• Journal of Korean Society for Atmospheric Environment
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• v.10 no.E
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• pp.332-342
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• 1994

Hierarchical cluster and factor analyses were used to identify various influences on free tropospheric air samples at Mauna Loa Observatory in Hawaii during MLOPEX. The cluster analysis separated thirteen chemical and meteorological variables into three characteristic groups (1)clean air, (2)anthropogenically influenced air, (3)marine and volcanic influenced air. The cluster analysis results compared well with those of factor analysis. Six independent components were identified in factor analysis. We have related these components to (1)volcano influenced air, (2)stratosphere-like air, (3)boundary-layer air with recent anthropogenic influence, (4)photochemical haze, (5)marine boundary- layer air, and (6)modified marine tropospheric air. Excluding local influence, we could calculate the nighttime free tropospheric values for $O_3$(41$\pm$10 ppbv), HN $O_3$(94$\pm$45 pptv), N $O_3$$^{[-10]}$ (16$\pm$10 ppbv), S $O_4$$^{[-10]}$ (60$\pm$0 pptv), N $H_4$$^{＋}$(71$\pm$6 pptv), N $a^{＋}$(5$\pm$1 pptv), PAN(13$\pm$9 pptv), MeN $O_3$(3.5$\pm$1.5 pptv), 2-butyl N $O_3$(0.6$\pm$0.1 pptv), $H_2O$$_2$(1015$\pm$44 pptv), $C_2$C $l_4$(3.3$\pm$0.1 pptv), condensation nuclei(249$\pm$13c $m^{-3}$), and dew point(-8.5$\pm$5.3$^{\circ}C$) during this experiment..

• Analytical Science and Technology
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• v.27 no.1
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• pp.1-10
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• 2014

The $PM_{10}$ and $PM_{2.5}$ samples were collected at Gosan Site of Jeju Island, and analyzed, in order to investigate the size distribution and pollution characteristics of their components. $NH{_4}{^+}$, nss-$SO{_4}^{2-}$, $K^+$, and $CH_3COO^-$ were mostly existed in fine particles. Meanwhile, $NO{_3}{^-}$ was distributed in both fine and coarse particles, and $Na^+$, $Cl^-$, $Mg^{2+}$, nss-$Ca^{2+}$ were rich in coarse particle mode. The concentrations of nss-$Ca^{2+}$ and $NO{_3}{^-}$ were increased 36.7 and 3.2 times in coarse particles, and 15.0 and 3.1 times in fine particles during the Asian Dust periods. Especially, the concentrations of crustal elemental species such as Al, Fe, Ca, K, Mg, Ti, Mn, Sr, Ba were highly increased for those periods. In the haze events, the concentrations of secondary air pollutants were increased 1.3~2.6 and 1.5~4.2 times in coarse and fine particles, respectively. Moreover, the remarkable increase of $NO{_3}{^-}$ concentration was also observed in fine particle mode. The factor analysis showed that the composition of coarse particles was influenced mainly by marine sources, followed by soil and anthropogenic sources. On the other hand, the fine particles were influenced by anthropogenic sources, followed by marine and soil sources.

• Journal of the Korean earth science society
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• v.26 no.6
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• pp.573-583
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• 2005

[ $PM_{10}\;and\;PM_{2.5}$ ] aerosols were collected at Busan from March, 2004 to December, 2004, and the concentrations of some metal elements were chemically analyzed to study their characteristics. The mean concentration of $PM_{10}$ was $58.2{\mu}g/m^3$ with a range of 8.3 to $161.1{\mu}g/m^3$. The mean concentration of $PM_{2.5}$ was $29.3{\mu}g/m^3$ with a range of 2.8 to $65.3\mu}g/m^3$. The mean mass concentrations of Asian dust and non Asian dust in $PM_{10}$ were $121.5\mu}g/m^3$ and $56.0{\mu}g/,^3$ respectively. The mean values of crustal enrichment factors for six elements (Cd, Cr, Cu, Ni, Pb and Zn) were all higher than 10, possibly suggesting the influence of anthropogenic sources. The crustal enrichment factors of some heavy metal elements in non-Asian dust (NAD) were higher than those in Asian dust (AD), possibly due to anthropogenic emissions transported from industries around this area by westerly wind. The soil contribution ratios for $PM_{10}$ and $PM_{2.5}$ were $15.2\%$ and $17.5\%$ on the whole. and those of AD/NAD for $PM_{10}$ and $PM_{2.5}$ were 1.9 and 2.1, respectively.

• Analytical Science and Technology
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• v.23 no.4
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• pp.371-382
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• 2010

TSP and PM2.5 atmospheric aerosols have been collected at Gosan site of Jeju Island, and their compositions were analyzed to understand the pollution characteristics. The composition ratios of nss (non-sea salt)-$SO_4^{2-}$ and $NH_4^+$ were higher in Gosan site than those in other Korean background and urban sites. However the composition ratio of $NO_3^-$ was conversely lower in Gosan site. From the study of aerosol components according to particle sizes, the anthropogenic nss-$SO_4^{2-}$, $NO_3^-$ and $NH_4^+$ components were mostly existed in the fine particles. But the nss-$Ca^{2+}$, $Na^+$, $Cl^-$ and $Mg^{2+}$ originated from soil and marine sources were distributed relatively in the coarse particles. In the seasonal comparison, the concentrations of nss-$Ca^{2+}$, Al, Fe, Ca and $NO_3^-$ increased in spring season, and nss-$SO_4^{2-}$ showed higher concentration in summer and spring seasons. Based on the factor analysis, the atmospheric aerosols in Gosan site have been found to be influenced largely by anthropogenic sources, and next by marine and soil sources. The backward trajectory analyses showed that the concentrations of nss-$SO_4^{2-}$, $NO_3^-$, Pb and nss-$Ca^{2+}$ increased when the air mass moved from Chinese continent to Jeju area. On the other hand, their concentrations decreased when the air mass moved in from the North Pacific Ocean.

• Korean Journal of Environmental Agriculture
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• v.30 no.2
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• pp.153-159
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• 2011

BACKGROUND: This experiment was conducted to investigate the distribution and burden characteristics of heavy metal in the rainwater sampled at Taean area, in the middle part of Korea, from April 2002 to October 2003. METHODS AND RESULTS: The relationship between concentration of heavy metal and other chemical properties in the rainwaters was also evaluated. Chemical properties in the rainwater were various differences with raining periods and years. It appeared that a weighted average pH values of rainwater was ranged from 5.0 to 5.1. Heavy metal concentrations in the rainwater were ranked as Pb > Zn > Cu > Ni > As > Cr > Cd. As compared with heavy metal concentrations of rainwater in 2002, Cu, Pb, and Zn were higher than other elements in 2003. There were positive correlation between major ionic components, such as ${NH_4}^+$, $Ca^{2+}$, $Mg^{2+}$, $K^+$, $Na^+$, ${SO_4}^{2-}$ and ${NO_3}^-$, and As, Cd, Zn, Cr, and Ni concentrations in rainwater. For heavy metal distribution of rainwater, the order of average enrichment factor was Cd > Pb > As > Cu > Zn > Ni > Cr, and these were relatively higher than the natural components such as Fe, Mg and Ca. The monthly enrichment factor were relatively high, from August to October at Taean. The monthly amount of heavy metal precipitation was high in the rainy season from July to August because of great influence of rainfall. CONCLUSION(s): The results of this study suggest that the heavy metals(Cd, Pb, As, Cu, and Zn) of rainwater is strongly influenced by anthropogenic sources rather than natural sources.

• Korean Journal of Agricultural and Forest Meteorology
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• v.25 no.1
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• pp.48-59
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• 2023

Ground-level ozone affects human health and plant growth. Ozone is produced by chemical reactions between oxides of nitrogen (NOx) and volatile organic compounds (VOCs) from anthropogenic and biogenic sources. In this study, two different land cover and emission factor datasets were input to the MEGAN v2.1 emission model to examine how these parameters contribute to the biogenic emissions and ozone production. Four input sensitivity scenarios (A, B, C and D) were generated from land cover and vegetation emission factors combination. The effects of BVOCs emissions by scenario were also investigated. From air quality modeling result using CAMx, maximum 1 hour ozone concentrations were estimated 62 ppb, 60 ppb, 68 ppb, 65 ppb, 55 ppb for scenarios A, B, C, D and E, respectively. For maximum 8 hour ozone concentration, 57 ppb, 56 ppb, 63 ppb, 60 ppb, and 53 ppb were estimated by scenario. The minimum difference by land cover was up to 25 ppb and by emission factor that was up to 35 ppb. From the modeling performance evaluation using ground ozone measurement over the six regions (East Seoul, West Seoul, Incheon, Namyangju, Wonju, and Daegu), the model performed well in terms of the correlation coefficient (0.6 to 0.82). For the 4 urban regions (East Seoul, West Seoul, Incheon, and Namyangju), ozone simulations were not quite sensitive to the change of BVOC emissions. For rural regions (Wonju and Daegu) , however, BVOC emission affected ozone concentration much more than previously mentioned regions, especially in case of scenario C. This implies the importance of biogenic emissions on ozone production over the sub-urban to rural regions.

• Journal of Environmental Science International
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• v.16 no.2
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• pp.179-185
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• 2007

Nitrous oxide ($N_2O$) is an important trace gas in the atmosphere not only because of its large global warming potential (GWP) but also because of the role in the ozone depletion in the stratosphere. It has been known that soil is the largest natural source of $N_2O$ in global emission. However, anthropogenic sources contributing from industrial section is likely to increase with rising the energy consumption, and transportation as well. In this study, a total of 32 gasoline-powered passenger vehicles (ranging from small to large engine's displacement and also ranging from aged catalyst to new catalyst) were tested on the chassis dynamometer system in order to elucidate the characteristics of $N_2O$ emission from automobiles under different driving modes. Ten different driving modes developed by NIER were adapted for the test. The results show that the $N_2O$ emission decreases logarithmically with increase of vehicle speed over the all test vehicles ($N_2O$) emission = -0.062 Ln (vehicle speed) + $0.289,\;r^2=0.97$). It revealed that the larger engine's displacement, the more $N_2O$ emission were recorded. The correlation between $N_2O$ emission and catalyst aging was examined. It found that the vehicles with aged catalyst (odometer record more than 8,0000km) emit more $N_2O$ than those with new catalyst. Average $N_2O$ emission was $0.086{\pm}0.095\;N_2O-g/km$ (number of samples=210) for the all test vehicles over the test driving modes.

• Korean Journal of Remote Sensing
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• v.36 no.2_1
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• pp.217-229
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• 2020

Recently, weather changes in Korea have intensified due to global warming, and the five major natural disasters that occur mostly include heavy rains, typhoons, storms, heavy snow, and earthquakes. Busan is vulnerable to snow disaster, given that the amount of natural disaster damage in Busan accounts for more than 50% of the total amount in the entire metropolitan cities in Korea, and that the Busan area includes many hilly mountains. In this study, we attempted to identify vulnerable areas for snowfall disasters in Busan areas using the geographic information system (GIS) with the data for both geographical and anthropogenic characteristics. We produced the maps of vulnerable areas for evaluating factors that include altitude, slope, land cover, road networks, and demographics, and overlapped those maps to rank the vulnerability to snowfall disasters as the 5th levels finally. To weight each evaluating factor, we used an entropy method. The riskiest areas are characterized by being located in mountainous areas with roads, including Sansung-ro in Geumjeong-gu, Mandeok tunnel in Buk-gu, Hwangnyeongsan-ro in Suyeong-gu, and others, where road restrictions were actually enforced due to snowfall events in the past. This method is simple and easy to be updated, and thus we think this methodology can be adapted to identify vulnerable areas for other environmental disasters.

• Analytical Science and Technology
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• v.24 no.4
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• pp.310-318
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• 2011

The collection of atmospheric $PM_{10}$ and $PM_{2.5}$ particle samples was made at Gosan site of Jeju Island, which is one of the most representative background sites in Korea. Their chemical compositions have been analyzed to explore the pollution characteristics and emission sources. The mass concentrations of $PM_{10}$ and $PM_{2.5}$ particles were $37.6{\pm}20.1$ and $22.9{\pm}14.3{\mu}g/m^3$, respectively, with the content of $PM_{2.5}$ to $PM_{10}$ as 61%. The $PM_{2.5}/PM_{10}$ ratios of nss-$SO_4^{2-}$, $NO_3^-$, and $NH_4^+$ were 0.94, 0.56, 1.02, respectively, indicating that these components were distributed mostly in the fine fractions. Based on the factor analysis, it was found that the compositions of fine particles were mainly influenced by anthropogenic sources, followed by soil or marine sources. The results of the backward trajectory analysis indicate that the concentrations of nss-$SO_4^{2-}$, $NO_3^-$, $NH_4^+$, nss-$Ca^{2+}$, and Pb were high when the air parcels moved from the China continent, while relatively low with the air parcels coming from North Pacific Ocean and/or East Sea.

• Ocean and Polar Research
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• v.36 no.4
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• pp.407-421
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• 2014

The benthic environmental impact experiment addresses environmental impacts at a specific site related to deep-sea mineral resource development. We have acquired several tens of multi- or box core samples at 31 sites within the Benthic environmental Impact Site (BIS) since 2010, aiming to examine the basic properties of surficial deep-sea sediment as a potential source for deep-water plumes. In this study, we present the geochemical properties such as major elements, rare earth elements (REEs), and heavy metal contents at the BIS. Such proxies vary distinctly according to the Facies association. The lithology of all core sediments in the BIS corresponds to both Association Ib and Association IIIb. The vertical profiles of some major elements ($SiO_2$, $Fe_2O_3$, CaO, $P_2O_5$, MgO, MnO) show noticeable differences between Association Ib and IIIb, while others ($Al_2O_3$, $TiO_2$, $Na_2O$, and $K_2O$) do not vary between Association Ib and IIIb. REEs are also distinctly different for Associations Ib and IIIb; in Association Ib, REY and HREE/LREE are uniform through the sediment section, while they increase downward in Association IIIb like the major elements; below a depth of 8 cm, REY is over 500 ppm. The metal enrichment factor (EF) evaluates the anthropogenic influences of some metals (Cu, Ni, Pb, Zn, and Cd) in marine sediments. In both Associations, the EF for Cu is over 1.5, the EF for Ni and Pb ranges from 0.5 to 1.5, and the EF for Zn and Cd are less than 0.5, indicating Cu is enriched but Zn and Cd are relatively depleted in the BIS. The vertical variations of geochemical properties between Association Ib and IIIb are shown to be clearly different, which seems to be related to the global climate changes such as the shift of Intertropical convergence zone (ITCZ).