• Title/Summary/Keyword: ammonia electrode

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Factors Afecting Hydrogen Evolution in Chlorobium limicola f. theosulfatophilum NCIB 8327 (Chlorobium limicola f. thiosulfatophilum NCIB 8327에서 수소발생에 영향을 끼치는 요인분석)

  • 나종욱;강사욱
    • Korean Journal of Microbiology
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    • v.30 no.6
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    • pp.553-557
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    • 1992
  • Hydrogen produced by cells of grown Chlorobium limicola f. thiosulfatophilum NCIB 8327 on modified Pfennig's medium containing glutamate as a major nitrogen source, was measured by amperometric method. In this system, oxygen, light. ammonia, methionine sulfoximine, NADPH, ATP, methyl viologen and benzyl viologen are affected. The production of hydrogen in intact cells depends on light intensity. It is also inhibited by adding ammonium ions, but restores immediately by adding methionine sulfoximine. Considering these results, the production of hydrogen in this strain can be mediated by nitrogenase.

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Automatic Analysis of Volatile Basic Nitrogen of Pork with an On-line Flow Injection Analysis System (온-라인 FIA시스템에 의한 돈육의 휘발성염기질소의 자동분석 -연구노트-)

  • 이형춘
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.29 no.5
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    • pp.965-967
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    • 2000
  • An on-line FIA system in place of traditional Conway method was used for quicker and simpler analysis of volatile basic nitrogen of pork. The on-line system was developed by connecting an FIA apparatus with an ammonia electrode as a detector to a personal computer. The data from Conway method and from the on-line FIA system were in good agreement and the correlation coefficient was 0.981. One sample could be analyzed in about 4 min.

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Performance Analysis of Ammonia-Fed Solid Oxide Fuel Cell Using Alternating Flow (교류 흐름 방식을 적용한 암모니아 공급 고체산화물 연료전지의 성능 분석)

  • QUACH, THAI-QUYEN;GIAP, VAN-TIEN;LEE, DONG KEUN;LEE, SUNYOUP;BAE, YONGGYUN;AHN, KOOK YOUNG;KIM, YOUNG SANG
    • Journal of Hydrogen and New Energy
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    • v.33 no.5
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    • pp.557-565
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    • 2022
  • The effect of flow configuration in ammonia-fed solid oxide fuel cell are investigated by using a three-dimensional numerical model. Typical flow configurations including co-flow and counter-flow are considered. The ammonia is directly fed into the stack without any external reforming process, resulting in an internal decomposition of NH3 in the anode electrode of the stack. The result showed that temperature profile in the case of counter-flow is more uniform than the co-flow configuration. The counter-flow cell, the temperature is highest at the middle of the channel while in the case of co-flow, the temperature is continuously increased and reached maximum value at the outlet area. This leads to a higher averaged current density in counter-flow compared to that of co-flow, about 5%.

Determination of L-Asparagine Using Proteus mirabilis Bacterial Electrode (Proteus mirabilis 박테리아 전극을 이용한 L-Asparagine의 정량)

  • Ihn Gwon-Shik;Moo-Jeong Sohn
    • Journal of the Korean Chemical Society
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    • v.32 no.5
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    • pp.422-427
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    • 1988
  • The bio-electrode for L-asparagine, excellent in the reproducibility of responsibility, has been constructed by immobilizing the bacterium Proteus mirabilis on an ammonia gas sensor. This electrode was investigated for the effects of pH, temperature, buffer solution, bacterial amounts and interferences, and stability with the lapse of time. The response of the bacterial electrode was linear in the range of $9.0{\times}10^{-5}$$1.0{\times}10^{-2}M$ L-asparagine with a slope of 58.9mV/decade in pH 7.8, 0.05M phosphate buffer solution at $30^{\circ}C$. The bacterial amounts used for this electrode was 3 mg and response time was 7∼9 min. Therefore, this assembly can be used for the determination of L-asparagine.

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Development of Carbon Felt Electrode Using Urea for Vanadium Redox Flow Batteries (Urea를 이용한 바나듐 레독스 흐름 전지용 카본 펠트 전극 개발)

  • Kim, So Yeon;Kim, Hansung
    • Korean Chemical Engineering Research
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    • v.57 no.3
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    • pp.408-412
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    • 2019
  • In this study, nitrogen doped carbon felt was prepared by pyrolysis of urea at high temperature and applied as an electrode for vanadium redox flow cell. Urea is easier to handle than ammonia and forms $NH_2$ radicals at higher temperatures, creating a nitrogen functional group on the carbon surface and acting as an active site in the vanadium redox reaction. Therefore, the discharge capacity of activated carbon felt electrodes using urea was 14.9 Ah/L at a current density of $150mA/cm^2$, which is 23% and 187% higher than OGF and GF, respectively. These results show the possibility that activated carbon felt electrode using urea can be used as electrode material for redox flow battery.

Gas and particle removal characteristics of a novel electrostatic precipitation type air cleaner using an activated carbon filter as an electrode (활성탄 섬유 필터를 전극으로 활용한 정전 방식의 공기정화장치의 가스 및 입자 제거 특성 분석)

  • Lim, Gi-Taek;Kim, Yong-Jin;Han, Bangwoo;Woo, Chang Gyu;Shin, Weon Gyu;Kim, Hak-Joon
    • Particle and aerosol research
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    • v.14 no.1
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    • pp.9-16
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    • 2018
  • We have developed an electrostatic precipitation (ESP) type air cleaner for indoor air quality and investigated its performances regarding CADR (Clean air delivery rate), single-pass efficiency and gas removal efficiency. The ESP air cleaner used an ACF (Activated carbon fiber) filter for gas removal and the ACF as a high voltage electrode for particle removal. The ESP air cleaner was tested in a chamber with the volume of $1m^3$ regarding CADR and gas removal efficiency. The applied CADR area of the ESP was $1.8m^2$. Gas removal efficiency was tested with 3 gases (Acetaldehyde, Acetic acid, Ammonia). As the results of the gas removal efficiency, the ESP air cleaner shows the removal efficiencies of 90, 98 and 85% for acetaldehyde, acetic acid and ammonia, respectively.

The removal characteristics of No, SOx for plasma reactor separated flue gas duct from discharge domain (연소가스관로와 방전영역 분리형 플라즈마 반응기에서 Nox, SOx 제거특성)

  • Park, J.Y.;Koh, Y.S.;Lee, J.D.;Song, W.S.;Park, S.H.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1999.07e
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    • pp.2007-2009
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    • 1999
  • In this paper, discharge domain of wire-cylindrical plasma reactor was separated from a gas flow duct to avoid unstable discharge by aerosol particle deposited on discharge electrode and grounded electrode. The NOx, SOx removal was experimentally investigated by a reaction induced to ammonium nitrate, ammonium sulfate using a low price of aqueous NaOH solution and a small quantity of ammonia. Volume percentage of aqueous NaOH solution used was 20% and $N_2$ flow rate was 2.5[$\ell$/min] for bubbling aqueous NaOH solution. Ammonia gas(14.82%) balanced by argon was diluted by air and was introduced to a main simulated flue gas duct through $NH_3$ injection system which was in downstream of reactor. The $NH_3$ molecular ratio[MR] was determined based on $NH_3$ to [NO+$SO_2$]. MR is 1.5. The NOx removal rates increased in the order of DC, AC and pulse, but SOx removal rates was not significantly effected by source of electricity. The NOx removal rate slightly decreased with increasing initial concentration but SOx removal rate was not significantly effect by initial concentration, and NOx, SOx removal rates decreased with increasing gas flow rate.

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Evaluation about a Usefulness of ECG-Gated Scan on 13N-ammonia PET (13N-ammonia 심장 PET 검사에서 ECG gated scan의 유용성 평가)

  • Kim, Jae-Il;Lee, Hong-Jae;Kim, Jin-Eui
    • The Korean Journal of Nuclear Medicine Technology
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    • v.20 no.1
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    • pp.20-23
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    • 2016
  • Purpose Because of heart movement, PET image of heart is very blur. So, PET scan gated with ECG is necessary to improve a spatial resolution of heart PET image. In this study, we will evaluate a image quality of both gated $^{13}N-ammonia$ PET scan and non-gated one. Materials and Methods Before start a heart PET, we attached a ECG electrode on patients (n = 5, $aged=54{\pm}17$). And we started a list mode PET scan that used by a mCT40 PET/CT (siemens, germany) during 10 minute, injected $^{13}N-ammonia$ ($378{\pm}50MBq$) to a patients at same time. By using this list mode data, we reconstructed both gated PET image and non-gated PET image. Then we analysed a profiles of those images, performed a blind test, and subtracted a gated image on non-gated image. Results FWHM of a gated image is improved about 23% and there is a differency count distribution at a subtracted image from non-gated image to a gated image. But in case of blind test, everybody select the gated image as a better quality among each images. Conclusion As a result, we can find that image quality will improve by using gated PET scan. In additional, we can calculate a EF valve, apply QGS, QPS of PET. Therefore, the gated PET scan help improving an accuracy, applying a more information for a diagnosis.

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Electrochemical Synthesis of Ammonia from Water and Nitrogen using a Pt/GDC/Pt Cell (Pt/GDC/Pt 셀을 이용한 물과 질소로부터 전기화학적 암모니아 합성)

  • Jeoung, Hana;Kim, Jong Nam;Yoo, Chung-Yul;Joo, Jong Hoon;Yu, Ji Haeng;Song, Ki Chang;Sharma, Monika;Yoon, Hyung Chul
    • Korean Chemical Engineering Research
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    • v.52 no.1
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    • pp.58-62
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    • 2014
  • Electrochemical ammonia synthesis from water and nitrogen using a Pt/GDC/Pt cell was experimentally investigated. Electrochemical analysis and ammonia synthesis in the moisture-saturated nitrogen environment were performed under the operating temperature range $400{\sim}600^{\circ}C$ and the applied potential range OCV (Open Circuit Voltage)-1.2V. Even though the ammonia synthesis rate was augmented with the increase in the operating temperature (i.e. increase in the applied current) under the constant potential, the faradaic efficiency was decreased because of the limitation of dissociative chemisorption of nitrogen on the Pt electrode. The maximum synthesis rate of ammonia was $3.67{\times}10^{-11}mols^{-1}cm^{-2}$ with 0.1% faradaic efficiency at $600^{\circ}C$.

Impurities in the methanol fuel on the performance of direct methanol fuel cell (직접메탄올 연료전지의 성능에 미치는 메탄올 연료의 불순물)

  • Peck, Dong-Hyun;Lee, Jae-Hyuk;Park, Young-Chul;Lim, Seongyop;Kim, Sang-Kyung;Jung, Doo-Hwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.124.1-124.1
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    • 2010
  • The impurities in the methanol fuel that is used for direct methanol fuel cell (DMFC) could greatly affect the performance of membrane electrode assemblies (MEA). The most common impurities in the commercial methanol fuel are mainly ethanol, acetone, acetaldehyde, or ammonia. In this study, the effect of impurities in methanol fuel was investigated on the performance of MEA. The MEA for DMFC were prepared using a semi-automatic bar-coating machine, which can prepare the catalyst layer with uniform thickness for MEA. As a result, a single cell supplied with one of the 6 different kinds of methanol fuels showed a significant degradation of the fuel cell performance. The most common impurities in the commercial methanol fuel is mainly ethanol, acetone, acetaldehyde, or ammonia. The effects of the kind and the concentration of impurities in the methanol fuels were investigated on the performance of MEA for DMFC. We will propose the optimum compositions and limit concentration of impurities in methanol fuel for high performance of MEA for DMFC.

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