• Bulletin of the Korean Chemical Society
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• v.31 no.10
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• pp.3038-3040
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• 2010

• International Journal of Highway Engineering
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• v.3 no.1 s.7
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• pp.177-184
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• 2001

A recycling agent has been manufactured on the basis of the chemical composition of reclaimed asphalt binders and virgin asphalt binders. The chemical compositions of reclaimed asphalt binders extracted from reclaimed asphalt pavements have been analyzed according to the ASTM method and the results were compared to those of virgin asphalt binder AP-3. Reclaimed asphalt binders have shown that asphaltenes was increased whereas saturates, naphthene aromatics, and polar aromatics fractions were decreased. A recycling agent made of aromatic compounds, in which its chemical composition is similar to the aromatics fraction in asphalt binders, has been produced to reduce the amount of asphaltenes in reclaimed asphalt hinders. The evaluation of the recycling agent produced was performed by testing ductility, rolling and ball softening point, penetration at $25^{\circ}C$ and viscosity at $60^{\circ}C$. It was found that, by adding the recycling agent 20% by weight to the reclaimed asphalt binders, the physical properties of reclaimed asphalt binders was recovered to the level of virgin asphalt binder AP-3.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.4
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• pp.371-377
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• 2011

The aim of this study is to investigate the effects of aromatics and T90 temperature for high cetane number (CN) of diesel fuels on combustion and exhaust emissions in low-temperature diesel combustion in a 1.9 L common rail direct injection diesel engine at 1500 rpm and 2.6 bar BMEP. Four sets of fuels with CN 55, aromatic content of 20% or 45% (vol. %), and T90 temperature of $270^{\circ}C$ or $340^{\circ}C$ were tested. Given engine operating conditions, all the fuels showed the same tendency of decrease of PM with an increase of an ignition delay time. At the same ignition delay time, the fuels with high T90 produced higher PM. At the same MFB50% location the amount of NOx was similar for all the fuels. Furthermore, at the same ignition delay time the amounts of THC and CO were similar as well for all the fuels. The amount of THC and CO increased with an extension of the ignition delay time mainly because of the increase of fuel-air over-mixing.

• Applied Chemistry for Engineering
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• v.1 no.2
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• pp.240-248
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• 1990

The catalytic activity and selectivity of metal loaded H-mordenite for transalkylation of $C_9$ aromatics were studied in a continuous flow fixed bed reactor under high pressure. Nickel loaded H-mordenite(T-Ni) catalyst showed high activity and slow decay of activity. Molybdenum and nickel loaded H-mordenite(T-NiMo) catalyst also showed high activity and suppressed coking of hydrocarbons. The selectivity of xylene for T-Ni and T-NiMo catalysts decreased with temperature, but that for T catalyst(commercial grade) monotonically increased with temperature within the experimental range. The performance of T-Ni and T-NiMo catalysts was better than that of T catalyst in terms of initial activity and its decay. The addition of Mo improved slightly stability of T-Ni catalyst.

• Journal of the Korean Chemical Society
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• v.25 no.2
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• pp.97-102
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• 1981

The conversion of methanol to hydrocarbons has been studied over synthetic ZSM-5 zeolite catalyst having high silica to alumina ratio. The conversion products were olefins, paraffins, cycloparaffins, and aromatics, and the catalyst showed especially high selectivity toward the formation of aromatics. The catalyst showed the shape-selectivity and the size of molecules in the product was limited approximately to the size of 1,3,5-trimethylbenzene. Hydrogen form(HZSM-5) was more active, indicating reactions following the dehydration of methanol seemed to be mainly catalyzed by acid sites. Comparison of the reaction characteristics and acid site distribution of the ZSM-5 catalyst with those of mordenite and faujasite type catalysts suggests that cross-linked pore channel structure and the strong acidity of the ZSM-5 catalyst are primarily responsible for the selective formation of aromatics over this catalyst.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.12
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• pp.1121-1126
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• 2010

This study is to investigate the effects of aromatics and T90 for low cetane number (CN) fuels on combustion and exhaust emissions in low-temperature diesel combustion. We use a 1.9-L common rail direct injection diesel engine at 1500 rpm and 2.6 bar BMEP. Low temperature diesel combustion was achieved via a high external EGR rate and strategic injection control. The tested fuels four sets: the aromatic content was 20% (A20) or 45% (A45) and the T90 temperature was $270^{\circ}C$ (T270) or $340^{\circ}C$ (T340) with CN 30. Given the engine operating conditions, the T90 was the stronger factor on the ignition delay time, resulting in a longer ignition delay time for higher T90 fuels. All the fuels produced nearly zero PM because of the extension of the ignition delay time induced by the low cetane number. The aromatic content was the main factor that affected the NOx and the NOx increased with the aromatic content.

• Journal of the Korean Chemical Society
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• v.40 no.7
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• pp.515-518
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• 1996

Functional conversion of polybrominated fullerenes has been discussed. These reactions are Friedel-Crafts fullerylation of aromatics, methoxylation and phosphorylation of polybrominated fullerenes.

• Bulletin of the Korean Chemical Society
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• v.15 no.7
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• pp.519-520
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• 1994

• Transactions of the Korean hydrogen and new energy society
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• v.13 no.1
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• pp.42-51
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• 2002

Methane can be converted directly to hydrogen by pyrolysis. The reaction is highly endothemic and heat must be supplied at high temperatures. Gibbs free energy minimization calculations have been carried out for the methane pyrolysis to determine equilibrium products. The calculation parameters are the temperature, the initial H/C ratio, the pressure and Gibbs energies of each substance. Methane, ethylene, acetylene, benzene, naphthalene, and hydrogen are the main products. Excluding hydrogen, it is observed that ethylene and aromatics(benzene+naphthalene) are predominant products below 1400K, whereas acetylene is significantly formed above 1400K. Hydrogen dilution increases the selectivities for ethylene and acetylene and decreases the selectivity for aromatics. Increasing the pressure also decreases the decomposition of methane.

• Journal of Microbiology
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• v.38 no.3
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• pp.183-186
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• 2000

Several types of bioluminescent reporter strains have been developed for the detection and monitoring of pollutant aromatics contaminating the environment. In this study, a bioluminescent reporter strain, E. coli SHP3, was constructed by fusing the luc gene of firefly luciferase with the promoter of pcbC responsible for the meta-cleavage of aromatic hydrocarbons. the bioluminescence expressed by the luc gene in the reporter was well triggered by the promoter when it was exposed to 2,3-dihydroxybiphenyI (2,3-DHBP) at 0.5 to 1 mM concentrations. The bioluminescent response was more extensive when the reporter strain was exposed to 5 mM catechol and 2 mM 4-chlorocatechol. These different types of bioluminescent responses by E. coli SHP3 appeared to be characterized by the nature of the aromatics to stress. Since E. coli SHP3 responded to 2,3-DHBP quite sensitively, this reporter strain could be applied for detecting some catecholic pollutants.