• Transactions of the Korean Society of Mechanical Engineers B
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• v.41 no.4
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• pp.269-275
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• 2017

$NO_X$ reducing technique such as LNT, LNC, and selective catalytic reduction (SCR) have been developed and applied, especially on heavy-duty vehicles. However, it is expected that $NO_X$ reduction techniques will also be applied to diesel passenger vehicles. The urea-SCR system is receiving attention as the most effective $NO_X$ reduction technology without a fuel penalty. Thus, many advanced countries are developing this technology. The urea-SCR system sprays an aqueous urea solution that separates $NO_X$ into $N_2$ and $H_2O$, which are harmless and emitted into the atmosphere. The urea injected in front of the SCR catalyst should be changed to 100％ $NH_3$, which is required for $NO_X$ reduction in the SCR system to maximize the reduction efficiency. The purpose of this study was to determine the basic data for the urea-SCR system to maximize the $NO_X$ reduction efficiency by understanding the $NO_X$ reduction characteristics in a real passenger vehicle to comply with the post EURO-6 emission regulation.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.7
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• pp.541-548
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• 2009

Iron coated media (activated carbon, sand and starfish) were prepared at pH 4 and applied for the treatment of landfill leachate containing organic compounds and soluble metal ions such as $Zn^{2+},\;Cu^{2+},\;Mn^{2+}$ in batch and column experiment. The amount of iron coated in media was analyzed with EPA 3050B method. The removal efficiency of metal ions and phenol was compared with iron coated media. The amount of iron coated in Fe-AC and ICS(iron coated sand) were 1,612 mg/kg and 1,609 mg/kg, respectively, while it was higher with 1,768 mg/kg in ICSF(iron coated starfish). The result of batch study represent the highest removal efficiency in the treatment of wastewater using iron coated starfish. In column study, the removal efficiency of phenol and metal ions was higher in multi-layered system of ICS, Fe-AC and ICSF compared to single layered system. Breakthrough time in the effluent was relatively enhanced for $Cu^{2+}$ and $Zn^{2+}$ in multi-layered system while the removal efficiency of $Mn^{2+}$ were not varied much. Therefore, multi-layered system was identified as the better system for the treatment of wastewater containing of metal ions and organic compound.

• Journal of the Korean Society of Safety
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• v.7 no.2
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• pp.63-70
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• 1992

The aim of this research is to obtain a basic quantitative understanding of the effect of a noncondensable gas on the absorption of water vapor by a $H_2O$ / LiBr combination with n-octanol as the surfactant. Nonflowing aqueous solutions of LiBr (40,45,50 mass％) were exposed to saturated water vapor following the addition of an n-octanol sufactant (0.01 and 0.6 mass％). A small amount of a noncondensable gas (air) was allowed into the absorber (0.03 volume％) and its effect was analyzed by measuring the amount of water vapor absorbed. This study will aid to predict the performance of heat pump and safety operating condition when the noncondensable gas is not allowed in the absorber The results indicate that, in the presence of small amounts of a noncondensable gas, vapor absorption enhancement ratios are less than half o( those obtained under the same experimental conditions when a noncondensable gas is not present (1). The presence of a noncondensable gas causes the partial vapor pressure of air to increase at the vapor / liquid interface, which results in an instability of vapor absorption rate nd. hence, in an inhibition of interfacial disturbance.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.7
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• pp.1273-1284
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• 2000

In this study, ultrafiltration was performed to remove humic acid from aqueous solution. Since the effects of system variables on the ultrafiltration were tangled with non-linearly. Response Surface Methodology(RSM) was used to know optimum conditions of ultrafiltration process, relations among system variables, and the effects of system variables such as pressure difference across the membrane, concentration of humic acid, and feed flow rates. As concentrations of humic acid were 10ppm, 40ppm, and 70ppm in feed stream, permeation fluxes were 2.56, 2.27, and $2.10({\times}10^{-2}cc/cm^2{\cdot}min)$ respectively ; in other words, permeation fluxes of 10ppm, 40ppm and 70ppm feed concentration decreased by 17.7%, 26.7% and 32.2% of pure water permeation flux respectively. Concentration of humic acid in permeate side were 0.5ppm, 1.2 ppm, and 2.1ppm respectively. When pressure difference(${\Delta}P$) increased from 1atm to 2atm and 3atm, permeation fluxes of 40ppm feed concentration increased by 66% and 152% of permeation rate at 1atm respectively. However, concentrations of humic acid in permeate side increased from 0.5ppm to 1.5ppm and 3.5ppm. RSM showed that the optimum condition of system variables is 38.5~40ppm of humic acid concentration in feed stream, 30~30.7cc/min of feed flow rate, and 2atm of pressure difference.

• The Journal of Engineering Research
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• v.6 no.1
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• pp.97-109
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• 2004

The synthesis and crystal structure of amorphous calcium carbonate obtained from gas-liquid reaction of CaO-$C_2 H_5 OH$-$CO_2$ system according to change of added amount of calcium oxide by blowing $CO_2$ gas and reaction time using ethanol and ethylene glycol were investigated by electric conductivity, X-ray diffraction, and scanning electron microscope. The powdery or gelatinous phases were prepared by passing $CO_2$ gas at a flow rate of 1$\ell$/min into the suspensions containing 10~40g of CaO in mixing solutions 900ml of $C_2 H_5 OH$- and 100ml of ethylene glycol. By rapid filtration and drying the both phases at $60^{\circ}C$ under reduced pressure, the phases converted to the spherical vaterite and amorphous phase. The stable phase of amorphous calcium carbonate(ACC) was formed in the region pH 7-9 but the formation regions of amorphous phase were remarkably affected by pH in the mother liquor. It seems that a part of ACC changed into chain calcite as an intermediate products. The initial reactants prior to the formation of precipitated calcium carbonate is ACC. And ACC is unstable in the aqueous solution and crystallizes finally to calcite by the through-solution reaction. Especially ACC was produced or gelatinous phase which precipitated from the reaction of CaO-$C_2 H_5 OH$-$CO_2$ system.

• Korean Chemical Engineering Research
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• v.46 no.2
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• pp.356-368
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• 2008

The effects of cosurfactant on silica nanoparticles were investigated in systems containing surfactant, oil and aqueous ammonia solution where nanoparticles were prepared using a single phase water-in-oil (W/O) microemulsion. For the same oil phase, a single phase region was dependent on the interaction between surfactant and oil. For the cyclohexane system, NP-5 surfactant showed a wider single phase region than NP-4. The addition of n-propanol as a cosurfactant resulted in an increase or a decrease of a single phase W/O microemulsion region depending on the continuous oil phase. For both cyclohexane and isooctane systems, the addition of n-propanol resulted in a decrease in the single phase region. On the other hand, for n-heptane system, the addition of n-propanol expanded a single phase W/O microemulsion region. Silica nanoparticles prepared within a single phase region showed that relatively large number of particles of irregular shape were obtained with the addition of n-propanol to NP surfactant system. The addition of n-propanol to LA-5 surfactant and n-heptane system produced a decrease in average particle size and an increase in the number of particles formed due to a decrease in the intermicellar exchange rate among microemulsion droplets.

• Korean Chemical Engineering Research
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• v.53 no.1
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• pp.57-63
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• 2015

Absorption characteristics of 2-methylpiperidine (2MPD), 3-methylpiperidine (3MPD) and 4-methylpiperidine (4MPD) absorbents were studied by a vapor-liquid equilibrium (VLE) apparatus and a differential reaction calorimeter (DRC). Using a VLE apparatus, the $CO_2$ loading capacity of each absorbent was estimated. After reaching the absorption equilibrium, nuclear magnetic resonance spectroscopy (NMR) had been conducted to characterize the species distribution of the ($H_2O$-piperidine-$CO_2$) system. Using a DRC, the reaction of heat was confirmed in accordance with the absorption capacity. The unique characteristics of 2MPD, 3MPD and 4MPD absorbents appeared by the position of methyl group. The 2MPD possessing the methyl group at the ortho position showed its hindrance effect during the absorption process; however, piperidine derivatives possessing the meta position and para position did not show its characteristics in $H_2O$-piperidine-$CO_2$ system.

• Analytical Science and Technology
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• v.16 no.5
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• pp.1041-1051
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• 2003

Neutron induced prompt gamma activation analysis (PGAA) offers a nondestructive, sensitive and relatively rapid method for the determination of trace and major elements and is proven to be convenient for online analysis of minerals, metals, coal, cement, petrochemical, coating, paper as well as many other materials and products. The technique has found many uses in medicine, industry, research, security and the detection of contraband items. This report reviews the present status and future trends of the PGAA techniques. Requirements for the system are neutron source, high resolution HPGe detectors with a high-voltage power supply, an amplifier, analog-to-digital converter, and a multichannel analyzer for the detection and measurement of prompt ${\gamma}$-ray emit form the neutron capture elements. Introducing a ${\gamma}$-${\gamma}$ coincidence system also improves the quality of the ${\gamma}$-ray spectrum by suppressing the background created from the Compton scattering of high energy prompt ${\gamma}$-rays. A PGAA system using a $^{252}Cf$ neutron source is currently under construction for the on-line measurement of several elements in aqueous samples at KAERI. The system can be applied for the detection of chemical weapons and explosives as well as various narcotics.

• Journal of Radiation Protection and Research
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• v.42 no.2
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• pp.83-90
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• 2017

Background: Different cases exist in the measurement of thyroid radiobioassays owing to the individual characteristics of the subjects, especially the potential variation in the counting efficiency. An In situ Object Counting System (ISOCS) was developed to perform an efficiency calibration based on the Monte Carlo calculation, as an alternative to conventional calibration methods. The purpose of this study is to evaluate the applicability of ISOCS to thyroid radiobioassays by comparison with a conventional thyroid monitoring system. Materials and Methods: The efficiency calibration of a portable high-purity germanium (HPGe) detector was performed using ISOCS software. In contrast, the conventional efficiency calibration, which needed a radioactive material, was applied to a scintillator-based thyroid monitor. Four radioiodine samples that contained $^{125}I$ and $^{131}I$ in both aqueous solution and gel forms were measured to evaluate radioactivity in the thyroid. ANSI/HPS N13.30 performance criteria, which included the relative bias, relative precision, and root-mean-squared error, were applied to evaluate the performance of the measurement system. Results and Discussion: The portable HPGe detector could measure both radioiodines with ISOCS but the thyroid monitor could not measure $^{125}I$ because of the limited energy resolution of the NaI(Tl) scintillator. The $^{131}I$ results from both detectors agreed to within 5% with the certified results. Moreover, the $^{125}I$ results from the portable HPGe detector agreed to within 10% with the certified results. All measurement results complied with the ANSI/HPS N13.30 performance criteria. Conclusion: The results of the intercomparison program indicated the feasibility of applying ISOCS software to direct thyroid radiobioassays. The portable HPGe detector with ISOCS software can provide the convenience of efficiency calibration and higher energy resolution for identifying photopeaks, compared with a conventional thyroid monitor with a NaI(Tl) scintillator. The application of ISOCS software in a radiation emergency can improve the response in terms of internal contamination monitoring.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.29 no.1B
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• pp.97-103
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• 2009

The decompostion characteristics of NAPL TCE in cement/slag/Fe(II) system were studied with various TCE concentration and amounts of binders (cement/slag) For analyses of the TCE degradation by cement/slag/Fe(II), TCE solution injected using gas-tight syringe after TCE solution dissolved a methanol. Initial concentrations of TCE are 0.42 mM, NAPL condition 11.7 mM and saturated condition 16.8 mM respectively. The result showed that the cases of 8.4 mM and 4.2 mM are decreased 88% of total TCE concentration within 18 days. NAPL condition 11.7 mM was decreased 84% within 50 days and saturated condition 16.8 mM was decreased 60% of total TCE concentration within 60 days respectively. This showed that degradations of TCE in various concentrations were in one kind reaction as pseudo-first-order. TCE was dissolved as aqueous solution before degraded. The reaction rate was increased $0.12day^{-1}$, $0.24day^{-1}$, $0.31day^{-1}$ when the mass of media 0.1, 0.2, 0.3 S/L rate was increased. TCE reaction speed is affected by cement/slag surface ares in this system. When HDTMA, experimental facter, was added, TCE decomposition rate was high despite the high concentration of NAPL. and The decompostion characteristics of NAPL TCE in cement/slag/Fe(II) system were studied by using modeling.