• 한국환경과학회지
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• 제11권12호
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• pp.1261-1265
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• 2002

This study was focused on the investigation of the characteristics of organics and nitrogen removal with the recycle ratio in anoxic/oxic(A/O) packed bed process that consisted of the anoxic reactor and the aerobic reactor. As increasing the recycle ratio by 0.5, 1.0, 2.0, the COD removal efficiency increased by 94.0%, 98.5%, 98.8% respectively. The aerobic reactor showed the perfect nitrification efficiency by 98.5%, 99.2%, 98.0% respectively. The T-N removal efficiency with the recycle ratio, increased by 56%, 67%, 70% respectively. As increasing the recycle ratio by 0.5, 1.0, 2.0, T-P removal efficiency decreased by 62.1%, 57.4%, 51.3% respectively. The process by releasing the stored phosphorus in the anoxic reactor and uptaking the excess phosphorus in the aerobic reactor, occurred well comparatively when recycle ratio is 0.5. But this process did not occur when the recycle ratio is 1.0 and 2.0. And optimum pH of nitrification was about 6~7 and alkalinity decreased as nitrification rate increased. As increasing the recycle ratio in the anoxic reactor, DO concentration and ORP increased.

• Environmental Engineering Research
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• 제20권1호
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• pp.65-72
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• 2015

A comparative study on response of a toxic compound thiocyanate ($SCN^-$) was carried out in continuous and fed batch moving bed reactor systems. Both systems had three sequential anaerobic, anoxic and aerobic reactors and operated at same hydraulic retention time. Feed $SCN^-$ was first increased from 600 mg/L to 1,000 mg/L for 3 days (shock 1) and then from 600 to 1,200 mg/L for 3 days (shock 2). In anaerobic continuous reactor, increase of effluent COD (chemical oxygen demand) due to shock load was only 2%, whereas in fed batch reactor it was 14%. In anoxic fed batch reactor recovery was partial in terms of $SCN^-$, phenol, COD and $NO{_3}{^-}$-N and $NO{_2}{^-}$-N removals and in continuous reactor complete recovery was possible. In both systems, inhibition was more significant on aerobic reactors than anaerobic and anoxic reactors. In aerobic reactors ammonia removal efficiency deteriorated and damage was irreversible. Present study showed that fed batch reactors showed higher substrate removal efficiency than continuous reactors during regular operation, but are more susceptible to toxic feed shock load and in nitrifying reactor damage was irreversible.

• 한국환경농학회지
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• 제25권3호
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• pp.202-210
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• 2006

자연정화공법에 의한 농촌 전원 독립가구 하수처리공법 개발을 위하여 호기성조와 혐기성조가 분리된 소형 하수처리 장치에서 혐기성조 위에 호기성조를 포갠 일체형으로 공법을 개선한 소형 하수처리장치를 설계 및 시공하여 하수처리공법별, 하수 부하량 및 하수 주입방법에 따른 수처리 효율을 조사하였다. 소형 하수처리장치의 최적공법은 호기-무산소-혐기조건이었으며, 최적여재는 쇄석이었고, 최적 하수 부하량은 $1,200L/m^3{\cdot}day$이었다. 이러한 조건에서 농촌 전윈 독립가구에서 간헐적으로 배출되는 하수에 대한 대응성을 조사하기 위해 하수 주입방법에 따른 하수처리효율을 조사한 결과 농촌 전원 독립가구 하수처리공법으로 개발된 호기-무산소-혐기조건인 소형 하수처리장치는 실제 농촌 전원독립가구에서 간헐적으로 발생되는 하수에 그대로 적용하더라도 현행 방류수 수질기준인 BOD 20 mg/L, COD 40 mg/L, SS 20 mg/L, T-N 60 mg/L 및 T-P 8 mg/L을 만족할 뿐만 아니라, 방류수 수질기준이 앞으로 BOD 10 mg/L, T-N 20 mg/L 및 T-P 2 mg/L로 강화되더라도 안정적으로 처리될 수 있을 것으로 판단된다. 이상의 결과에서 농촌 전원 독립가구 하수처리공법으로 개발한 호기-무산소-혐기조건인 소형 하수처리장치는 BOD 99%, COD 95%, SS 99%, T-N 83% 및 T-P 96%초 질소 처리효율을 호기성조와 혐기성조가 분리된 소형 하수처리장치에 비해 17%정도 향상시켰으며, 모든 조가 일체형이므로 부지면적을 최소화할 수 있다. 따라서 본 공법은 자연정화공법의 단점을 보완할 수 있으므로 농촌 전원 독립가구에 적합할 것으로 사료된다.

• 한국환경농학회지
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• 제27권1호
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• pp.18-26
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• 2008

본 연구는 농촌전원독립가구 하수처리장에서 오염물질의 존재형태별 처리 경향을 파악하여 하수처리장의 설계 및 시공 시 부지면적 감소와 오염물질의 처리효율 극대화를 위한 기초자료로 활용하기 위하여 농촌전원독립가구 하수처리장에서 하수 중 오염물질의 거동 특성과 오염물질의 존재형태별 분해속도를 각각 조사하였다. 하수 중 오염물질의 존재형태별 거동을 조사한 결과 BOD 및 COD는 대부분 호기성조에서 처리되었으며, 처리된 BOD와 COD는 대부분 insoluble형태이었다. 그러나 무산소조와 혐기성조에서의 BOD와 COD는 존재형태별로 별 차이 없었다. SS는 대부분 호기성조에서 처리되었으며, 처리된 SS는 대부분 volatile 형태이었다. T-N은 BOD, COD 및 SS와 달리 호기성조에서 처리효율이 높지 않았고, 처리된 대부분의T-N은 dissolved 형태이었다. T-P는 모든 조에서 일정하게 처리효율이 증가되었으며, 처리된 T-P는 대부분 dissolved 형태이었다. 현장 하수처리장에서 존재형태별 오염물질의 분해속도를 조사한 결과 BOD, COD 및 SS의 분해속도는 호기성조에서 각각 30.79, 17.15 및 29.96 $day^{-1}$로 무산소조 및 혐기성조에 비해 매우 빨랐으며, 호기성조에서 존재형태별 분해속도는BOD 및 COD의 경우 insoluble 형태가 빨랐으며, SS의 경우 fixed 형태가 빨랐다. T-N 및 T-P의 분해속도는 호기성조에서 각각 4.78 및 13.09 $day^{-1}$로 다른 조에 비해 약간 빨랐으며, 호기성조에서 존재형태별 분해속도는 suspended 형태가 약간 빨랐고, 혐기성조와 무산소조에서는 별 차이 없이 비슷하였다. 이상의 결과는 하수처리장의 설계 및 시공 시 부지면적 감소와 오염물질의 처리효율 극대화를 위한 기초자료로 활용 할 수 있을 것으로 판단된다.

• Environmental Engineering Research
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• 제11권4호
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• pp.173-180
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• 2006

Autotrophic nitrogen removal and its microbial community from a laboratory scale upflow anaerobic sludge bed reactor were characterized with dynamic behavior of nitrogen removal and sequencing result of molecular technique (DNA extraction, PCR and amplification of 16S rDNA), respectively. In the experiment treating inorganic wastewater, the anaerobic granular sludge from a full-scale UASB reactor treating industrial wastewater was inoculated as seed biomass. The operating results revealed that an addition of hydroxylamine would result in lithoautotrophic ammonium oxidation to nitrite/nitrate, and also hydrazine would play an important role for the success of sustainable nitrogen removal process. Total N and ammonium removal of 48% and 92% was observed, corresponding to nitrogen conversion of 0.023 g N/L-d. The reddish brown-colored granular sludge with a diameter of $1{\sim}2\;mm$ was observed at the lower part of sludge bed. The microbial characterization suggests that an anoxic ammonium oxidizer and an anoxic denitrifying autotrophic nitrifier contribute mainly to the nitrogen removal in the reactor. The results revealed the feasibility on development of high performance lithoautotrophic nitrogen removal process with its microbial granulation.

• KSBB Journal
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• 제16권4호
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• pp.337-343
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• 2001

탈질화 유동층 생물막 반응기에 모래와 활성탄 입자를 담체로 사용한 결과 다음과 같은 결론을 얻었다. 1. 정상상태 생물막 두께는 부하율이 증가할수록 증가하였다. 2. 활성탄 담체의. 경우 모래 담에의 경우보다 두꺼운 생물막이 형성되었다. 3. 생물막 건조밀도는 생물막 두께가 증가함에 따라 감소 하였다. 4. 모래담체 유동층 생물막 반응기가 질산성질소 제거효율 및 제거속도 면에서 활성탄담체 유동층 생물막 반응기보다 유리하였다. 5. 모래를 담체로 사용하였을 때 반응기 내 최대 균체량은 37 kg/㎥, 최대 질산성질소 제거속도는 21 kg N/㎥d의 값을 각각 나타내었다.

• 한국물환경학회지
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• 제22권2호
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• pp.222-229
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• 2006

The treatment performance and operational parameters of a tertiary wastewater treatment process a biological filtration system were investigated. The biological filtration system consisted of a nitrification filter (Fiter 1) and a polishing filter with anoxic and aerobic parts (Filter 2). SS, T-C-BOD, and T-N in effluent were kept stable at less than 3, 5 mg/L, and 5 mgN/L, respectively, under a HRT in Filter (filter-bed) of 0.37~2.3 h. T-N at the outlet of Filter 2 were about 1~5 mgN/L under the condition of LV of 50~202 m/d. In Filter 2, denitrification was accomplished under LV of 50~168 m/d in a 1 m filter-bed. However, the denitrification capacity reached the maximum when the linear velocity was increased to 202 m/d. Relationship between increase in microorganism and headloss was clearer in Filter 2. As a result, the denitrification rate increased from 1.0~2.3 kgN/($m^3-filter-bed{\cdot}d$) as the headloss increased. The COD removal rate was 6.0~9.6 kgCOD/($m^3-filter-bed{\cdot}d$) when operated with Filters 1 and 2. These results mean that captured bacteria contributed a part of COD consumption and denitrification. The maximum nitrification and denitrification rate was 0.5 and 4 kgN/($m^3-filter-bed{\cdot}d$) in Filter 1 and 2.The ratio of backwashing water to the treated water was about 5~10 %. In Filter 1, wasted sludge in backwashing was only 0.7~5.3 gSS/($m^3$-treated water). In Filter 2, added methanol was converted into sludge and its value was 8.0~24 gSS/($m^3$-treated water). These results proved that this process is both convenient to install as tertiary treatment and cost effective to build and operate.

• 환경위생공학
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• 제12권3호
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• pp.95-102
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• 1997

The process which can stabilize water quality of treatment and improve nitrogen removal rate under the condition of high organic loading was developed by charging fibrous HBC media to single sludge nitrification-denitrification process. This process was operated easier, minimized the treatment cost, and shortened the retention time. To improve T-N removal rate, a part of nitrifing liquid at aerobic zone was recycled to anoxic zone by approximate internal recycle ratio. The experimental results are as follows ; T-N removal efficiency in the organic volumetric loading 0.14-0.19 kg/COD/m$^{3}$·d was obtained asmaxium of 85% at internal recycle ratio 2.5 and in more ratio than this it was decreased. Organic removal efficiency was about 91% under the overall experimental conditions and not influenced by recycle ratio.

• KSBB Journal
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• 제15권5호
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• pp.514-520
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• 2000

Simultaneous nitrification and denitrification of ammonia and organic compounds-containing wastewater were performed in a fluidized bed biofilm reactor with polysulfone(PS) hollow fiber as a double layer biomass carrier. The PS hollow fiber fragment has both aerobic and anoxic environments for the nitrifiaction and denitrification at the shell and lumen-side respectively. The reactor system showed about 80% nitrification efficiency stably throughout the ammonia load conditions applied in the experiment. Denitrification efficiency depended on organic load and C/N ratio. High free ammonia concentration and low dissolved oxygen resulted in nitrite accumulation which leads to enhance organic carbon efficiency in denitrification when compared to nitrate denitrification. The simultaneous nitrification and denitrification reactor system has an economic advantages in reduced chemical cost of organic carbon for denitrification as well as compact reactor configuration.

• 대한환경공학회지
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• 제27권5호
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• pp.542-548
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• 2005

부착 미생물을 이용한 다공성 담체 유동상 반응기는 하폐수중의 유기물 및 질소제거에 많이 적용되어져 왔다. 특히 생물막이 형성된 담체에서는 호기, 무산소 그리고 혐기영역이 공존하여 동시적 질산화/탈질 반응에 의한 질소제거에 유리한 환경이 제공된다고 알려져 있다. 이러한 반응을 활성화시키기 위해서는 담체표면과 내부에서 산소와 유기물등의 적절한 기질확산이 이루어져야 한다. 그러나 하폐수중의 유기물농도나 생물막의 마찰조건등 운전조건에 따라서는 표면에서의 종속영양균의 과잉성장에 의해 질소 제거 반응이 저해되기도 한다. 다공성 담체 유동상 반응기에 막모듈을 결합시킨 하이브리드 반응기는 단일조내에서 활성화된 동시적 질산화/탈질 반응으로 종래의 유동상 반응기에 비해 30% 이상 질소제거 효율이 증가하였다. 미소전극 연구를 통해 담체내부의 탈질율을 조사할 수 있으며 유동상 반응기에 비하여 하이브리드 반응기내 담체내부에서는 탈질반응에 대한 유기물의 확산에 대한 제한인자가 작으며 따라서 보다 높은 탈질율을 유지할 수 있음을 보였다.