• Applied Chemistry for Engineering
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• v.18 no.1
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• pp.94-97
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• 2007

Carbon nanotubes and nanowires were prepared by methane pyrolysis over Pd(5)/SPK catalyst by changing oxygen molar ratio in a fixed bed flow reactor under atmospheric condition and also analyzed by SEM and TEM. When the $CH_4/O_2$ molar ratio was 1, carbons were not almost deposited on the catalyst bed support, but when it was 2, carbons were deposited as much as plugging reactor. TEM and SEM images for the deposited carbons showed a number of single-walled carbon nanotubes and carbon nanowires. The growth mechanism of carbon nanotubes produced on the catalyst surface was the tip growth mode. It should be played an important role in carbon nanotubes and nanowires produced on the catalyst bed support to formate the carbon growth velocity vectors and nuclei of ring structure of carbon nanowires. SPK carrier was $N_2$ isotherm of IV type with mesopores, and excellent in the thermal stability.

• Economic and Environmental Geology
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• v.35 no.2
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• pp.149-154
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• 2002

Column tests were carried out to examine the effect of surfactant solution conditions on surfactant-enhanced remediation of contaminated soil. The selected conditions of the surfactant solution were concentration and pH. 1,2,4-trichlo-robenzene (TCB) was chosen as the model hydrophobic organic substances. Sodium diphenyl oxide disulfonate (DOSL) and octylphenoxypoly ethoxyethanol (OPEE) surfactants were selected for this study. Two Iowa soils, Fruitfield sand and Webster clay loam, were leached with surfactant solution. The test results revealed that an optimum condition was achieved for 4 %(v/v) of concentration and 10 of pH, respectively. The maximum recoveries of added TCB (93-98%) were obtained when optimal conditions of each surfactant solution parameter were simultaneously met. The optimum conditions of these parameters may be useful for surfactant-assisted remediation in soil contaminated by TCB.

• Journal of Energy Engineering
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• v.18 no.4
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• pp.239-246
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• 2009

A fundamental investigation has been conducted on the combustion of single particle of a sub-bituminous coal char burning at different temperatures and residence times. The lab-scale test setup consisted of a drop tube furnace where gas temperatures varied from $900^{\circ}C$ to $1400^{\circ}C$. A calibrated two color pyrometer, mounted on the top of the furnace, provided temperature profiles of luminous particle during a char oxidation. An amount of char mass reacted during the reaction is measured with thermogravimetry analyzer by using an ash tracer method. As a result, mass and area reactivity as well as reaction rate coefficients are determined for the char burning at atmospheric pressure condition.

• Journal of The Korean Society of Grassland and Forage Science
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• v.21 no.4
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• pp.217-224
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• 2001

In order to identify the growth characterization, the yield and chemical composition of Jeju barnyard grass (Echinochloa crusgalli var. fiurnentacea(Roxb) Wight) based on seeding date in Jeju region, seeding carried out the 10-day intervals from March 27 to September 30 in 2000, respectively. Plant height was 143.2 cm, showing the highest on seeding date, April 6 among that of any other seeding date. On the other hand, those of early and late seeding gradually decrease. Plant height was 119.2 an in May 16 seeding. The results of stem diameter, number of withering leaves, number of leaves and fresh weight per plant were similar to those of the plant heights. The yield of fresh, dry matter forage, crude protein and TDN found the highest on April 6 seeding, 63.5 MT/ha, 13.9 MTha, 1.1 MT/ha, and 7.6 MT/ha, respectively. In early and late seeding, the yield was gradually decreased. In seeding May 16, the yield found .38.2 MTIha in fresh forage, 6.2 MTha in dry matter forage, 0.7 MT/ha in crude protein and 3.7 MTha in TDN, respectively. According to delaying the seeding date, March 27 to May 16, the contents of crude protein (from 7.9 to 10.8%), ether extract (from 4.6 to 6.0%), nitrogen free extract (from 45.1 to 46.5%), and TDN (from 54.2 to 60.8%) were gradually increased, respectively. On the other hand, those of crude fiber (from 28.9 to 25.6%) and crud ash (from 13.5 to 11.2%) were decreased. These results showed that April 6 was the optimum seeding date with the sole object of feed production of Jeju barnyard grass under the environmental condition like as atmospheric phenomena and soil in Jeju region. (Key words : Jeju barnyard grass, Seeding date, Forage yield, Chemical composition)

• Journal of Hydrogen and New Energy
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• v.13 no.2
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• pp.101-109
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• 2002

This work was focused on the thermal decomposition of methane into hydrogen and carbon black without emitting carbon dioxide. Extensive experimental investigation on the thermal decomposition of methane has been carried out using a continuous flow reaction system with tubular reactor. The experiments were conducted at the atmospheric pressure condition in the wide range of temperature ($950-1150^{\circ}C$) and flow rate (250 - 1500 ml/min) in order to study their dependency on hydrogen yield. During the experiments the carbon black was successfully recovered as an useful product. Undesirable pyrocarbon was also formed as solid film, which was deposited on the inside surface of tubular reactor. The film of pyrocarbon in the reactor wall became thicker and thicker, finally blocking the reactor. The design of an efficient reactor which can effectively suppress the formation of pyrocarbon was thought to be one of the most important subjects in the thermal cracking of methane.

• Journal of Radiation Protection and Research
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• v.39 no.4
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• pp.176-181
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• 2014

The object of this paper is to evaluate the fission product inventories and radiological doses in a non-LOCA event, based on the U.S. NRC's regulatory methodologies recommended by the TID-14844 and the RG 1.195. For choosing a non-LOCA event, one fuel assembly was assumed to be melted by a channel blockage accident. The Hanul nuclear power reactor unit 6 and the CE $16{\times}16$ fuel assembly were selected as the computational models. The burnup cross section library for depletion calculations was produced using the TRITON module in the SCALE6.1 computer code system. Based on the recently licensed values for fuel enrichment and burnup, the source term calculation was performed using the ORIGEN-ARP module. The fission product inventories released into the environment were obtained with the assumptions of the TID-14844 and the RG 1.195. With two kinds of source terms, the radiological doses of public in normal environment reflecting realistic circumstances were evaluated by applying the average condition of meteorology, inhalation rate, and shielding factor. The statistical analysis was first carried out using consecutive three year-meteorological data measured at the Hanul site. The annual-averaged atmospheric dispersion factors were evaluated at the shortest representative distance of 1,000 m, where the residents are actually able to live from the reactor core, according to the methodology recommended by the RG 1.111. The Korean characteristic-inhalation rate and shielding factor of a building were considered for a series of dose calculations.

• Transactions on Electrical and Electronic Materials
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• v.5 no.5
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• pp.204-207
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• 2004

In this work, we present the electrochemical properties of Al bipolar plate, which can be re-searched for the application of PEMFC system. Bulk resistance of the plate was measured with a four-point probe method. The electrical conductivity of noble metal coated Al plate was 4.40 x 10$^4$ S/cm. On the other hand, the electrical interfacial resistance of the noble metal coated Al plate valued at 0.15 mΩ-$\textrm{cm}^2$ and that of graphite was 0.26 mΩ-$\textrm{cm}^2$ under the holding pressure of 140 N/$\textrm{cm}^2$ at the applied current of 5 A. And the performance of Al bipolar plate for PEMFC was evaluated at various conditions. The single cell performance was more than 0.43 W/$\textrm{cm}^2$ (0.47 Wig) for noble metal coated Al bipolar plate at 5$0^{\circ}C$ under atmospheric pressure in external humidified hydrogen and oxygen condition. As the present results, we could show the results that the noble metal coated Al bipolar plates were favorable in the aspect of electrical properties compared with those of the commercialized resin-impregnated graphite plates.

• Journal of the Korean Chemical Society
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• v.33 no.5
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• pp.522-529
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• 1989

Symmetrical divinyl ketones and divinyl ${\alpha}$-diketones were synthesized in moderately good yields through palladium catalyzed carbonylative homocoupling reaction of vinylic halides. Divinyl ${\alpha}$-diketones were obtained in the highest yield in the presence of 10 atm of carbon monoxide, using 2 mol% ligand added to palladium(II) acetate as catalyst and three equivalents of tributylamine as base in polar solvent at $100^{\circ}C$. Divinyl ketones were synthesized mainly under atmospheric pressure of carbon monoxide. The reaction was also proceeded to several other vinylic halides under the above reaction condition. Thus, divinyl ketones and divinyl ${\alpha}$-diketones were synthesized selectively as expected.

• Journal of the Korean Society of Propulsion Engineers
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• v.18 no.4
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• pp.81-89
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• 2014

Tandem-ejector has been devised for engine-bay cooling. In this study, 1-D model has been developed to analyze Tandem-ejector. In the model, the primary, the secondary and the tertiary flow conditions have been analyzed with isentropic process. The mixing process has been analyzed with conservation laws based on the control volume analysis. The total pressure loss of the primary flow has been analyzed under the matching condition between the static pressure of Tandem-ejector discharge flow and atmospheric pressure. Consequently, 1-D model can predict Tandem-ejector performance accurately and provide the performance map.

• Proceedings of the SAREK Conference
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• 2008.06a
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• pp.1195-1200
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• 2008

This study have goal with conceptual design for Offshore Structures of high pressure control valve for localization. Ball valve for development accomplished with flow analysis based on provision of ANSI B16.34, ANSI B16.10, ANSI B16.25 In order to localize the Offshore Structures high pressure control valve. Numerical simulation using CFD(Computational Fluid Dynamic) in order to predict a mass flow rate and a flow coefficient form flow dynamic point of view. The working fluid assumed the glycerin($C_3H_8O_3$). The valve inlet and outlet setup a pressure boundary condition. The outlet pressure was fixed by atmospheric pressure and calculated until increasing 1bar to 10bar. CFD analysis used STAR-CCM+ which is commercial code and Governing equations were calculated by moving mesh which is rotated 90 degrees when ball valve operated opening and closing in 1 degree interval. The result shows change of mass flow rate according to opening and closing angle of valve. Flow decrease observed open valve that equal percentage flow paten which is general inclination of ball valve. Relation with flow and flow coefficient can not be proportional according to inlet pressure when compare with mass flow rate. Because flow coefficient have influence in flow and pressure difference. Namely, flow can be change even if it has same Cv value. The structural analysis used ANSYS which is a commercial code. Stress analysis result of internal pressure in valve showed lower than yield strength. This is expect to need more detail design and verification for stem and seat structure.