• 한국안전학회지
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• 제24권2호
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• pp.42-47
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• 2009

The flash point and the AIT(auto-ignition temperature) are the most important combustible properties used to determine the potential for the fire and explosion hazards of flammable material. In order to know the accuracy of data in MSDS(Material Safety Data Sheet), the flash point of n-acids were measured by using Pensky-Martens closed cup tester(ASTM D93), Setaflash closed cup tester(ASTM D3278), Tag open cup tester(ASTM D1310) and Cleveland open cup tester(ASTM D92). Also, the AIT of n-acids were measured by using ASTM E659-78 tester. The measured the flash points and the AIT were compared with literatures and MSDS in KOSHA. The measured the flash points and the AIT were different from those in literatures and MSDS. Therefore, This paper shows that it is needed to investigate the MSDS compatibility of n-acids for the fire safety objectives.

• 한국화재소방학회논문지
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• 제31권5호
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• pp.1-6
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• 2017

가연성물질의 화재 및 폭발 특성치는 안전한 취급, 저장, 수송, 처리 및 폐기하는데 반드시 필요하다. 공정 안전을 위한 대표적인 연소특성치로 최소자연발화온도(AIT)를 들 수 있다. 최소자연발화온도는 가연성 액체의 안전한 취급을 위해서 중요한 지표가 된다. 최소자연발화온도는 가연성물질이 주위의 열에 의해 스스로 발화하는 최저온도이다. 본 연구에서는 ASTM E659 장치를 이용하여 가연성 혼합물인 n-Pentanol과 p-Xylene 혼합물의 최소자연발화온도와 발화지연시간을 측정하였다. 2성분계를 구성하는 순수물질인 n-Pentanol과 p-Xylene의 최소자연발화온도는 각각 $285^{\circ}C$, $557^{\circ}C$로 측정되었다. 그리고 측정된 n-Pentanol과 p-Xylene 혼합물의 최소자연발화온도와 AIT에서의 발화지연시간의 실험값은 제시된 식에 의한 계산값과 적은 평균절대오차에서 일치하였다. 따라서 본 연구에서 제시한 예측식들을 이용하여 n-Pentanol과 p-Xylene 혼합물의 다른 조성에서도 최소자연발화온도와 발화지연시간을 예측이 가능하다.

• 한국안전학회지
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• 제34권4호
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• pp.32-40
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• 2019

During the manufacturing process of a printed circuit board(PCB), fumes and mists are generated as the ink dries on the PCB surface. The generated fumes and mists are deposited in the dryer wall and the exhaust duct. Deposited fumes and mists may present a fire hazard if the dryer temperature control system fails. In this study, the thermal stability of the fumes and mists deposited in the dryer and ducts has been analyzed by experimental methods such as thermo gravimetric analysis (TGA), differential scanning calorimetry (DSC), auto ignition temperature (AIT), and multiple mode calorimetry(MMC). According to the experimental analyses, experimental samples are likely to generate gas at the temperature ($180{\sim}240^{\circ}C$) that deviates from the normal operating temperature ($150{\sim}156^{\circ}C$). It has been shown that the thermal stability is degraded when the temperature is deviated from the normal operating temperature. In the end, engineering and management safety measures of accidental prevention have been suggested.

• 한국가스학회지
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• 제14권4호
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• pp.24-30
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• 2010

최소자연발화온도(AIT, autoignition temperature)의 정확한 정보는 산업화재를 예방하고 제어하는데 중요하다. 본 연구에서는 ASTM E659-78 장치를 이용하여 트리클로로실란 순수물질 그리고 디클로로실란(DCS)과 트리클로로실란(TCS) 혼합물의 AIT를 측정하였다. 트리클로로실란의 AIT는 $225^{\circ}C$로 측정되었으며, TCS(90wt%)-DCS(10wt%) 혼합물은 $250^{\circ}C$, TCS(70wt%)-DCS(30wt%) 혼합물은 각각 $236^{\circ}C$에서 발화가 발생하였다.

• 한국안전학회지
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• 제30권2호
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• pp.21-26
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• 2015

For the safe handling of o-cresol, this study was investigated the explosion limits of o-cresol in the reference data. The flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. The lower flash points of o-cresol by using closed-cup tester were experimented in $77^{\circ}C$ and $80^{\circ}C$. The lower flash points of o-cresol by using open cup tester were experimented in $86^{\circ}C$ and $87^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for o-cresol. The AIT of o-cresol was experimented as $495^{\circ}C$. The lower explosion limit(LEL) by the measured the lower flash point for o-cresol was calculated as 1.27 Vol%.

• 한국안전학회지
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• 제27권3호
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• pp.83-88
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• 2012

For the safe handling of n-tridecane, the lower flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. Also lower explosion limits by the lower flash points were calculated. The lower flash points of n-tridecane by using closed-cup tester were experimented $92^{\circ}C$ and $96^{\circ}C$. The lower flash points and fire point of n-tridecane by using open cup tester were experimented 100 oC and 103 oC, respectively. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-tridecane. The experimental AIT of n-tridecane was 223 oC. The calculated lower explosion limit by using measured lower flash point 92 oC for n-tridecane was 0.6 Vol.%.

• 한국안전학회지
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• 제29권4호
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• pp.85-90
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• 2014

For the safe handling of acetic anhydride, this study was investigated the explosion limits of acetic anhydride in the reference data. And the lower flash points, upper flash points, and AITs(auto-ignition temperatures) by ignition delay time were experimented. The lower and upper explosion limits of acetic anhydride by the investigation of the literatures recommended 2.9 Vol% and 10.3 Vol.%, respectively. The lower flash point of acetic anhydride by using Setaflash closed-cup tester was experimented $49^{\circ}C$. The lower flash point acetic anhydride by using Tag and Cleveland open cup tester were experimented $55^{\circ}C$and $62^{\circ}C$, respectively. Also, this study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for acetic anhydride. The experimental AIT of acetic anhydride was $350^{\circ}C$.

• 한국안전학회지
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• 제26권2호
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• pp.36-41
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• 2011

For the safe handling of n-hexane, the explosion limit at $25^{\circ}C$, the temperature dependence of the explosion limits and the lower flash point were investigated. And AITs(auto-ignition temperatures) by ignition delay time for n-hexane were experimented. By using the literatures data, the lower and upper explosion limits of n-hexane recommended 1.0 Vol% and 8.0 Vol%, respectively. In this study, the lower flash points of n-hexane recommended $-23^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659-78 apparatus for n-hexane, and the experimental AIT of n-hexane was $240^{\circ}C$. The new equations for predicting the temperature dependence of the explosion limits of n-hexane is proposed. The values calculated by the proposed equations were a good agreement with the literature data.

• 한국가스학회지
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• 제17권6호
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• pp.33-38
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• 2013

3-헥사논의 안전한 취급을 위해, 폭발한계는 문헌을 통해 고찰하였고, 인화점과 발화지연시간에 의한 발화온도를 측정하였다. 그 결과, 밀페식 장치에 의한 3-헥사논(에틸프로필케톤)의 하부인화점은 $18^{\circ}C$로 측정되었으며, 개방식에서는 $27^{\circ}C{\sim}32^{\circ}C$로 측정되었다. ASTM E659 장치를 사용하여 자연발화온도와 발화지연시간을 측정하였고, 3-헥사논의 최소자연발화온도는 $425^{\circ}C$로 측정되었다. 측정된 인화점에 의한 폭발하한계는 1.21 Vol%로 계산되었다.

• 한국안전학회지
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• 제27권5호
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• pp.70-76
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• 2012

For the safe handling of n-tetradecane, the lower flash points and the upper flash point, fire point, AITs (auto-ignition temperatures) by ignition delay time were experimented. Also lower and upper explosion limits by using measured the lower and upper flash points for n-tetradecane were calculated. The lower flash points of n-tetradecane by using closed-cup tester were measured $104^{\circ}C$ and $112^{\circ}C$. The lower flash points and fire point of n-tetradecane by using open cup tester were measured $113^{\circ}C$ and $115^{\circ}C$, respectively. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-tetradecane. The experimental AIT of n-tridecane was $207^{\circ}C$. The calculated lower and upper explosion limit by using measured lower $104^{\circ}C$ and upper flash point $140^{\circ}C$ for n-tetradecane were 0.63 Vol.% and 3.18 Vol%.