• Title/Summary/Keyword: amorphous magnetic materials

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EXCHANGE INTERACTIONS IN SOFT NANOCRYSTALLINE MATERIALS

  • Hernando, A.;Vazquez, M.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.583-588
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    • 1995
  • Fe rich nanocrystals embedded in an amorphous magnetic matrix have been shown to exhibit outstanding soft magnetic properties. The cause of softness in the exchange coupling between the two-phases. In this paper some effects of the exchange coupling between the nanocrystals and the matrix are reviewed.

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Magnetic Bias Effects in Field-annealed CoFeSiB Amorphous Ribbons (공기 중에서 자기장 열처리된 CoFeSiB 비정질 리본에서의 자기 바이어스 효과)

  • Cha, Yong-Jun;Jeong, Jong-Ryul;Kim, Cheol-Gi;Kim, Dong-Young;Yoon, Seok-Soo
    • Journal of the Korean Magnetics Society
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    • v.19 no.6
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    • pp.191-196
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    • 2009
  • Magnetic bias phenomena of field-annealed CoFeSiB amorphous ribbons showing asymmetric giant magnetoimpedance was investigated by MOKE method. The specimens removed the crystalline layer at one surface side by chemical etching were prepared and measured magnetization curves by MOKE to investigate the effect of the crystalline layer on magnetization of inner soft amorphous phase. We observed the shift of hysteresis loop, and concluded that the crystalline layer exerts bias field effect on inner soft amorphous phase and the direction of bias filed is opposite to the magnetization direction of surface crystalline layer.

Annealing Effect of Co/Pd Multilayers on Magnetic Properties During Interdifusion

  • Kim, Jai-Young;Jan E. Evetts
    • Journal of Magnetics
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    • v.2 no.4
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    • pp.147-156
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    • 1997
  • An artificially modulated magnetic Co/Pd multilayer is one of the promising candidates for high density magneto-optic (MO) recording media, due to a large Kerr rotation angle in the wavelength of a blue laser beam. However, since multilayer structure, as well as amorphous structure, is a non-equilibrium state in terms of free energy and a MO recording technology is a kind of thermal recording which is conducted around Curie temperature (Tc) of the recording media, when the Co/Pd mulilayer is used for the MO recording media, changes in the magnetic properties are occurred as the amorphous structure do. Therefore, the assessment of the magnetic properties in the Co/Pd multilayer during interdiffusion is crucially important both for basic research and applications. As the parameter of the magnetic properties in this research, saturation magnetization and perpendicular magnetic anisotropy energy of the Co/Pd multilayer are measured in terms of Ar sputtering pressure and heat treatment temperature. Form the results of the research, we find out that the magnetic exchange energy between Co and Pd sublayers strongly affects the changes in the magnetic properties of the Co/Pd multilayers during the interdiffusion in ferromagnetic state. This discovery will provide the understanding of the magnetic exchange energy in the Co/Pd multilayer structure and suggest the operating temperature range for MO recording in the Co/Pd multilayer for the basic research and applications, respectively.

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Magnetoresistance Characteristics of Magnetic Tunnel Junctions Consisting of Amorphous CoNbZr Alloys for Under and Capping Layers

  • Chun, Byong Sun;Lee, Seong-Rae;Kim, Young Keun
    • Journal of Magnetics
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    • v.9 no.1
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    • pp.13-16
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    • 2004
  • Magnetic tunnel junctions (MTJs) comprising amorphous CoNbZr layers have been investigated. $Co_{85.5}Nb_8Zr_{6.5}$(in at. %) layers were employed to substitute the traditionally used Ta layers with an emphasis given on under-standing underlayer effect. The typical junction structure was $SiO_2/CoNbZr$ or Ta 2/CoFe 8/IrMn 7.5/CoFe 3/Al 1.6 + oxidation/CoFe 3/CoNbZr or Ta 2 (nm). For both as-deposited state and after annealing, the CoNbZr-underlayered structure showed superior surface smoothness up to the tunnel barrier than Ta-underlayerd one (rms roughness of 0.16 vs. 0.34 nm). CoNbZr-based MTJs was proven beneficial for increasing thermal stability and increasing $V_h$ (the bias voltage where MR ratio becomes half) characteristics than Ta-based MTJs. This is because the CoNbZr-based junctions offer smoother interface structure than the Ta-based one.

The Magnetic Properties of Amorphous F$e_32Ni_36Cr_14P_12B_6$ (비정질 F$e_32Ni_36Cr_14P_12B_6$의 자기적 성질)

  • Kim, Jung-Gi
    • Korean Journal of Materials Research
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    • v.2 no.4
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    • pp.293-297
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    • 1992
  • The magnetic properties of the amorphous Fe/sub 32/Ni/sub 36/Cr/sub 14/P/sub 12/B/sub 6/ has been studied by Mossbauer spectroscopy in the temperature range of 88-400K. The analysis of the spectrum of B8K, the magnetic hyperfine field and quadrupole splitting are found to be 140.5kOe and almost zero, which means that the magnetic hyperfine field is randomly oriented with respect to the principal axes of the electric field gradient, respectively. The values of quadrupole splitting in paramagnetic phase with Tc=280K are independent on the changes of temperature. Debye temperature is found to be about 288k from the analysis of recoilless fraction.

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19F NMR investigation on the ratio of amorphous to crystal for the binder PVdF in Li ion battery

  • Im, Jong-san;Park, Junghwan;Kim, Kyoung Soo;Jung, Hyunok
    • Journal of the Korean Magnetic Resonance Society
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    • v.23 no.1
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    • pp.1-5
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    • 2019
  • $^{19}F$ NMR experiments were carried out to observe the change of the characteristics of the PVdF binder which is an auxiliary material of the lithium ion battery. PVdF has various crystalline or amorphous phases by thermal treatment. A mixture of cathode and auxiliary materials including PVdF was coated on aluminum foil as an electron collector and then subjected to thermal treatment at various temperatures. The overlapped $^{19}F$ NMR signals obtained from the various phases were separately convoluted into the respective phases, and it was found that there was a relative ratio change of these phases. In addition, the crystal and amorphous phase of PVdF was changed during the vacuum drying, which is the last step of the actual electrode manufacturing. It was observed that the relative amount of amorphous phase, which may affect the flexibility of the electrode or the wettability of the electrolyte, abruptly changes after a certain temperature.

Characteristics of Shield Materials for Wireless Power Transfer

  • Chu, In Chang;Jeong, Jinseong
    • Journal of Magnetics
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    • v.19 no.3
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    • pp.291-294
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    • 2014
  • In this paper, we examine the electrical and magnetic properties of three different types of shield materials used for wireless power transfer systems: namely, FeSiAl-composite, NiZn-ferrite, and FeSi-amorphous types. The power transfer efficiency and resistance of an RX coil are measured, while varying the shield thickness. For all three types, a thicker shield provides better power transfer efficiency. Analysis of the measurements shows that the FeSiAl-composite type is suitable for systems with size limitation. In terms of magnetic properties, the FeSi-amorphous type shows the best features, and is suited to high power applications. This work can be used as a guideline to select suitable shielding material in various wireless power transfer systems.

The Effects of Co Addition on Glass Forming Ability and Magnetic Properties for FeSiBNb Ribbon Alloys (FeSiBNb 리본 합금의 비정질 형성능과 자기적 특성에 미치는 Co의 첨가 효과)

  • Lee, Tae-Gyu;Noh, Tae-Hwan
    • Journal of the Korean Magnetics Society
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    • v.17 no.3
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    • pp.128-132
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    • 2007
  • The thermal and magnetic properties of amorphous (FeCo)SiBNb ribbon alloys with high glass forming ability have been investigated. The glass forming ability was enhanced by Co substitution in amorphous ($Fe_{1-X}Co_X)_{72}Si_4B_{20}Nb_4$ alloys with the thickness of about $40{\mu}m$. With the increase in Co content, the temperature range of supercooled liquid phase increased indicating the high glass forming ability of the Co-added alloys. Further the ac permeability increased, and the core loss decreased considerably by Co substitution, while small change in $B_8$ (magnetic flux density at 800 A/m) was observed. The frequency characteristics of permeability deteriorated as compared to conventional amorphous ribbon alloys with the thickness of about $20\;{\mu}m$ due to the increased skin effect.

The Magnetic Properties of $Fe_{87}Zr_{7}B_{5}Ag_{1}$(at.%) Amorphous Alloy ($Fe_{87}Zr_{7}B_{5}Ag_{1}$ 비정질합금의 연자기 특성)

  • 김병걸;송재성;김현식;오영우
    • Journal of the Korean Magnetics Society
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    • v.5 no.1
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    • pp.8-14
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    • 1995
  • The magnetic properties of an $Fe_{87}Zr_{7}B_{5}Ag_{1}$(at.%) amorphous alloy have been investigated as a function of annealing temperatures to clarify its application potential as a core material for high-frequency use by adding a small amount of insoluble element of Ag. A new excellent soft magnetic material was developed. The amorphous alloy produced by relatively low temperature annealing at $T_{a}=400^{\circ}C$ exhibited very high initial permeability$(\mu_{i})$ of 288,000 at 1kHz and 2mOe, very low coercivity$(H_{c})$ of 15mOe and low core loss$(W_{c})$ of 50W/kg at 100kHz and 1,000G which is comparable with Co-based amorphous alloys, respectively. It is notable that the values obtained in the present study are the best magnetic properties among various kinds of Fe-based soft amorphous materials reported up to date. The reasons for the achievement of good soft magnetic properties are presumably due to the homogeneous formation of very fine $\alpha$-Fe clusters with the size of 2~3nm in an amorphous matrix, which can be deduced from the increase of resistivity and the TEM observation. The very fine $\alpha$-Fe clusters embedded in an amorphous matrix had a great influence on reduction of magnetostriction and refinement of magnetic domain.

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Magnetic Microstructures and Corrosion Behaviors of Nd-Fe-B-Ti-C Alloy by Ga Doping

  • Wu, Qiong;Zhang, Pengyue;Ge, Hongliang;Yan, Aru;Li, Dongyun
    • Journal of Magnetics
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    • v.18 no.3
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    • pp.240-244
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    • 2013
  • The influences of Gallium doping on the magnetic microstructures and corrosion behaviors of Nd-Fe-B-Ti-C alloys are investigated. The cooling rate for obtaining fully amorphous structure is raised, and the glassforming ability is improved by the Ga addition. The High Resolution Transmission Electron Microscopy image shows that the ${\alpha}$-Fe and $Fe_3B$ soft magnetic phases become granular surrounded by the $Nd_2Fe_{14}B$ hard magnetic phase. The rms and $({\Delta}{\varphi})_{rms}$ value of Nd-Fe-B-Ti-C nanocomposite alloy thick ribbons in the typical topographic and magnetic force images detected by Magnetic Force Microscopy(MFM) decreases with 0.5 at% Ga addition. The corrosion resistances of $Nd_9Fe_{73}B_{12.6}C_{1.4}Ti_{4-x}Ga_x$ (x = 0, 0.5, 1) alloys are enhanced by the Ga addition. It can be attributed to the formation of more amorphous phases in the Ga doped samples.