• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2000.11a
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• pp.3-4
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• 2000

Many researchers are interested in the synthesis and characterization of carbon nitride and diamond-like carbon (DLq because they show excellent mechanical properties such as low friction and high wear resistance and excellent electrical properties such as controllable electical resistivity and good field electron emission. We have deposited amorphous carbon nitride (a-C:N) thin films and DLC thin films by shielded arc ion plating (SAIP) and evaluated the structural and tribological properties. The application of appropriate negative bias on substrates is effective to increase the film hardness and wear resistance. This paper reports on the deposition and tribological OLC films in relation to the substrate bias voltage (Vs). films are compared with those of the OLC films. A high purity sintered graphite target was mounted on a cathode as a carbon source. Nitrogen or argon was introduced into a deposition chamber through each mass flow controller. After the initiation of an arc plasma at 60 A and 1 Pa, the target surface was heated and evaporated by the plasma. Carbon atoms and clusters evaporated from the target were ionized partially and reacted with activated nitrogen species, and a carbon nitride film was deposited onto a Si (100) substrate when we used nitrogen as a reactant gas. The surface of the growing film also reacted with activated nitrogen species. Carbon macropartic1es (0.1 -100 maicro-m) evaporated from the target at the same time were not ionized and did not react fully with nitrogen species. These macroparticles interfered with the formation of the carbon nitride film. Therefore we set a shielding plate made of stainless steel between the target and the substrate to trap the macropartic1es. This shielding method is very effective to prepare smooth a-CN films. We, therefore, call this method "shielded arc ion plating (SAIP)". For the deposition of DLC films we used argon instead of nitrogen. Films of about 150 nm in thickness were deposited onto Si substrates. Their structures, chemical compositions and chemical bonding states were analyzed by using X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy and infrared spectroscopy. Hardness of the films was measured with a nanointender interfaced with an atomic force microscope (AFM). A Berkovich-type diamond tip whose radius was less than 100 nm was used for the measurement. A force-displacement curve of each film was measured at a peak load force of 250 maicro-N. Load, hold and unload times for each indentation were 2.5, 0 and 2.5 s, respectively. Hardness of each film was determined from five force-displacement curves. Wear resistance of the films was analyzed as follows. First, each film surface was scanned with the diamond tip at a constant load force of 20 maicro-N. The tip scanning was repeated 30 times in a 1 urn-square region with 512 lines at a scanning rate of 2 um/ s. After this tip-scanning, the film surface was observed in the AFM mode at a constant force of 5 maicro-N with the same Berkovich-type tip. The hardness of a-CN films was less dependent on Vs. The hardness of the film deposited at Vs=O V in a nitrogen plasma was about 10 GPa and almost similar to that of Si. It slightly increased to 12 - 15 GPa when a bias voltage of -100 - -500 V was applied to the substrate with showing its maximum at Vs=-300 V. The film deposited at Vs=O V was least wear resistant which was consistent with its lowest hardness. The biased films became more wear resistant. Particularly the film deposited at Vs=-300 V showed remarkable wear resistance. Its wear depth was too shallow to be measured with AFM. On the other hand, the DLC film, deposited at Vs=-l00 V in an argon plasma, whose hardness was 35 GPa was obviously worn under the same wear test conditions. The a-C:N films show higher wear resistance than DLC films and are useful for wear resistant coatings on various mechanical and electronic parts.nic parts.

• Journal of the Society of Naval Architects of Korea
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• v.58 no.3
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• pp.175-181
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• 2021

This study describes the model tests in ice according to the frictional coefficient of an ice-breaking ship and the change in ice resistance by the analysis method for each component of ice resistances. The target vessel is a 90K DWT ice-breaking tanker capable of operating in ARC7 ice conditions in the Arctic Ocean, and twin POD propellers are fitted. The hull was specially painted with four different frictional coefficients on the same ship model. The total ice resistance can be separated by ice breaking, ice buoyancy, ice clearing resistances through the tests in level ice, pre-sawn ice and creep test in pre-sawn ice under sea ice thickness of 1.2 m and 1.7 m. Ice resistance was analyzed by correcting the thickness and bending strength of model ice by the ITTC correction method. As the frictional coefficient between the hull and ice increases, ice buoyancy and clearing resistances increase significantly. When the surface of the hull is rough, it is considered that the broken ice pieces do not slip easily to the side, resulting in an increase in ice buoyancy resistance. Also, the frictional coefficient was found to have a great influence on the ice clearing resistance as the ice thickness became thicker.

• Proceedings of the KIEE Conference
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• 1995.07c
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• pp.1117-1119
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• 1995

Fluoroplastics have been used widely for chemical or electrical facility materials and lubricable engineering structural materials because they have the superior characteristics such as thermal stability, chemical stability, solid lubricity, arc resistance, wearable durability and good sealing property. In this study, PTFE composite materials for the insolation parts of high voltage and current breaker were investigated and estimated.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.04b
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• pp.683-686
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• 1998

In this paper, we carried out the fundamental experiments on the resistance of chemical attack of mortar using the electric are furnace slag as fine aggregate. The mortar specimens made from the EAF slag as fine aggregate were immersed in four sorts of chemical solutions, and measured to investigate the change of compressive strength and weight. As the results of this study, it was found that compressive strength and weight were increased with incresing replacement ratio of the EAF slag.

• Proceedings of the Korean Society For Composite Materials Conference
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• 1999.11a
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• pp.77-82
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• 1999

탄소 fabric 표면을 각기 다른 농도의 인산용액으로 표면처리함으로써 2-D 카본/페놀릭 복합 재료에 미치는 물성과 내 산화성, Arc plasma Torch test를 통하여 내열성등을 알아보았으며 ESCA를 통하여 인산 표면 처리에 의한 표면 functionality를 측정하였다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1997.11a
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• pp.501-504
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• 1997

We investigated the tracking and erosion resistance of the silicone rubber by Inclined-Plane Method. And. with the variation of experiment time, the chance of the leakage current waveform was evaluated. The typical leakage current waveform was the form of mixture of sinusoidal wave and rectifying wave. It is thought that the sinusoidal wave is due to conductivity of contaminant when wet. and the rectifying wave is due to arc of dry band.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2007.11a
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• pp.7-9
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• 2007

Thin films of CrAlSiN were deposited on SKD11 tool steel substrate using Cr and AlSi cathodes by a cathodic arc plasma deposition system. The influence of process parameters on the deposited film properties were investigated. The oxidation characteristics of the films were studied at temperatures ranging from 800 and 1000+C up to 50 h in air. The films showed superhardness and good oxidation resistance..

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.3
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• pp.87-95
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• 2020

As an experimental study on the corrosion behavior of steel materials to which ATMS method using EIS was applied in concrete, immersion of Ca(OH)₂ saturated aqueous solution and NaCl aqueous solution simulating the environment inside concrete The corrosion behavior was tested. The equivalent circuit was derived through the analysis of the Nyquist plot, and the interfacial resistance and the polarization resistance of the Ca(OH)₂ aqueous solution were compared, and Al ATMS was the best interfacial resistance and Zn ATMS was the best polarization resistance. After burying ATMS steel material of cement mortar, the initial immersion impedance measurement value was the highest in the Zn ATMS test body in the impedance measurement by the immersion time by immersing it in the NaCl aqueous solution. Al ATMS test piece has the highest impedance and is highly reliable. This is because Al, which has a high ionization tendency, is continuously oxidized in a strong alkaline environment to form a film and protect the steel from permeation of chlorine ions.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 2000.06a
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• pp.179-193
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• 2000

Aluminium titanate (Al₂TiO5) with an excellent thermal shock resistant and a low the expansion coefficient was obtained by solid solution with MgO, SiO₂, and ZrO₂ in the Al₂TiO5 lattice or in the grain boundary solution through electrofusion in an arc furnace. However, these materials have low mechanical strength due to the presence of microcracks developed by a large difference in thermal expansion coefficients along crystallographic axes. Pure Al₂TiO5 tends to decompose into α-Al₂O₃ and TiO₂-rutile in the temperature range of 750-1300℃ that rendered it apparently useless for industrial applications. Several thermal shock tests were performed: Long therm thermal annealing test at 1100℃ for 100h; and water quenching from 950 to room temperature (RT). Cyclic thermal expansion coefficients up to 1500℃ before and after decomposition tests was also measured using a dilatometer, changes in the microstructure, thermal expansion coefficients, Young's modulus and strengths were determined. The role of microcracks in relation to thermal shock resistance and thermal expansion coefficient is discussed.

• Journal of the Korean institute of surface engineering
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• v.37 no.2
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• pp.128-136
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• 2004

Effects of alloying elements on the surface characteristics of Fe-38Al intermetallic compounds were investigated using potentiostat. The specimens were casted by the vacuum arc melting. The subsequent homogenization and the stabilization led to the homogeneous DO$_3$ structure of the specimen. After the corrosion tests, the surface of the tested specimen was observed by the optical microscopy and scanning electron microscopy(SEM). For Fe-38 at.% Al intermetallic compound, the addition of Cr and Mo proved to be beneficial in decreasing the grain boundary attack by decreasing the active current density. Addition of Band Nb resulted in a higher active current density and also a higher passive current density. These results indicated the role of Cr and Mo in improving the pitting corrosion resistance of Fe-38 at.%Al intermetallic compound. Band Nb addition to Fe-38 at.%Al accelerated the granular corrosion. Fe-38 at.%Al containing Cr and Mo showed remarkably improved pitting corrosion resistance in comparison with Band Nb addition to Fe-38 at. %Al.