• 제목/요약/키워드: ammonium hydroxide

검색결과 168건 처리시간 0.023초

분광광도법에 의한 혈중일산화탄소의 측정에 관한 연구 (A Study on the Determination of Carbon monoxide in the Blood by Spectrophotometry)

  • 정근호
    • 한국환경보건학회지
    • /
    • 제2권1호
    • /
    • pp.49-51
    • /
    • 1975
  • The accidents, homicides and suicides of carbon monoxide poisoning to increase in number every year are required precize, accurate, and rapid method for the determination of carbon monoxide in the blood samples. Here is the basis of this method for the determination of percentage saturation of hemoglobin by carbon monoxide which have found out to be suitable in laboratory as follows: A 0.1ml of blood is mixed with 20ml of 0.1% ammonium hydroxide, and 20mg sodium hydrosulfite is added to convert oxyhemoglobin to reduction hemoglobin. The absorbance is measured at 538nm and 578nm, the measurement was carried out within ten minutes of addition of sodium hydrosulfate.

  • PDF

구리 CMP 후 연마입자 제거에 화학 기계적 세정의 효과 (Effect of Chemical Mechanical Cleaning(CMC) on Particle Removal in Post-Cu CMP Cleaning)

  • 김영민;조한철;정해도
    • 대한기계학회논문집A
    • /
    • 제33권10호
    • /
    • pp.1023-1028
    • /
    • 2009
  • Cleaning is required following CMP (chemical mechanical planarization) to remove particles. The minimization of particle residue is required with each successive technology generation, and the cleaning of wafers becomes more complicated. In copper damascene process for interconnection structure, it utilizes 2-step CMP consists of Cu and barrier CMP. Such a 2-steps CMP process leaves a lot of abrasive particles on the wafer surface, cleaning is required to remove abrasive particles. In this study, the chemical mechanical cleaning(CMC) is performed various conditions as a cleaning process. The CMC process combined mechanical cleaning by friction between a wafer and a pad and chemical cleaning by CMC solution consists of tetramethyl ammonium hydroxide (TMAH) / benzotriazole (BTA). This paper studies the removal of abrasive on the Cu wafer and the cleaning efficiency of CMC process.

카티온화제 처리에 의한 면직물의 염색성 개선 (The Improvement of Dyeing Property of Cotton Fabric by Cationic Agent Treatment)

  • Sung, Woo Kyung;Park, Sang Joo;Lee, Won Chul
    • 한국염색가공학회지
    • /
    • 제9권1호
    • /
    • pp.33-43
    • /
    • 1997
  • This study was carried out to investigate increasing the neutral substantivity of anionic dyes for cationic-modified cotton fabric treatied with cationic agent. In the present study 3-chloro-2-hydroxypropyltrimethyl ammonium chloride for reactive cationic agent was produced by reaction of epichlorohydrine with trimethylamine hydrochloride. 3-chloro-2-hydroxypropyltrimethylammonium chloride was converted in an aqueous solution of sodium hydroxide into glycidyltrimethylammonium chloride. By treating with this epoxy reagent the hydroxyl groups of cotton fabric was modified to trimethylammonium group through ether linkage. The introduction of new cationic sites into cotton fabric by pretreating with cationic agent improves the substantivity of anionic dyes with the cotton in dyebath. Dyeablity of the modified cotton fabric for direct and reactive dyes was much improved in a non-electrolytic or a little electrolytic dyebath and was proportional to the concentration of cationic agent.

  • PDF

산/알칼리 촉매에 의한 팔미트산 함유 유채유의 Biodiesel화 (Conversion of Rapeseed Oil Containing Palmitic Acid into Biodiesel by Acid/Alkali Catalysts)

  • 현영진;김해성
    • 한국응용과학기술학회지
    • /
    • 제23권4호
    • /
    • pp.300-306
    • /
    • 2006
  • The esterification of palmitic acid in rapeseed oil and methanol emulsified by propylene glycol with PTSA(p-toluene sulfonic acid) was followed by the transesterification of rapeseed oil into biodiesel with 1(w/v)% GMS(glycerol monostearate) as an emulsifier using TMAH(tetramethyl ammonium hydroxide) catalysts at $60^{\circ}C$. The former reaction was optimized at the 1:20 of molar ratio of oil to methanol and 5wt% PTSA, and the latter was optimized at the 1:8 of molar ratio of oil to methanol and 0.8wt% TMAH. The overall conversion into biodiesel was 98% after 60min of reaction time at the 1:8 of molar ratio, 0.8wt% TMAH and $60^{\circ}C$. TMAH was a good catalyst to control the viscosity of biodiesel mixture.

$CaCo_3-CO_2-NH_3$계에서의 배연탈황 특성 (Characteristics of the Flue Gas Desulfurization in $CaCo_3-CO_2-NH_3$ System)

  • 모세영;이경재;장홍기;손종렬
    • 환경위생공학
    • /
    • 제14권2호
    • /
    • pp.84-89
    • /
    • 1999
  • This experiment was performed to develop the new desulfurization process which can eliminate the possibility of generation of the secondary pollutants by regenerating the limestone from the sulfite/sulfate slurry generated from the wet lime/limestone flue gas desulfurization process by treating it with the ammonium hydroxide and carbon dioxide and using it again. In the experiments, regent grade calcium carbonate was dissolved to obtain the 200ml of sample slurry of the concentration of 2.0~0.4 weight percent. After three times of regeneration and desulfurization process, the coefficients of regeneration and desulfurization efficiencies are calculated/measured. The obtained results are that the coefficients of generation of the first. second, and third regenerated calcium carbonate were 90.88, 92.13, and 91.50%, respectively; and the desulfurization efficiencies of those are 93.4, 94.2 and 93.0%, respectively.

  • PDF

CMOS공정 기반의 저전력 NO 마이크로가스센서의 제작 (Fabrication of low power NO micro gas senor by using CMOS compatible process)

  • 신한재;송갑득;이홍진;홍영호;이덕동
    • 센서학회지
    • /
    • 제17권1호
    • /
    • pp.35-40
    • /
    • 2008
  • Low power bridge type micro gas sensors were fabricated by micro machining technology with TMAH (Tetra Methyl Ammonium Hydroxide) solution. The sensing devices with different heater materials such as metal and poly-silicon were obtained using CMOS (Complementary Metal Oxide Semiconductor) compatible process. The tellurium films as a sensing layer were deposited on the micro machined substrate using shadow silicon mask. The low power micro gas sensors showed high sensitivity to NO with high speed. The pure tellurium film used micro gas sensor showed good sensitivity than transition metal (Pt, Ti) used tellurium film.

구리 CMP 후 연마입자 제거에 버프 세정의 효과 (Effect of buffing on particle removal in post-Cu CMP cleaning)

  • 김영민;조한철;정해도
    • 대한기계학회:학술대회논문집
    • /
    • 대한기계학회 2008년도 추계학술대회A
    • /
    • pp.1880-1884
    • /
    • 2008
  • Cleaning is required following CMP (chemical mechanical planarization) to remove particles. The minimization of particle residue is required with each successive technology generation, and the cleaning of wafers becomes more complicated. In copper damascene process for interconnection structure, it utilizes 2-steop CMP consists of Cu CMP and barrier CMP. Such a 2-steps CMP process leaves a lot of abrasive particles on the wafer surface, cleaning is required to remove abrasive particles. In this study, the buffing is performed various conditions as a cleaning process. The buffing process combined mechanical cleaning by friction between a wafer and a buffing pad and chemical cleaning by buffing solution consists of tetramethyl ammonium hydroxide (TMAH)/benzotriazole(BTA).

  • PDF

알루미나수화물(水和物)의 침전(沈澱)pH가 물성(物性)에 미치는 영향(影響) (Effect of pH of Precipitation on Physical and Chemical Properties of Hydrous Aluninum Oxide)

  • 이계주
    • Journal of Pharmaceutical Investigation
    • /
    • 제6권2호
    • /
    • pp.95-100
    • /
    • 1976
  • A study on the effect of the pH of precipitation on the acid consuming capacity, aging stability, physical and chemical properties of hydrous aluminum oxide prepared by the reaction of aluminum chloride and ammonium hydroxide solution was carried out by means of X-ray diffraction, IR spectra and differential thermal analysis. The results from these experiments are as follows: 1. Hydrous aluminum oxide precipitated at lower pH showed better acid consuming capacity, higher stability and more anion contained in the structure than that prepared at higher pH. 2. The hydrous aluminum oxide prepared at lower pH is amorphous and that prepared at higher pH is crystalline hydrated hydrous aluminum oxide, i.e., Bayerite and these results are conformed to Rhee's hypothesis. 3. The rate of loss of reactivity and the end-point reactivity are related to the pH of precipitation.

  • PDF

수용성 TMAH/IPA 용액의 실리콘 이방성 식각 (Anisotropic Etching of Silicon in Aqueous TMAH/IPA Solutions)

  • 박진성;송승환;정귀상
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
    • /
    • pp.334-337
    • /
    • 1996
  • Si anisotropic etching is a key technology for micromachining. The main advantages of tetramethyl ammonium hydroxide (TMAH)-based solution are their full compatibility with IC process. In this work the anisotropic etching of single crystal Si in a TMAH (($CH_3$)$_4$NOH) based solution was studied. The influence of the addition of IPA to TMAH solution on their etching characteristics was also presented. The crystal planes bounding the etch front and their etch rates were determined as a function of temperature, crystal orientation, and etchant concentration. The etch rates of (100) oriented Si crystal planes decreased linearly with increasing the IPA concentration, The etched (100) planes were covered by Pyramidal-shaped hillocks below 15 wt.%, but very smooth surfaces were obtained above 20 wt.%. The addition of IPA to TMAH solution leads to smoother surfaces of sidewalls etched planes.

  • PDF

알킬디메틸벤질암모늄 클로라이드에 의한 PET섬유의 감량가공에 관한 연구 (Studies on the Treatment of Weight Loss of PET Fibers by Alkyldimethylbenzylammonium Chlorides)

  • 박홍수
    • 한국응용과학기술학회지
    • /
    • 제10권2호
    • /
    • pp.29-33
    • /
    • 1993
  • n-Octyldimethylbenzylammonium chloride, dodecyldimethylbenzylammonium chloride, and octadecyldimethylbenzylammonium chloride were synthesized to be used as the accelerating weight loss agent. These synthesized compounds were used for the weight loss treatment of PET textile with sodium hydroxide. From the treatments, it was found that the lower carbon number of high alkyl group existed in quaternary ammonium salts, the better effect of weight loss was acquired. The proper concentration of accelerating weight loss agent was $8{\sim}10g/l$, the proper treatment time was $60{\sim}90$ minutes, the proper treating bath ratio was 1 : 50. It is proved that n-octyldimethylbenzylammonium chloride and dodecyldimethylbenzylammonium chloride are good accelerating weight loss agent.