• Title/Summary/Keyword: aromatic

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Sonochemical Reaction of Fullerene Oxides, [C70(O)n](n≥1) with Aromatic Amines (방향족 아민 화합물과 풀러렌 산화물의 [C70(O)n](n≥1)의 초음파 화학 반응)

  • Ko, Weon-Bae;Park, Byoung-Eun;Lee, Young-Min
    • Elastomers and Composites
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    • v.43 no.1
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    • pp.31-38
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    • 2008
  • Sonochemical reaction of fullerene oxides, $[C_{70}(O)_n](n\geq1)$ with several aromatic amines such as 4-nitroaniline, 3-nitroaniline, and 4-isopropylaniline, in the presence of $FeCl_3$ were investigated under ultrasonic irradiation. This method is applicable to a wide variety of aromatic amines especially ring deactivated, to afford the corresponding cleavage products under mild conditions. The aminated fullerenes were confirmed by MALDI-TOF-MS and UV-vis spectra.

Complete genome sequence of Runella sp. ABRDSP2, a new mono-aromatic compounds degrading bacterium isolated from freshwater (담수로부터 분리한 단환성 화합물 분해 미생물 Runella sp. ABRDSP2의 전장 유전체 서열)

  • Kang, Hye Kyeong;Ryu, Byung-Gon;Choi, Kyung Min;Jin, Hyun Mi
    • Korean Journal of Microbiology
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    • v.55 no.1
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    • pp.55-57
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    • 2019
  • The Runella sp. ABRDSP2, capable of degrading mono-aromatic compounds such as toluene, was isolated from freshwater. The whole genome, consisting of a circular single chromosome and three plasmids, was composed of total 7,613,819 bp length with 44.4% G+C contents and 6,006 genes. The genome of strain ABRDSP2 contains many aromatic hydrocarbon degrading genes such as monooxygenase, ring-cleaving dioxygenase, and catechol 1,2-dioxygenase. The complete genome reveals versatile biodegradation capabilities of Runella sp. ABRDSP2.

Accumulation and Characterization of Polycyclic Aromatic Hydrocarbons in Seafood from the Coastal Areas of Korea

  • Moon Hyo-Bang;Choi Hee-Gu;Kim Sang-Soo;Lee Pil-Yong
    • Fisheries and Aquatic Sciences
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    • v.5 no.2
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    • pp.127-135
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    • 2002
  • Twenty seafood samples, which are common edible species and commercially important items in Korea, were purchased at the local fisheries markets and were analyzed for polycyclic aromatic hydrocarbons (PAHs) using gas chromatography coupled to mass spectrometer detector (GC/MSD). The levels of sixteen PAHs in seafood from Korean coasts were 161 to 2,243 pg/g wet weight. The highest concentration was found at saury (Coloabis saira) and the lowest level was found at jacopever (Sebastes schlegeli). The concentrations of potentially carcinogenic PAHs of six species were in the range of 9 to 123 pg/g wet weight. The residues of PAHs in fishes from Korean coasts were slightly low or relatively moderate to other countries. There was no correlation between PAH residues and lipid contents in seafood samples. The predominant contributors in fish samples were lower-molecular-weight two and three ring aromatic PAHs such as naphthalene, acenaphthene, fluorene and phenanthrene. Filter-feeding organisms like shrimp, crab and topshell were dominated by three- and four-ring aromatic PAHs. The PAH profiles in marine sediments, bivalves, fishes, shrimp, crab and topshell according to exposure pathway were compared through factor analysis. The PAH profiles were clearly classified by the difference of species or environmental matrices. This result suggests that most of PAHs within the same samples behave identically in marine environment.

Investigation of gene encoding catechol 1,2-dioxygenase from Phenol-degrading, Rhodococcus sp. EL-GT

  • Lee, Hui-Jeong;Han, Chang-Min;Jo, Sun-Ja;Park, Geun-Tae;Park, Jae-Rim;Lee, Sang-Jun
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.549-551
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    • 2001
  • The heavy use of petroleum products in modern livings has brought ubiquitous environmental contaminants of aromatic compounds, which persist in aquatic and geo-environment without the substantial degradation. The persistence and accumulation of the aromatic compounds, which include xylene, phenol, toluene, phthalate, and so on are known to cause serious problems in our environments. Some of soil and aquatic microorganisms facilitate their growth by degrading aromatic compounds and utilizing degrading products as growth substrates, the biodegradation helps the reentry of carbons of aromatic compounds, preventing their accumulation in our environments. The metabolic studies on the degradation of aromatic compounds by microoganisms were extensively carried out along with their genetic studies. A Rhodococcus sp. EL-GT isolated in activated sludges has shown the excellent ability to grow on phenol as a sole carbon source. In the present study investigated a gene encoding phenol-degrading enzymes from a Rhodococcus sp. EL-GT.

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Cell Biological Studies of the Effect of Aromatic Amino Acids on Early Development of Chick Embryo (방향족 아미노산이 초기계배에 미치는 영향에 관한 세포생물학적 연구)

  • 최임순;주충노;최춘근;김재원
    • The Korean Journal of Zoology
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    • v.28 no.4
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    • pp.257-278
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    • 1985
  • The effect of aromatic amino acids such as phenylalaine, tryptophan and tyrosine on somitogenesis at the early stage of chick embryo has been investigated morphologically using light and electron microscopy. Micrographs of aromatic amino acid injected chick embryo showed that an incomplete somite segmentation occurred and some decremental effect on the nervous system were observed. Somites were poorly developed and their size were variable. Electron micrograph of somatic cells from aromatic amino acid injected chick embryo showed that chromatins were coagulated, some of mitochondria were damaged, and nucleus were transformed considerably in some cases. The protein and nucleic acid levels and some enzyme activities of 15-day chick embryo which received the injection of 1mg of aromatic amino acid in 0.05 ml of saline 24 hours after the incubation were analyzed. Protein, DNA and RNA levels of the test group were not lowered significantly but the activities of enzymes for basic metabolism, such as lactate dehydrogenase, succinate dehydrogenase, malate dehydrogenase and glucose 6-phosphate dehydrogenase were considerably lowered as compared with those of control. From the present expeerimental results, it was tentatively suggested that the administration of amino acid might slow down the yolk granule degradation probably by feed back mechanism resulting in the disturbance of amino acid balance in the cell, which might give rise to impair normal metabolic pattern leading to abnormal somitogenesis to chick embryo at very early stage of development.

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The Study on Classification of Aromatic Herbs in Oriental Medicine for Aromatherapy (방향성(芳香性) 본초(本草) 분류를 통한 향기요법(香氣療法) 연구(硏究))

  • Uhm, Ji-Tae;Kim, Kyoung-Shin;Kang, Jung-Soo;Kim, Byoung-Soo
    • Journal of Haehwa Medicine
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    • v.20 no.1
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    • pp.39-50
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    • 2011
  • In western, aromatherapy uses essential oils to prevent and treat disease, and is one of the ways to stay healthy. In oriental medicine, there was also a similar medical treatment using aromatic herbs for a long ago. The exisiting research of oriental medical herbs is mainly focused on the theory of qi and flavor(氣味論). But on aromatherapy used with aromatic herbs, it is necessary to study the aromatic herbs by aroma. So "xi$\bar{a}$ng p$\check{u}$, 香譜" and "b$\check{e}$n c$\check{a}$o g$\bar{a}$ng m$\grave{u}$, 本草綱目" mainly contain the study about clinical effects of aromatic herbs. And "b$\check{e}$n c$\check{a}$o p$\check{i}$n hu$\grave{i}$ j$\bar{i}$ng y$\grave{a}$o, 本草品彙精要"mainly explains the effects of medical herbs with five aroma classification of x$\bar{i}$ng(腥), sh$\bar{a}$n(膻), xi$\bar{a}$ng(香), ch$\grave{o}$u(臭), xi$\check{u}$(朽). The former one makes more clinical uses of medical herbs, and the latter one grows up the theory of medical herbs. This study is expected to have a good influence on aromatherapy and classification of oriental medical herbs.

Group Contribution Method and Support Vector Regression based Model for Predicting Physical Properties of Aromatic Compounds (Group Contribution Method 및 Support Vector Regression 기반 모델을 이용한 방향족 화합물 물성치 예측에 관한 연구)

  • Kang, Ha Yeong;Oh, Chang Bo;Won, Yong Sun;Liu, J. Jay;Lee, Chang Jun
    • Journal of the Korean Society of Safety
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    • v.36 no.1
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    • pp.1-8
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    • 2021
  • To simulate a process model in the field of chemical engineering, it is very important to identify the physical properties of novel materials as well as existing materials. However, it is difficult to measure the physical properties throughout a set of experiments due to the potential risk and cost. To address this, this study aims to develop a property prediction model based on the group contribution method for aromatic chemical compounds including benzene rings. The benzene rings of aromatic materials have a significant impact on their physical properties. To establish the prediction model, 42 important functional groups that determine the physical properties are considered, and the total numbers of functional groups on 147 aromatic chemical compounds are counted to prepare a dataset. Support vector regression is employed to prepare a prediction model to handle sparse and high-dimensional data. To verify the efficacy of this study, the results of this study are compared with those of previous studies. Despite the different datasets in the previous studies, the comparison indicated the enhanced performance in this study. Moreover, there are few reports on predicting the physical properties of aromatic compounds. This study can provide an effective method to estimate the physical properties of unknown chemical compounds and contribute toward reducing the experimental efforts for measuring physical properties.

Analysis of the aromatic components of the forest bathing (삼림욕 향기 성분 분석)

  • 노택우;윤석신
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.17 no.1
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    • pp.29-38
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    • 1991
  • As the suitable place of the forest bathing, Two places of the needle-leaf trees, which are located in the Oh-Saek mineral spring near place from the Sorak mountain, were selected. And then, Headspace gas trapping apparatus were setted in that two places and the aromatic components of the forest were adsorbed by Tenax-TA column for 24 hours. And Tenax-TA column were analyzed by the GC SE GC-MS. The analyzed components were found to contain up to between 70-80% of pollutants, which are Toluene, Methyl Chloride, Hexane, p-Xylene, Benzene, ... etc. On the other hand, the aromatic components of the forest, which give aromatheraphitical effectness, are as follow: alpha-Pinene, Limonene, 1, 8-Cin-eol, Benzaldehyde, . . . etc.

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Development of Whitenin Agents by Synthesis of Polyhydroxy Aromatic Compounds

  • Hyun-Ho Lee;You
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.23 no.3
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    • pp.86-91
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    • 1997
  • Some natural polyhydroxy aromatic compounds have inhibitory activity against tyrosinase, key enzyme for formation of melanin pigment. We examined the structure-activity relationship of the natural polyhydrowy aromatic compounds and synthesized a number of new derivetives through various methods. Skin lightening effects of these compounds were examined through inhibition of mushroom tyrosinase and inhibitory of melanogenesis on B-16 melanoma cells. These new compounds showed strong inhibitory activity against tyrosinase. Good lightening effects sue to inhibition of melanogenesis were observed from several resorcinol and pyrogallol derivatives. In toxicological tests such as skin primary irritation and sensitization, the above compounds were sufficiently safe for cosmetic use.

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One-pot, Three-component Synthesis of Fully Substituted 1,3,4-Oxadiazole Derivatives from (N-Isocyanoimino)triphenylphosphorane, Aromatic Carboxylic acids and (1R)-(-)-Campherchinon

  • Ramazani, Ali;Nasrabadi, Fatemeh Zeinali;Abdian, Behnaz;Rouhani, Morteza
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.453-458
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    • 2012
  • Reactions of (N-isocyanimino)triphenylphosphorane with (1R)-(-)-campherchinon in the presence of aromatic carboxylic acids proceed smoothly at room temperature and in neutral conditions to afford sterically congested 1,3,4-oxadiazole derivatives in high yields. The reaction proceeds smoothly and cleanly under mild conditions and no side reactions were observed.