• Analytical Science and Technology
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• v.12 no.5
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• pp.436-440
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• 1999

Antistatic property and crystallization behavior of antistatic poly(ethylene terephthalate) (PET) were studied by feeding antistatic agents into polycondensation reactor. Glass transition and melting temperature of antistatic PET were decreased by poly(ethylene glycol) (PEG) component of antistatic agent. The crystallization rate of antistatic PET was inhibited by decreasing crystallization temperature. Thermal properties and crystallization behavior was affected POAG content of antistatic agent rather than sodium alkylsulfonate of it. The main antistatic component of antistatic agent was POAG. The main role of sodium alkylsulfonate was increasing melt viscosity of antistatic poly(ethylene terephalate) polymer.

• Journal of the Korean Applied Science and Technology
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• v.26 no.1
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• pp.93-101
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• 2009

Antistatic acrylic resin is made from n-butyl methacrylate, methyl methacrylate, dimethyl amino ethyl methacrylate(DMAEMA), 2-ethyl hexyl methacrylate, hydroxy ethyl methacrylate, 2,2'-azobis iso-butyronitrile by synthesis. To achieve a lowest surface resistance of antistatic acrylic resin was applied to a variety of synthesis processes. The acrylic resin has been determined from the value of surface resistance and -then the antistatic acrylic resin including dimethyl amino ethyl methacrylate of the 10%, 20% and 30% is synthesized. Finally, dimethyl sulfate(DMS) on a variety of weight ratios is added to antistatic acrylic resin. When DMAEMA / DMS weight ratio is 1/1, antistatic acrylic resin isn't haze the lower the surface resistance. Compared to the traditional antistatic agent, all aspects of the physical properties is outstanding.

• Macromolecular Research
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• v.15 no.7
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• pp.617-622
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• 2007

A simple and economic antistatic agent, (2-methacryloyloxyethyl)acid phosphate (acryl phosphate), was synthesized via the reaction of 2-hydroxyethyl methacrylate with phosphorus pentoxide. The acryl phosphate antistatic agent, synthesized in this study, was introduced into poly(methyl methacrylate) (PMMA) resin via copolymerization with MMA. This antistatic agent provides the PMMA matrix with excellent antistatic properties, including surface resistance and electric charge. A comparison of the present antistatic agent with other commercial agents demonstrated the excellence of not only its electrical, but also its thermal and mechanical properties.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.4
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• pp.575-581
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• 2020

A colorless antistatic agent was prepared for use in antistatic films for liquid crystal displays (LCDs) requiring low surface resistance and high transmittance. Among various lithium-fluoro compounds and quaternary ammonium salts, antistatic materials were selected based on their electrical conductivity, and antistatic agents were prepared to measure the surface resistance. As a result, the material with high conductivity showed a relatively low surface resistance, i.e., relatively good antistatic performance. Based on the antistatic materials selected, the formulation ratio for producing the best antistatic agent was established through the experimental design method and the effects of each factor were analyzed. The higher the use of lithium- fluoro compounds as antistatic materials, the higher the ratio of oligomer use with multi-functional groups, and the smaller the surface resistance. The quaternary ammonium salts increased the antistatic performance of the lithium-fluoro compounds, but the effects of the amount used were not relatively large. After manufacturing the antistatic PET film, the properties of the antistatic film showed low surface resistance values (<10⁹ Ω/sq.), high permeability (>92%), low haze (<0.5%), and high whiteness (L^⁎>95). In addition, the antistatic film reliability was found to be excellent by showing a stable surface-resistance change rate of less than 10%, even under high temperature and high humidity conditions.

• Textile Coloration and Finishing
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• v.13 no.6
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• pp.413-427
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• 2001

In this studs, we synthesized durable antistatic agents with acrylic monomers for preventing the electrification of static electricity which is one of defects of polyester fabrics. Also we synthesized quaternary ammonium salts which give antistatic property and crosslinking agents which make antistatic agents adhere to fiber. The treatment of synthesized antistatic agents on polyester fabric carried out at the condition of various concentrations, treatment times and temperatures. The antistatic property, handle characteristics and other properties of treated and untreated polyester fabrics were also investigated.

• Textile Coloration and Finishing
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• v.13 no.6
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• pp.55-55
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• 2001

In this study, we synthesized durable antistatic agents with acrylic monomers for preventing the electrification of static electricity which is one of defects of polyester fabrics. Also we synthesized quaternary ammonium salts which give antistatic property and crosslinking agents which make antistatic agents adhere to fiber. The treatment of synthesized antistatic agents on polyester fabric carried out at the condition of various concentrations, treatment times and temperatures. The antistatic property, handle characteristics and other properties of treated and untreated polyester fabrics were also investigated.

• Textile Coloration and Finishing
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• v.35 no.1
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• pp.20-28
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• 2023

In this study, TPU resin for coating was prepared by varying the mixing ratio of antistatic TPU and recycled TPU to manufacture permanent antistatic materials. The coated yarn was prepared by coating on the nylon yarn, and then the thermal, rheological, mechanical properties and antistatic properties were analyzed. In addition, antistatic properties and durability were confirmed after manufacturing UD fabrics using coated yarns. The mixing ratio of antistatic TPU and recycled TPU was most appropriate at 4:6, and the antistatic property had a surface resistance of 2.20 × 10⁹ Ω and a static charge of 398 V. In the coating process, the coating speed was most appropriate at 0.21 m/s, and the surface resistance of the UD fabric manufactured with the coated yarn manufactured under this condition was 6.80 × 10⁹ Ω and the static charge was 484 V. The UD fabric had a surface resistance of 7.21 × 10⁹ Ω and a static charge of 517 V after washing 10 times, and it was confirmed that the permanent antistatic property was excellent.

• Journal of the Korean Society of Safety
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• v.10 no.1
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• pp.20-27
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• 1995

There are many methods to move or reduce the static electricity which often causes disasters in Industry, etc. The methods may Include grounding of a potentially-charged body, use of antistatic materials, humidification of an atmosphere, use of static electricity eliminators. Among those methods, the one utilizing antistatic materials is widely used in the industrial fields due to its effectiveness and inexpectiveness. In Korea, safety regulations and technical standards are not sufficient for applying to industrial fields as electrostatic disaster prevention measures due to the shortage of practically verified and reliable data. The propose of this paper is to examine the electrostatic characteristics of the antistatic materials and non-antistatic ordinary materials under the various conditions of different temperature and humidity.

• Applied Chemistry for Engineering
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• v.10 no.5
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• pp.707-710
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• 1999

Moisture content and intrinsic viscosity of antistatic polyethyleneterephthalate(PET) depending on the thermal stabilizer content was studied. The terminal moisture content of antistatic PET was a function of drying temperature rather than drying time. Intrinsic viscosity drop of antistatic PET after melt spinning increased with increasing moisture content of it. After melt spinning, intrinsic viscosity of antistatic PET was decreased due to the thermal degradation of polyoxyalkyleneglycol(POAG) component of antistatic agent. Triphenylphosphate(TPP) was more effective as a thermal stabilizer than trimethylphosphate(TMP). A little intrinsic viscosity drop after melt spinning was found in PET containing 300 ppm of TPP as a thermal stabilizer.

• Journal of the Korean Society of Safety
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• v.5 no.1
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• pp.57-66
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• 1990

The purpose of this study is to investigate electrostatic charge condition and possibility of electrostatic hazards in case of putting on synthetic smocks and antistatic garments for the purpose of prevention of electrostatic hazards due to a human body electrical charge. It is shown in case of a synthetic smocks, electrostatic voltage by friction is about 2,900 (V), half life period is 12 second, and electrostatic charge is 1.4―1.8 ($\mu$ C). When putting on a synthetic smocks, electrostatic voltage is 2,500―2,800(V). When putting on a jumper of chemical fiber, electrostatic voltage is 8,000(V) . It is, therfore, possible to cause a electrostatic hazards. It is also shown in case of a antistatic garments, electrostatic voltage by friction is 87(V) ―280(V) (washing 90 times), half life period is 3―5 second, and electrostatic charge is 0.24―0.28($\mu$ C) which is much lower than 0.6($\mu$ C) limitation of fire and explosion occurance. When putting on a antistatic garments, electrostatic voltage is 10(V) ―125(V). In conclusion, it is shown when putting on a antistatic garments it is possible to prevent a electrostatic hazards such as fire or explosion due to human body, to prevent a destruction of semiconductor elements and capacity decline, and to prevent a misoperation of automation facilities and semiconductor electric and electronic products.