• Journal of the Korean Electrochemical Society
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• v.1 no.1
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• pp.14-17
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• 1998

Mesophase pitch-based carbon fibers(MPCF) have been investigated as an anode active material for lithium ion secondary battery. Graphitized MPCF gives high discharge capacity and good Ah efficiency. MPCF/Li cell shows an initial discharge capacity of 300 mAh/g and Ah efficiency above $90\%$ at a current density of 25 mA/g at $0\~1$ V. Cylindrical lithium ion secondary battery was fabricated using mixed carbon anode and $LiCoO_2$, cathode. In order to improve the cyclability of lithiun ion secondary battery, other carbons were added to the MPCF up to $10wt\%$. The cycle performance of lithium ion secondary battery using mixed carbons was superior to those using graphitized MPCF.

• Journal of the Korean Ceramic Society
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• v.50 no.6
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• pp.480-484
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• 2013

Since SiOC was introduced as an anode material for lithium ion batteries, it has been studied with different chemical compositions and microstructures using various silicon based inorganic polymers. Poly(phenyl carbosilane) is a SiOC precursor with a high carbon supply in the form of the phenyl unit, and it has been investigated for film applications. Unlike any other siloxane-based polymers, oxygen atoms must be utilized in an oxidation process, and the amount of oxygen is controllable. In this study, SiOC anodes were prepared using poly(phenyl carbosilane) with different heat treatment conditions, and their electrochemical properties as an anode material for lithium ion batteries were studied. In detail, cyclic voltammetry and charge-discharge cycling behavior were evaluated using a half-cell. A SiOC anode which was prepared under a heat treatment condition at $1200^{\circ}C$ after an oxidation step showed stable cyclic performance with a reversible capacity of 360 mAh/g.

• Journal of Korean Association for Spatial Structures
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• v.6 no.4 s.22
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• pp.73-80
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• 2006

It is an object of the present paper to investigate a electrochemical properties of Mg-based sacrificial anodes and the effect of calcium added from calcium chloride into magnesium on the melt protection during the melting. Electrochemical data will be correlated with processing control variables, and the microstructural change by the addition of CaCl2. Small addition of calcium into magnesium from CaCl2 imparts beneficial effect in electrochemical properties of Mg alloys, primarily, through microstructural modifications. In addition, the protection effect of the melts surface of Ca with low melting point modification is obtained by adding Ca not more than 0.6%.

• Korean Chemical Engineering Research
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• v.49 no.6
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• pp.846-850
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• 2011

Nanocomposite anodes for rechargeable lithium battery are prepared by mixing tin and nickel nanoparticles via wet method and their electrochemical properties are examined. The Sn-Ni nanocomposite anode shows a maximum discharge capacity of 700 mAh $g^{-1}$ at the first cycle but very poor cycle performance. This means that the electrode porosity and the Ni component formed by the simple mixing of nanoparticles no longer play the role of buffering the volume expansion/contraction of Sn component during charge-discharge. To solve the cycle performance problem, a novel nanostructured Sn-Ni anode should be designed and tested.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.277-277
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• 2010

The capacity of the carbonaceous materials reached ca. $350\;mAhg^{-1}$ which is close to theorestical value of the carbon intercalation composition $LiC_6$, resulting in a relatively low volumetric Li capacity. Notwithstanding the capacities of carbon, it will not adjust well to the need so future devices. Silicon shows the highest gravimetric capacities (up to $4000\;mAhg^{-1}$ for $Li_{21}Si_5$). Although Si is the most promising of the next generation anodes, it undergoes a large volume change during lithium insertion and extraction. It results in pulverization of the Si and loss of electrical contact between the Si and the current collector during the lithiation and delithiation. Thus, its capacity fades rapidly during cycling. We focused on electrode materials in the multiphase form which were composed of two metal compounds to reduce the volume change in material design. A combination of electrochemically amorphous active material in an inert matrix (Si-M) has been investigated for use as negative electrode materials in lithium ion batteries. The matrix composited of Si-M alloys system that; active material (Si)-inactive material (M) with Li; M is a transition metal that does not alloy with Li with Li such as Ti, V or Mo. We fabricated and tested a broad range of Si-M compositions. The electrodes were sputter-deposited on rough Cu foil. Electrochemical, structural, and compositional characterization was performed using various techniques. The structure of Si-M alloys was investigated using X-ray Diffractometer (XRD) and transmission electron microscopy (TEM). Surface morphologies of the electrodes are observed using a field emission scanning electron microscopy (FESEM). The electrochemical properties of the electrodes are studied using the cycling test and electrochemical impedance spectroscopy (EIS). It is found that the capacity is strongly dependent on Si content and cycle retention is also changed according to M contents. It may be beneficial to find materials with high capacity, low irreversible capacity and that do not pulverize, and that combine Si-M to improve capacity retention.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.288-288
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• 2013

Lithium-ion battery (LIB) is one of the most important rechargeable battery and portable energy storage for the electric digital devices. In particular, study about the higher energy capacity and longer cycle life is intensively studied because of applications in mobile electronics and electric vehicles. Generally, the LIB's capacity can be improved by replacing anode materials with high capacitance. The graphite, common anode materials, has a good cyclability but shows limitations of capacity (~374 mAh/g). On the contrary, silicon (Si) and germanium(Ge), which is same group elements, are promising candidate for high-performance LIB electrodes because it has a higher theoretical specific capacity. (Si:4200 mAh/g, Ge:1600 mAh/g) However, it is well known that Si volume change by 400% upon full lithiation (lithium insertion into Si), which result in a mechanical pulverization and poor capacity retention during cycling. Therefore, variety of nanostructure group IV elements, including nanoparticles, nanowires, and hollow nanospheres, can be promising solution about the critical issues associated with the large volume change. However, the fundamental research about correlation between the composition and structure for LIB anode is not studied yet. Herein, we successfully synthesized various structure of nanowire such as Si-Ge, Ge-Carbon and Si-graphene core-shell types and analyzed the properties of LIB. Nanowires (NWs) were grown on stainless steel substrates using Au catalyst via VLS (Vapor Liquid Solid) mechanism. And, core-shell NWs were grown by VS (Vapor-Solid) process on the surface of NWs. In order to characterize it, we used FE-SEM, HR-TEM, and Raman spectroscopy. We measured battery property of various nanostructures for checking the capacity and cyclability by cell-tester.

• Journal of Industrial and Engineering Chemistry
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• v.68
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• pp.161-167
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• 2018

In this study, transition metal coated carbon nanofibers (CNFs) were synthesized and applied as anode materials of Li secondary batteries. CNFs/Ni foam was immersed into 0.01 M transition metal solutions after growing CNFs on Ni foam via chemical vapor deposition (CVD) method. Transition metal coated CNFs/Ni foam was dried in an oven at $80^{\circ}C$. Morphologies, compositions, and crystal quality of CNFs-transition metal composites were characterized by scanning electron microscopy (SEM), Raman spectroscopy (Raman), and X-ray photoelectron spectroscopy (XPS), respectively. Electrochemical characteristics of CNFs-transition metal composites as anodes of Li secondary batteries were investigated using a three-electrode cell. Transition metal/CNFs/Ni foam was directly employed as a working electrode without any binder. Lithium foil was used as both counter and reference electrodes while 1 M $LiClO_4$ was employed as the electrolyte after it was dissolved in a mixture of propylene carbonate:ethylene carbonate (PC:EC) at 1:1 volume ratio. Galvanostatic charge/discharge cycling and cyclic voltammetry measurements were taken at room temperature using a battery tester. In particular, the capacity of the synthesized CNFs-Fe was improved compared to that of CNFs. After 30 cycles, the capacity of CNFs-Fe was increased by 78%. Among four transition metals of Fe, Cu, Co and Ni coated on carbon nanofibers, the retention rate of CNFs-Fe was the highest at 41%. The initial capacity of CNFs-Fe with 670 mAh/g was reduced to 275 mAh/g after 30 cycles.

• Nuclear Engineering and Technology
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• v.51 no.5
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• pp.1417-1427
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• 2019

In this study, we evaluated the performance of a commercial pixelated cadmium zinc telluride (CZT) detector for spectroscopy and identified its feasibility as a Compton camera for radiation monitoring in a nuclear power plant. The detection system consisted of a $20mm{\times}20mm{\times}5mm$ CZT crystal with $8{\times}8$ pixelated anodes and a common cathode, in addition to an application specific integrated circuit. The performance of the various radioisotopes $^{57}Co$, $^{133}Ba$, $^{22}Na$, and $^{137}Cs$ was evaluated. In general, the amplitude of the induced signal in a CZT crystal depends on the interaction position and material non-uniformity. To minimize this dependency, a drift time correction was applied. The depth of each interaction was calculated by the drift time and the positional dependency of the signal amplitude was corrected based on the depth information. After the correction, the Compton regions of each spectrum were reduced, and energy resolutions of 122 keV, 356 keV, 511 keV, and 662 keV peaks were improved from 13.59%, 9.56%, 6.08%, and 5%-4.61%, 2.94%, 2.08%, and 2.2%, respectively. For the Compton imaging, simulations and experiments using one $^{137}Cs$ source with various angular positions and two $^{137}Cs$ sources were performed. Individual and multiple sources of $^{133}Ba$, $^{22}Na$, and $^{137}Cs$ were also measured. The images were successfully reconstructed by weighted list-mode maximum likelihood expectation maximization method. The angular resolutions and intrinsic efficiency of the $^{137}Cs$ experiments were approximately $7^{\circ}-9^{\circ}$ and $5{\times}10^{-4}-7{\times}10^{-4}$, respectively. The distortions of the source distribution were proportional to the offset angle.

• Journal of the Korean Electrochemical Society
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• v.22 no.1
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• pp.22-35
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• 2019

Development of low cost rechargeable batteries has been considered as a significant task for future large-scale energy storage units (i.e. electric vehicles, smart grids). Sodium-ion batteries (SIBs) have been recognized as a promising alternative to replace conventional lithium-ion batteries (LIBs) because of their abundancy and economic benign. Nevertheless, Na ions have larger ionic radius than that of Li ions, resulting in sluggish transport of Na ions in electrodes for cell operation. There have been efforts to seek suitable anode materials for the past years operated based on three different kinds of reaction mechanism (intercalation, alloy reaction, and conversion reaction). In this review, we introduce a class of conversion reaction anode materials for Na-ion batteries, which have been reported.

• Korean Chemical Engineering Research
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• v.57 no.2
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• pp.267-273
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• 2019

Hierarchically porous $Fe_2O_3$ nanofibers with meso- and macro- pores are designed and synthesized by electrospinning and subsequent heat-treatment. The macro pores are generated by selectively decomposition of polystyrene as a dispersed phase in the as-spun fibers containing $Fe(acac)_3$/polyacrylonitrile continuous phases during heat-treatment. Additionally, meso-pores formed by evaporation of infiltrated water vapor during electrospinning process interconnected the macro-pores and results in the formation of hierarchically porous $Fe_2O_3$ nanofibers. The initial discharge capacity and Coulombic efficiency of the hierarchically porous $Fe_2O_3$ nanofibers at a current density of $1.0A\;g^{-1}$ are $1190mA\;h\;g^{-1}$ and 79.2%. Additionally, the discharge capacity of the nanofibers is $792mA\;h\;g^{-1}$ after 1,000 cycles. The high structural stability and morphological benefits of the hierarchically porous $Fe_2O_3$ nanofibers resulted in superior lithium ion storage performance.