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An Experimental Study on the Workability and Engineering Properties of Recycled Aggregate Concrete Mixed Fly ash. - Part 1. In the case of fresh concrete - (플라이애쉬를 혼입한 재생골재의 시공성 및 공학적 특성에 관한 실험적 연구 -제 1보 아직 굳지않은 콘크리트의 성상을 중심으로-)

  • 남상일;김진만;김무한
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.04a
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    • pp.254-259
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    • 1994
  • Recycling of waste concrete will contribute not only to the solution of a growing waste disposal problem, also help to conserve natural resources of aggregate and to secure future supply of reasonably priced aggregates for building construction purpose within large urban areas. But there recycled aggregates are more porous and less resistant to mechanical actions. In comparison with natural aggrete concrete, recycled aggregate concrete shows reductions in strength and other engineering properties. And it may also be less durable due to increase in porosity and permeability. Economical ways of improving the quality of recycled aggregate concrete are: (1)by reducing the water-cement ratio; (2)by reducing the water content using a superplasticizer without affecting the workability; (3)addition of pozzolan, such as fly ash; and (4)blending of recycled aggregate with the natural aggretes.

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Effects of Admixture to Sulfate Attack Resistance of Cement Mortar (시멘트 모르타르의 황산염 침식 저항성에 대한 혼화재의 영향)

  • 형원길;소승영;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.04a
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    • pp.704-709
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    • 2000
  • This study is to test effects of sulfate attack on deterioration of cement mortar. Four tests have been carried out with four types of mortars mixed by ordinary portland cement and sulfate-resistant portland cement containing blast-furnace slag and fly-ash. It was immersed in sulfate solution for 7, 28, 91, and 180 days. from the test results, sulfate attack resistance of cement mortar was improved by admixtures (blast-furnace slag and fly-ash), sulfate-resistance portland cement mortar showed high resistance than ordinarily portland cement at compressive strength, and similar the resistance of sulfate attack with ordinarily portland cement mortar with admixtures.

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Experimental Study on the Stress-Strain and Acid-Resistance of Pine Needle Ash Concrete (솔잎재 콘크리트의 응력-변형과 내산성에 관한 실험적 연구)

  • 성찬용
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.41 no.5
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    • pp.99-103
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    • 1999
  • This study examines the stress-strain and acid-resistance of pine needle ash (PNA) concrete. Materials used for this experiment are PNA , normal portland cement, natural fine and coarse aggregate. Test results show that the highest static modulus of elasticity are achieved by 5 % PNA filled PNA concrete. Acid-resistance of PNA concrete is increased with increase of the content of PNA. It is 1.29 times of the normal cement concrete for 5 % PNA filled PNA concrete and 2.57 times fo r15% PNA filled PNA concrete, based on the elased days for 25% mass loss of original mass immersed in the 5% H2SO4 solution. Accordingly, PNA concrete will greatly improve the properties of concrete.

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A Study on the Sulfate Attack of Concrete Using in Crushed Aggregates (부순모래 콘크리트의 황산염해에 관한 연구)

  • Kim, Kwang-Yuil;Kim, Kang-Min;Beak, Dong-Il;Kim, Myung-Sik;Kim, Jong-Soo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.217-220
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    • 2005
  • As this study is to test effects of sulfate attack on deterioration of concrete using in crushed aggregates. Besides tests have been carried out with concrete by river sand and crushed sand by fine sand, concrete mixes various proportions of slica fume and fly ash(up to 15$\%$ by weight fo cement) were prepared and immersed in pure water, sodium sulfate solution for 28 and 60days. Test on the change in the weight and compressive strength of concrete according to the duration of immersion time and the content of slica fume and fly ash was performed.

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An Experimental Study on the Salt Damage Resistance of High Durable Concrete (고내구성콘크리트의 염해저항성에 관한 실험적 연구)

  • Yoon, Jai-Hwan;Jaung, Jae-Dong
    • Journal of the Korea Institute of Building Construction
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    • v.3 no.3
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    • pp.73-81
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    • 2003
  • In this paper, salt damage resistance of high durable concrete was tested. High durable concrete was made by using low water cement ratio, chemical admixture called super-durable admixture and mineral admixtures such as fly-ash, ground granulated blast-furnace slag, silica fume. Two kinds of salt damage resistance test were carried out. One method is chloride ion penetration test(ASTM C1202), and the other one is depth of chloride penetration test in saline solution. Test results were as followers: 1) The depth of chloride ion penetration increased exponentially as water cement ratio was increased and time passed. 2) Super-durable admixture had little effect on the improvement of salt damage resistance of concrete. 3) Silica fume and ground granulated blast-furnace slag were effective on salt damage resistance because of pozzolanic reaction, but fly-ash had a little effect.

Characteristics of Sulfuric acid corrosion of Recycled PET Polymer Concrete with Different Filler (충전재 변화에 따른 PET 재활용 폴리머 콘크리트의 황산 부식에 관한 특성)

  • Jo Byung Wan;Gu Ja Kap;Park Jong Hwa;Park Seung Kook
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.719-722
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    • 2004
  • Resins using recycled PET offer the possibility of a lower source cost of materials for making useful polymer concrete products. The purposed of this paper is to form a part of reducing the damage of sulfuric acid, through investigating recycled PET polymer concrete, . immersed at sulfuric acid solution for 84 days. Recycled PET PC is excellent chemical resistance, resulting in the role of unsaturated polyester resin which consists of polymer chain structure accomplishes bond of aggregates and filler strongly. Also, Recycled PET PC, used fly-ash as filler, is stronger resistance of sulfuric acid corrosion than $CaCO_3$, because it is composed of $SiO_2$ and very strong glassy crystal structure. Therefore, Recycled PET PC, used fly-ash as filler, is available under corrosion circumstances like sewer pipe or waste disposal plant.

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Phenol removal by tailor-made polyamide-fly ash composite membrane: Modeling and optimization

  • Vandana, Gupta;Anandkumar, J.
    • Membrane and Water Treatment
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    • v.10 no.6
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    • pp.431-440
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    • 2019
  • A novel composite membrane was synthesized using crosslinked polyamide and fly ash ceramic substrate for phenol removal. Glutaraldehyde was used as crosslinker. Characterization shows that synthesized membrane possesses good permeability ($0.184l.m^{-2}.h^{-1}.kPa^{-1}$), MWCO (1.7 kDa), average pore size (1.08 nm) and good chemical stability. RSM was adopted for phenol removal studies. Box-Behnken-Design using quadratic model was chosen for three operating parameters (feed phenol concentration, pH and applied pressure) against two responses (phenol removal, flux). ANOVA shows that model is statistically valid with high coefficient of determination ($R^2$)value for flux (0.9897) and phenol removal (0.9302). The optimum conditions are obtained as pH 2, $46mg.l^{-1}$ (feed phenol concentration) and 483 kPa (applied pressure) with 92.3% phenol removal and $9.2l.m^{-2}.h^{-1}$ flux. Data validation with deviation of 4% confirms the suitability of model. Obtained results reveal that prepared composite membrane can efficiently separate phenol from aqueous solution.

Studies of Purifying Waste Cotton for Esterification & Molecular Weight Distribution Curve of Cellulose Acetate (落綿의 精製 및 이를 原料로 하는 醋酸纖維素의 分子量 分配曲線에 關한 硏究)

  • Kim, Dong-Il;Noh, Ick-Sam
    • Journal of the Korean Chemical Society
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    • v.4 no.1
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    • pp.38-43
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    • 1957
  • Purified cellulosic materials suitable for the production of cellulose esters can be prepared from waste cotton (carding waste from textile mill). The most desirable conditions in purifying waste cotton were obtained. Waxy materials were removed by boiling in 2-3% soda ash solution for more than 30 minutes in open vessel at atmospheric pressure. As for bleaching, it is desirable to use the bleaching powder solution containing 1%, available chlorine for 60 minutes at 35 deg. C. Purified cellulosic material was acetylated to fibrous cellulose triacetate, which was fractionated in the solution of 70% monochloroacetic acid using water as a precipitant, and the degree of polymerizaion and molecular weight of each fraction were measured viscometrically, thereon, molecular weight distribution curve was drawn. Analyzing the shape of this curve, most of the polymers were concentrated on the part of higher degree of polymerization. Purified waste cotton was also analysed, the result was that this cellulosic material can be used as a raw material for cellulose esters and ethers.

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Evaluation on Sulfate Attack Resistance of Cement Matrix (시멘트 경화체의 황산염침식 저항성 평가)

  • 문한영;김홍삼;이승태
    • Journal of the Korea Concrete Institute
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    • v.12 no.5
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    • pp.141-151
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    • 2000
  • Compressive strength, sulfate deterioration factor(SDF) and length change of 5 types of mortars immersed in sodium sulfate solution were observed. As the results of tests, it was found that the sulfate resistance of blended cement mortars were superior to that of portland cement mortars. Pore volume with diameter larger than 0.1 $\mu\textrm{m}$ of 5 types of pastes indicated that the micro-structures of blended cement pastes were denser, due to pozzolan reaction and latent hydraulic properties, than those of portland cement pastes. The XRD, ESEM, EDS and TG analyses demonstrated that the reactants such as ettringite and gypsum were significantly formed in portland cement pastes. Besides, compared with the $Ca(OH)_2$ content of ordinary portland cement pastes immersed in water and sodium sulfate solution, the $Ca(OH)_2$ contents of fly ash blended cement and ground granulated blast-furnace slag cement paste were about 58% and 28% in water, and 55% and 20% in sodium sulfate solution, respectively.

Dimensional Change of PEG-Freeze Dried Waterlogged Woods Exposed at Various Humidity Conditions (PEG처리 후 동결건조한 수침고목재의 습도조건에 따른 상태변화)

  • Kim, Soo-Chul;Park, Won-Kyu;Yi, Yong-Hee
    • Journal of Conservation Science
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    • v.16 s.16
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    • pp.110-118
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    • 2004
  • In order to evaluate two-step treatment of PEG-freeze drying for highly-degraded waterlogged ash woods (Fraxinus PP.; ca. 5,700 BP), which were excavated from peat lands in western Korea, dimension stability was examined during 45 months after complete treatment. The samples pre-treated with PEG in water solution showed better dimensional stabilities than the ones with PEG in t-butanol(TBA) solution. It suggests that TBA reduced the flexibility of wood cells and overflying by TBA induced micro-checks during freeze drying. Micro-checks results in fragile wood structures and consequently, large shrinkage by moisture absorbances of high PEG contents during exposure in humid condition. The results suggest that PEG in water-solution treatment is better than PEG in t-butanol as pretreament for freeze drying of highly-degraded waterlogged ash woods.

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