• Title/Summary/Keyword: ash analysis

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Stabilization of Heavy Metal (Ni, Cr) in Soil Amended with Biomass Ash (바이오매스 회분 혼합에 따른 토양 내 중금속 (Ni, Cr) 안정화)

  • Kang, Ku;Park, Seong-Jik;Hong, Seong-Gu
    • Journal of The Korean Society of Agricultural Engineers
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    • v.58 no.3
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    • pp.39-46
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    • 2016
  • This study investigated the potential use and the effectiveness of biomass ashes for the stabilization of heavy metals in soil through a series of experiments. The ashes used for the experiments were obtained from the gasification of biomass including miscanthus and woodchips. The amounts of nickel and chromium released from the soil and ash mixture were analyzed. Chemical analysis showed that the ash contained unburned carbon as well as silica and alkali metals. Miscanthus ashes have C (83.400 %) > Si (9.040 %) > K (3.180 %) > Ca (1.800 %), and woodchip ashes have C (93.800 %) > Ca (2.220 %) > Fe (1.370 %) > K (1.200 %). KSLT and TCLP test results implied that the heavy metal concentrations were below the environmental standards and would not impose the risks. The results also showed that Ni releases were more limited as more ashes were mixed with the soil due to the increases in exchangeable, carbonate, and oxide nikels. Both miscanthus and woodchip ahses were effective in stabilizing nickel and chromium through mixing with the soil. It could be seen that ashes produced from biomass gasification can be used to stabilize the heavy metals in soils.

Predicting the compressive strength of self-compacting concrete containing fly ash using a hybrid artificial intelligence method

  • Golafshani, Emadaldin M.;Pazouki, Gholamreza
    • Computers and Concrete
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    • v.22 no.4
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    • pp.419-437
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    • 2018
  • The compressive strength of self-compacting concrete (SCC) containing fly ash (FA) is highly related to its constituents. The principal purpose of this paper is to investigate the efficiency of hybrid fuzzy radial basis function neural network with biogeography-based optimization (FRBFNN-BBO) for predicting the compressive strength of SCC containing FA based on its mix design i.e., cement, fly ash, water, fine aggregate, coarse aggregate, superplasticizer, and age. In this regard, biogeography-based optimization (BBO) is applied for the optimal design of fuzzy radial basis function neural network (FRBFNN) and the proposed model, implemented in a MATLAB environment, is constructed, trained and tested using 338 available sets of data obtained from 24 different published literature sources. Moreover, the artificial neural network and three types of radial basis function neural network models are applied to compare the efficiency of the proposed model. The statistical analysis results strongly showed that the proposed FRBFNN-BBO model has good performance in desirable accuracy for predicting the compressive strength of SCC with fly ash.

Use of Stone Powder Sludge in Fly Ash-Based Geopolymer

  • Choi, Se-Jin
    • Architectural research
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    • v.12 no.1
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    • pp.49-55
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    • 2010
  • Stone powder sludge is a by-product of the manufacturing process of crushed sand. Most of it is dumped with soil in landfills, and the disposal of stone powder sludge causes a major environmental problem. This paper investigates the applicability of stone powder sludge in fly ashbased geopolymer. For this, stone powder sludge was used to replace fly ash at a replacement ratio of 50% and 100% by weight. The compressive strength of the samples was measured and scanning electron microscopy/ energy dispersive spectroscopy (SEM/EDS) analysis and X-ray diffraction (XRD) were performed. The test results indicated that the optimum level of the alkali activator ratio ($Na_2SiO_3$/NaOH) for fly ash-based geopolymer using stone powder sludge was 1.5. The strength development is closely related to the NaOH solution concentration. In addition, the compressive strength of the sample cured at $25^{\circ}C$ was significantly improved between 7 days and 28 days, even though the strength of the sample showed the lowest value at 7 days. Microscopy results indicated that a higher proportion of unreacted fly ash spheres remained in the sample with 5M NaOH, and some pores on the surface of the sample were observed.

Performance Evaluation of Wall Blower Nozzle using Erosion Analysis (침식 해석을 이용한 월 블로워 노즐의 성능 예측)

  • Paek, Jae Ho;Jang, llkwang;Jang, Yong Hoon
    • Tribology and Lubricants
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    • v.34 no.5
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    • pp.175-182
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    • 2018
  • Accumulation of coal ash at the boiler wall reduces combustion and fuel efficiency. The design of a wall blower is important to effectively remove coal ash. We present numerical results for the removal of coal ash from boiler walls of domestic coal-fired power plants, associated with the computational fluid dynamics for the flow from spray nozzle to boiler wall. The numerical model simulates an erosion process in which the multiphase fluid comprising saturated vapor and fluid water is sprayed from the nozzle, and the water particles impact the boiler wall. We adopt the Finnie erosion model for water particles. We obtain the erosion rate density as a function of nozzle angle and its injection angle. As excessive coal ash removal usually induces damage to the boiler wall, the removal operation typically focuses on a large area with uniform depth rather than the maximum removal of coal ash at a specific location. In order to estimate the removal performance of the wall blower nozzle considering several functionality and reliability factors, we evaluate the optimal injection and nozzle angles with respect to the biggest cumulative and highest erosion rates, as well as the widest range and lowest standard deviation of the erosion rate distribution.

Analysis of DNA Conformation in the Particles of Bacteriophage P4 Mutant, P4 ash8 (박테리오파아지 P4 ash8 sid71 입자 내 DNA 형태 분석)

  • Song, Jae-Ho;Kim, Kyoung-Jin
    • Korean Journal of Microbiology
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    • v.42 no.1
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    • pp.62-66
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    • 2006
  • To study the packaging mechanism of the bacteriophage P2-P4 system which is a useful experimental tool for the study of viral capsid assembly, we analyzed the DNA contents of P4 sid- mutant, P4 ash8 sid71's phage particles. Two kind of particles having different density were separated by the CsCl buoyant equilibrium density gradient experiment with fresh made stock of P4 ash8 sid71. The DNA from each particles was prepared and its conformations was analyzed by electrophoresis. Unexpectedly, both particles contain not only dimeric and trimeric but also monomeric P4 DNA.

THE QUALITY PROPERTIES FOR FLY ASH OF COMBINED HEAT POWER PLAINT AND MECHANANICAL PROPERTIES IN CONCRETE (열병합발전소 플라이애쉬 품질 및 콘크리트의 역학적 특성)

  • Lee, Sang-Soo;Back, Myung-Jong;Won, Cheol;Ahn, Jae-Hyen;Park, Chil-Lim
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.10a
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    • pp.69-74
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    • 1995
  • The primary purpose of this study is to investigate reusal techniques of fly ash of combined heat power plant in the construction field, which may contribute to the saving of construction materials and conservating environment. Firstly chemical and physical characteristics of fly ash is analysed. And then, the usability of the concrete is tested by investigating the flowablility and stength development through parameters of various replacement ratios with respect to different mixing conditions. Finally, the durability and mechanical properties(elastic modulus) of the concrete is tested. As the result of the study, the following conclusions are derived : (1) the quantity of the CaO in the fly ash is relatively high based on the chemical analysis, (2)the compressive strength ratio of the mortar is satisfied with the specification, but the unit water ratio increased, (3)high strength concrete of more than 400kg/$\textrm{cm}^2$ can be developed in the ranges of FA 30%, W/B 40%, (5)the slump loss with the elapsed time due to the delivery is decreased as the replacement ratio of the fly ash is increased, (6)the modulus of the elasticity is matched withn the specification of the Architectural Institute of Korea.

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hydration of the Fly Ash-CaO System in the Presence of Various Chemical Activators (화학 활성화제에 의한 플라이애쉬-생석회계의 수화반응)

  • 송종택;김재영;류동우;고상렬;한경섭
    • Journal of the Korean Ceramic Society
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    • v.35 no.2
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    • pp.185-195
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    • 1998
  • This experiment carried out in order to investigate the effect of the chemical activators for acceleration of hydration the system of Fly ash-Cao The paste was consisted of 80wt% Fly ash and 20wt% CaO with 1. 3. 5wt% of 4 activators(N{{{{ alpha _2 }}S{{{{ OMICRON _4 }}, CaC{{{{ {l }_{2 } }}, NaOH, Ca(N{{{{ OMICRON _3 {)}_{2 } }} and W/S ratio of 0.42 After curing for 1, 3, 7, 14, 28 days the paste hydration was characterized by the measurement of compressive strength XRD analysis SEM observation the combined water and the reaction amount of Ca(OH)2 determination. As a result of this ex-periment all of the system which involved Na2SO4 or NaOH had a god compressive strength. In the case of 7 days curing a system which added CaCl2 showed the highest compressive strength among all especially NaOH system showed a high increase in strength as a dosage of it increased. Hydration products were different according to activatores added. Only C-S-H was observed in NaOH system. As the reaction amount of Ca(OH)2 and combined water were increased the compressive strength increased. There were few differences in the comparision of strength between ignited loss 3.1% and loss 9.3% of fly ash.

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A Study on The Resilient Modulus of Coal Ash (석탄회(石炭灰)의 MR특성(特性)에 관한 연구(硏究))

  • Chun, Byung Sik;Oh, Min Yeoul;Kwon, Hyung Seok
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.12 no.3
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    • pp.215-220
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    • 1992
  • The rational methods of pavement design and analysis using the resilient modulus have been increasingly adopted by major advanced countries and many researches concerning the resilient characteristics of pavement materials as well as developement of reliable testing method have been actively performed. Accordingly, fundamental researches on the resilient modulus characteristics of domestic subgrade soils are very important. With want of aggregate due to the national constuction projects, it is siginificant to examine on the utilization of coal ash as pavement materials. The purpose of this study is to examine resilient modulus characteristics and to evaluate the relationship between MR and CBR by AASHTO testing method. The materials for this investigation are Coal Ash (Fly Ash, Bottom Ash) from 5 thermal-power-plants and 4 decomposed-granite-soils from central regions of Korea.

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Analysis of Contents and Deviations of Chemical Constituents of flue-cured leaf Tobacco from 1997 to 2001 Crop Years (연산별 황색종 가공엽의 화학성분 함량 및 편차 분석)

  • 김상범;정기택;조수헌;김용규
    • Journal of the Korean Society of Tobacco Science
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    • v.25 no.1
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    • pp.20-26
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    • 2003
  • To investigate the effects of reduction of leaf processing factories on the uniformity of processed leaf quality, the contents and their C.V.(Coefficient of Variation) of chemical constituents of flue-cured leaf tobacco produced from 1997 to 2001 and processed at various factories were analysed. The average leaf chemical contents of 12 grades for 5 years ranged as follows ; nicotine 2.00∼0.85%. total sugar 10.7∼16.9%, total nitrogen 2.36∼2.78%, crude ash 14.6∼15.6% and chlorine 0.50∼0.75%. The variations of chemical contents among crop years was higher in total sugar content while lower in crude ash content. The C.V. of chemical content in same grade leaves was higher in chlorine content while lower in total nitrogen and crude ash contents, and the ratio of C.V. among processing factories/C.V. in total population was higher in total sugar content while lower in crude ash content. When the leaves were processed at one factory, the deviations of chemical contents reduced considerably. Particularly, the decreasing effect of deviation was higher in total sugar content.

A Study on the Distribution of Heavy Metal Concentrations in Marine Surface Sediments around Samcheonpo Power Plant (삼천포화력발전소 주변해역 표층퇴적물중의 중금속원소함량 분포 연구)

  • Lee, Doo-Ho;Lim, Ju-Hwan;Jeon, Byeong-Yeol;Jeong, Nyeon-Ho
    • Journal of Environmental Impact Assessment
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    • v.9 no.1
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    • pp.1-11
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    • 2000
  • An environmental geochemical survey of heavy metal distribution in marine surface sediments around the ocean of Samcheonpo coal-fired power plant was conducted to investigate the possibility of coal-ash leakage from ash pond and the associated heavy metal pollution in sedimental deposits due to the operation of the coal-fired power plant. The X-Ray Diffractometry (XRD) analysis showed that the main leakage point of coal-ash was limited to a single site of the first ash pond. It also appeared that the amounts of organic carbon and metal elements were positively correlated to the grain size distribution, and that Co, Cr, Cu, Fe, Ni, and Zn were bounded to organic ligands. However, the distributions of Cd, Hg, and Mn did not have any significant correlation with the sediment grain size and organic matters. In particular, the distribution of Cd appeared to be affected by the concentration of the carbonate materials in the study area.

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