• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2004년도 추계학술발표회 발표논문집
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• pp.1119-1120
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• 2004

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2005년도 춘계학술발표회
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• pp.783-784
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• 2005

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2019년도 춘계학술논문요약집
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• pp.420-421
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• 2019

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2017년도 춘계학술논문요약집
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• pp.311-312
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• 2017

• Korean Chemical Engineering Research
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• 제43권1호
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• pp.9-15
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• 2005

본 연구에서는 전기화학적 방법에 의한 암모니아의 질소화 분해 특성을 파악하기 위하여 여러 암모니아 전해 실험 변수에 대하여 조사하였다. $IrO_2$, $RuO_2$, Pt 양극에서 암모니아의 분해에 대한 pH 및 염소 이온의 영향이 상호 비교되었으며, 전해 반응기에서의 분리막의 존재 유무, 전류밀도, 암모니아 초기 농도 등의 변화에 따른 암모니아의 전기화학적 분해 특성이 조사되었다. 산성이나 알칼리 조건에서 암모니아의 분해에 대한 전극의 성능은 전체적으로 $RuO_2{\approx}IrO_2>Pt$ 순으로 나타났다. 암모니아의 분해는 전극에 공급되는 전류 밀도가 $80mA/cm^2$에서 가장 높았으며 그 이상의 전류 밀도에서는 산소발생에 의해 암모니아의 전극 흡착이 영향을 받아 오히려 감소되었다. 암모니아 용액에 존재하는 염소 이온의 농도가 증가할수록 암모니아의 분해는 증가하나 10 g/l 이상에서는 분해율 증가가 크게 둔화되었다. pH 7의 전해 반응의 경우 전극 표면에서 OH 라디칼이 생성되어 암모늄 이온의 분해가 이루어지는데, 이 OH 라디칼은 $RuO_2$ 전극에서 가장 많이 생성이 되었다.

• Korean Chemical Engineering Research
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• 제43권3호
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• pp.352-359
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• 2005

본 논문에서는 암모니아의 전해 분해를 위한 분리막 반응기의 음극방 및 양극방에서 물의 전해에 따른 암모니아 용액의 pH 변화가 고찰되었으며, 단위 전해 셀이 적층된 다단 전해 반응기에서의 암모니아의 연속식 분해 특성이 평가되었다. 분리막을 가지는 반응기에서 암모니아 용액의 전해 반응 시, 양극에서는 pH가 8 이하에서부터 수소 이온이 생성되는 물 분해 반응이 일어나며, 음극에서는 pH가 11 이상에서부터 수산기 이온이 생성되는 물 분해 반응이 일어나 암모니아 용액의 pH를 변화시켜 암모니아 전해 분해에 영향을 크게 미쳤으며, 음이온 교환막을 사용하는 경우가 양이온 교환막을 사용하는 경우보다 양극방에서 암모니아 분해에 유리한 알카리 분위기를 보다 효과적으로 유지할 수 있었다. 분리막 전해 반응기의 특성을 이용하여 자체 pH 조정 기능을 가지는 연속식 암모니아 전해 반응기가 새롭게 고안하였고, 여기서는 pH-조정조 탱크 용액을 두고 이의 용액 일부를 음극방으로 순환시킴으로써, 양극방으로 주입되는 pH-조정조의 용액의 pH를 높여 암모니아 분해율을 높일 수 있었다. 또한, 그러한 반응기를 이용한 salt-free 연속식 암모니아 전해 분해 공정이 제시되었으며, 이러한 공정에서는 염소 이온을 가지는 암모니아 용액의 80％까지 연속적으로 암모니아를 환경에 무해한 질소로 분해 시킬 수 있었다.

• Nuclear Engineering and Technology
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• 제41권6호
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• pp.831-840
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• 2009

In order to evaluate the start-up behavior and to identify, through abnormal operation occurrences, the transient behaviors of the Sulfur Iodine(SI) process, which is a nuclear hydrogen process that is coupled to a Very High Temperature Gas Cooled Reactor (VHTR) through an Intermediate Heat Exchanger (IHX), a dynamic simulation of the process is necessary. Perturbation of the flow rate or temperature in the inlet streams may result in various transient states. An understanding of the dynamic behavior due to these factors is able to support the conceptual design of the secondary helium loop system associated with a hydrogen production plant. Based on the mass and energy balance sheets of an electrodialysis-embedded SI process equivalent to a 200 $MW_{th}$ VHTR and a considerable thermal pathway between the SI process and the VHTR system, a dynamic simulation of the SI process was carried out for a sulfuric acid decomposition process (Second Section) that is composed of a sulfuric acid vaporizer, a sulfuric acid decomposer, and a sulfur trioxide decomposer. The dynamic behaviors of these integrated reactors according to several anticipated scenarios are evaluated and the dominant and mild factors are observed. As for the results of the simulation, all the reactors in the sulfuric acid decomposition process approach a steady state at the same time. Temperature control of the inlet helium is strictly required rather than the flow rate control of the inlet helium to keep the steady state condition in the Second Section. On the other hand, it was revealed that the changes of the inlet helium operation conditions make a great impact on the performances of $SO_3$ and $H_2SO_4$ decomposers, but no effect on the performance of the $H_2SO_4$ vaporizer.

• 방사선산업학회지
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• 제5권4호
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• pp.359-364
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• 2011

This study was aimed to investigate the effect of oxidants on biodegradability and decomposition of acetaminophen (ACT) by gamma ray. Three kinds of chemical, potassium persulfate, hydrogen peroxide and ferrous sulfate were selected as an oxidant. The absorbed dose was ranged from 0.2 to 10 kGy and the concentration of oxidants was from 0.1 to 10 mM and the initial concentration of acetaminophen was $30mg\;l^{-1}$ in this study. The concentration of ACT was gradually decreased corresponding to the increase of the absorbed dose. However, mineralization of ACT was not occurred by the increased of the absorbed dose. When the 10 mM of oxidants applied to the ACT aqueous solution, the concentration of ACT was rapidly decreased according to absorbed dose and the mineralization was observed in potassium persulfate. Biodegradability of ACT with potassium persulfate was higher than that of ACT without potassium persulfate in lower absorbed dose and decreased according to higher absorbed dose.

• Macromolecular Research
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• 제11권5호
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• pp.387-392
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• 2003

The ablation effects of Ar-plasma treatment and alkali-decomposition behavior in NaOH solution of polyethylene terephthalate (PET) film were investigated. The modifications were evaluated by analysis of atomic force microscopy topographical changes, and by the measurement of decomposition yield in conjunction with heats of formation and electron densities of acyl carbon calculated by Parameterization Method 3 method. It has shown that the alkali-decomposition is hampered by plasma treatment and its decomposition yield is closely related with plasma treatment conditions such as exposure time to plasma. Plasma-treated PET films exhibited lower decomposition yield, compared to that of virgin PET. Increasing plasma exposure time contributes positively to decrease the decomposition yield. It has also shown that the topography of PET surface was affected by the base-promoted hydrolysis as well as Ar-plasma treatments. These behaviors are attributed to the decreased nucleophilicity of acyl carbon damaged by the ablation of Ar-plasma.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1998년도 춘계학술발표회논문집(2)
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• pp.273-278
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• 1998

The phase stability of atomized U-10wt. ％Mo powder and the thermal compatibility of dispersed fuel meats at 40$0^{\circ}C$ and 50$0^{\circ}C$ have been characterized. Atomized U-10Mo powder has a good \ulcorner-U phase stability, and excellent thermal compatibility with aluminum matrix in a dispersion fuel. It is thought that the good phase stability is related to th large supersaturation of Mo atoms in the atomized particles. The reasons for the excellent thermal compatibility have been considered to be as follows. Before thermal decomposition of ${\gamma}$-U in particle, supersaturated Mo atoms at ${\gamma}$-U grain boundaries inhibit the diffusion of Al atoms. After thermal decomposition of ${\gamma}$-U into ${\gamma}$-U and U$_2$Mo, the intermetallic compound of U$_2$Mo seems to retard the penetration of Al atoms. The penetration mechanisms of aluminum atoms in the atomized particles are assumed be classified as (a) diffusion through the reacted layer between fuel particles and Al matrix leaving a kernel-like unreacted island and (b) diffusion along grain boundaries showing several unreacted islands and more reacted regions.