DOI QR코드

DOI QR Code

The Measurement of Combustible Properties of Acetic Anhydride for the Compatibility of MSDS

MSDS 적정성을 위한 아세틱안하이드리드의 연소특성치 측정

  • Ha, Dong-Myeong (Department of Occupational Health and Safety Engineering, Semyung University)
  • 하동명 (세명대학교 보건안전공학과)
  • Received : 2014.04.16
  • Accepted : 2014.08.04
  • Published : 2014.08.31

Abstract

For the safe handling of acetic anhydride, this study was investigated the explosion limits of acetic anhydride in the reference data. And the lower flash points, upper flash points, and AITs(auto-ignition temperatures) by ignition delay time were experimented. The lower and upper explosion limits of acetic anhydride by the investigation of the literatures recommended 2.9 Vol% and 10.3 Vol.%, respectively. The lower flash point of acetic anhydride by using Setaflash closed-cup tester was experimented $49^{\circ}C$. The lower flash point acetic anhydride by using Tag and Cleveland open cup tester were experimented $55^{\circ}C$and $62^{\circ}C$, respectively. Also, this study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for acetic anhydride. The experimental AIT of acetic anhydride was $350^{\circ}C$.

Keywords

References

  1. D.A. Crowl and J.F. Louvar, "Chemical Process Safety Fundamentals with Application", 2nd ed., Pearson Education Inc., 2002.
  2. F.P. Lees, "Loss Prevention in the Process Industries", Vol. 2, 2nd ed., Butterworth-Heinemann, 1996.
  3. D.R. Lide, "Handbook Chemistry and Physics", 76th ed., CRC Press, 1996.
  4. NFPA, "Fire Hazard Properties of Flammable Liquid, Gases, and Volatile Solids", NFPA 325M, NFPA, 1991.
  5. R.E Lenga. and K.L. Votoupal, "The Sigma Aldrich Library of Regulatory and Safety Data, Volume I-III", Sigma Chemical Company and Aldrich Chemical Company Inc., 1993.
  6. V. Babrauskas, "Ignition Handbook", Fire Science Publishers, SFPE, 2003.
  7. J.A. Dean, "Lange's handbook of Chemistry", 14th ed. McGraw-Hill, 1992.
  8. R.J. Lewis, "SAX's Dangerous Properties of Industrial Materials", 11th ed., John Wiley & Son, Inc., N.J., 2004
  9. Fluka Chemie AG., Catalog 1986-87, CH-9470, Bucks/Switzerland.
  10. C.J. Hilado and S.W. Clark, "Autoignition Temperature of Organic Chemicals", Chemica Engineering, Vol. 4, pp.75-80, 1972.
  11. G.S. Scott, G.W. Jones and F.E. Scott, "Determination of Ignition Temperature of Combustible Liquids and Gases", Analytical Chemistry, Vol. 20, No.3, pp. 238-241, 1948. https://doi.org/10.1021/ac60015a015
  12. D.M. Ha, "The Measurement of Fire and Explosion Properties of n-Pentadecane", J. of the Korean Society of Safety, Vol. 28, No. 4, pp. 53-57, 2013. https://doi.org/10.14346/JKOSOS.2013.28.4.053
  13. J. Gmehing, U. Onken and W. Arlt, "Vapor-Liquid Equilibrium Data Collection", DECHEMA, 1980.
  14. N.N. Semenov, "Some Problems in Chemical Kinetics and Reactivity, Vol. 2", Princeton University Press, Princeton, N.J., 1959.