xNx on the temperature and composition are calculated by modifying the band anti-crossing(BAC) model. The calculation results are consistent with experimental values, and the coupling parameter CMN of InAs1-xNx is found to be equal to 1.8 by fitting the EPM data.

Optical properties and thermodynamic function properties of undoped and Co-doped $Zn_{0.5}Cd_{0.5}Al_{2}Se_{4}$ Single Crystals ($Zn_{0.5}Cd_{0.5}Al_{2}Se_{4}$$Zn_{0.5}Cd_{0.5}Al_{2}Se_{4}:Co^{2+}$ 단결정의 광학적 특성과 열역학 함수 추정)

  • Hyun, Seung-Cheol;Kim, Hyung-Gon;Kim, Duck-Tae;Park, Kwang-Ho;Park, Hyun;Oh, Seok-Kyun
    • Proceedings of the KIEE Conference
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    • 2002.06a
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    • pp.88-93
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    • 2002
  • $Zn_{0.5}Cd_{0.5}Al_{2}Se_{4}$ and $Zn_{0.5}Cd_{0.5}Al_{2}Se_{4}:Co^{2+}$ + single crystals were grown by CTR method. The grown single crystals have defect chalcopyrite structure with lattice constant a= 5.5966A. c= 10.8042${{\AA}}$ for the pure. a= 5.6543${{\AA}}$. c= 10.8205${{\AA}}$ for the Co-doped single crystal. respectively. The optical energy band gap was given as indirect band gap. The optical energy band gap was decreased according to add of Co-impurity. Temperature dependence of optical energy band gap was fitted well to the Varshni equation. From this relation. we can deduced the entropy. enthalpy and heat capacity. Also. we can observed the Co-impurity optical absorption peaks assigned to the $Co^{2+}$ ion sited at the $T_d$ symmetry lattice and we consider that they were attributed to the electron transitions between energy levels of ions.

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