• Title/Summary/Keyword: arrhenius equation

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Consideration of Geosynthetics Chemical Resistance Test for Long-Term Performance Evaluation (장기성능 평가를 위한 토목섬유 화학저항성 시험 고찰)

  • Jeon, Han-Yong;Jang, Yeon-Soo
    • Journal of the Korean Geotechnical Society
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    • v.25 no.7
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    • pp.55-64
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    • 2009
  • In this study, improved test methods, which consider the real site test conditions, were suggested to measure for geosynthetics chemical resistance. For this purpose index and performance tests were done to specify and regulate the test method most approaching to the installation condition and accelerated model by Arrhenius equation was applied to interpretate the experimental data. Through the analysis and comparison of the overall experimental results, we could suggest the possibility and setup of the advanced chemical resistance test method for geosynthetics fitting to the field installation conditions.

Cure Kinetics of DGEBA/MDA/HQ-PGE System (DGEBA/MDA/HQ-PGE계의 경화 반응 속도론)

  • Song, Young-Wook;Shim, Mi-Ja;Kim, Sang-Wook
    • Applied Chemistry for Engineering
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    • v.7 no.2
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    • pp.356-361
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    • 1996
  • Cure kinetics of diglycidyl ether of bisphenol A(DGEBA)/4,4'-methylene dianiline(MDA) with hydroquinone-phenyl glycidyl ether(HQ-PGE) as a reactive additive, which was preliminarily synthesized, was investigated by DSC and FT-IR analyses. Kissinger equation and Arrhenius' equation were used to calculate activation energy and pre-exponential factor. When HQ-PGE was added to DGEBA/MDA system, it reduced activation energy of system. When the 5 phr of HQ-PGE was added to DGEBA/MDA system, activation energy was 7.8 kcal/mol by FT-IR analysis and 11.3 kcal/mol by DSC, in comparison with the system without HQ-PGE, activation energy decreased about 30% and 9%, respectively. According to these results, HQ-PGE, introducing agent of this system, acted as a catalyst.

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Fracture Mechanics Applied to Fatigue Crack Growth Behavior at Elevated Temperatures (고온 피로균열 성장거동에 관한 파괴역학의 응용에 관한 연구)

  • 서창민;김영호
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.6
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    • pp.1552-1560
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    • 1990
  • A general form of the mathematical function in the fatigue crack growth rate law for CT specimens was determined by means of the dimensional analysis at elevated temperatures. The experimental results can be rigorously described by the combination of rate theory and fracture mechanics. The rate theory approach extends the scope of fracture mechanics through the consideration of the temperature. The fatigue crack growth rates are represented by the Arrhenius type equation. This equation explains fairly well the experimental data for Cr-Mo-V rotor steel and A517-F steel in the comparatively wide temperature regions as affected with the temperature and the stress intensity factor range interaction.

Prediction Method of Useful Life of PVC Tape for Wiring Harness (와이어링 PVC 테이프 내구 수명 예측)

  • Kim, Seong-Woo;Jung, Won-Wook;Park, Jong-Koo;Ahn, Mi-Jung
    • Journal of Applied Reliability
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    • v.7 no.4
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    • pp.163-172
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    • 2007
  • Phenomenon, such as hardening, cracking or breaking etc.. of PVC tape for wiring harness by aging were detected on driven automobile in field. Hardening or cracking of PVC tape were confirmed decline of elongation by surrounding stress. The accelerated heat aging test was carried out applying temperature most important factor of aging, and then deduced an equation of useful life using arrhenius model. Prediction method of useful life of PVC tape was developed using miner rule calculating damage value by thermal energy classified temperature by matching deduced equation of useful life and measured temperature value on driven automobile in field.

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Oxidation Study on the Fabrication of Fe-36Ni Oxide Powder from Its Scrap

  • Yun, Jung Yeul;Park, Man Ho;Yang, Sangsun;Lee, Dong-Won;Wang, Jei-Pil
    • Journal of Powder Materials
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    • v.20 no.1
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    • pp.48-52
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    • 2013
  • A study of oxidation kinetic of Fe-36Ni alloy has been investigated using thermogravimetric apparatus (TGA) in an attempt to define the basic mechanism over a range of temperature of 400 to $1000^{\circ}C$ and finally to fabricate its powder. The oxidation rate was increased with increasing temperature and oxidation behavior of the alloy followed a parabolic rate law at elevated temperature. Temperature dependence of the reaction rate was determined with Arrhenius-type equation and activation energy was calculated to be 106.49 kJ/mol. Based on the kinetic data and micro-structure examination, oxidation mechanism was revealed that iron ions and electrons might migrate outward along grain boundaries and oxygen anion diffused inward through a spinel structure, $(Ni,Fe)_3O_4$.

Consideration of Geosynthetics Chemical Resistance Test for Long-Term Performance Evaluation (장기성능 평가를 위한 토목섬유 화학저항성 시험 고찰)

  • Jeon, Han-Yong;Jang, Yeon-Soo;Gong, Hak-Bong
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.03a
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    • pp.222-232
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    • 2009
  • In this study, the real site test conditions were considered and applied to suggest the improved test method for geosynthetics chemical resistance. For this, index and performance tests were done to specify and regulate the more approached test method. Accelerated model by Arrhenius equation was applied to interpretate the experimental data. Through analysis and comparison the overall experimental results, we could suggest the possibility and setup the advanced chemical resistance test method for geosynthetics.

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The Condition Assessment of Cast Resin Molded Transformer Windings Using Vertical Analysis of Thermal Distribution

  • Lim Young-Bae;Jung Jong-Wook;Jung Jin-Soo;Cho Seong won;Kim Joon-Bum
    • KIEE International Transactions on Electrophysics and Applications
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    • v.5C no.5
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    • pp.191-195
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    • 2005
  • This paper presents an assessment method in integrity of the windings in cast resin molded transformers by using vertical analysis of thermal distribution. The proposed method is to compare the temperature distribution in a sound specimen with that in the faulted specimen with a layer to layer short circuit. Temperature distribution was acquired by an infrared thermography system, and the Arrhenius equation was adopted to the accelerated test. The proposed method can be used to detect the failures in the transformers.

The Theoretical Calculations of Kinetic and Thermodynamics Parameters and Anharmonic Correction for the Related Reactions of NO3

  • Yu, Hongjing;Liu, Yancheng;Xia, Wenwen;Wang, Li;Jiang, Meiyi;Hu, Wenye;Yao, Li
    • Journal of the Korean Chemical Society
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    • v.65 no.6
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    • pp.419-432
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    • 2021
  • According to the transition state (TS) theory, Gaussian software and Yao and Lin (YL) method, the thermodynamics and kinetic data respectively were calculated, and anharmonic effect was considered for related reactions of NO3. The methods of calculating and fitting kinetic and thermodynamics parameters were provided by least square method and related equations in this paper. Notably, the fitted E of Arrhenius equation was close to the calculated barrier of related reaction by QCISD(T) method. Therefore, the kinetic fitting result can well express the physical meaning of E in Arrhenius equation. Besides, the conversion process and the reaction mechanism of NO3 were researched. For NO3, it seemed that its instability results from its easy reaction with other substances rather than the decompose reaction of itself.

A Study on Cable Lifetime Evaluation Based on Characteristic Analysis of Insulation Resistance by Acceleration Factor of the Arrhenius Equation (아레니우스 방정식의 가속인자를 만족하는 절연저항특성 분석에 의한 케이블 수명평가 연구)

  • Um, Kee-Hong;Lee, Kwan-Woo
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.14 no.5
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    • pp.231-236
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    • 2014
  • With the development of industry these days, the demand for electric power increases and the larger capacity for power transfer is required. The scales of facilities should become larger; and the relative systems are required to operate with a higher degree of reliability. Therefore, stabilization of electric power systems is an important issue. The high degree of reliability required in the process of production and supply of electric power is an essential part of industrial society. Accident such as blackouts causes a hugh amount of economic losses to the high-tech industrial society dependent upon electric power. In this paper, in order to determine a stable operation of high-voltage power cable, used as a unique means of delivering electric power generated at a power station, we figure out the time rate of change of insulation resistance following a decay accelerating factor Arrhenius equation. With the data from the insulation resistance, we can determine the lifetime of power cable in operation.