• 제목/요약/키워드: aluminum polymer

검색결과 201건 처리시간 0.024초

고분자/저분자 발광재료의 혼합비에 따른 유기 전계발광 소자의 에너지 전달 및 발광특성 (Energy Transfer and Emission Properties of Organic Electroluminescent Device According to Polymer/Dye Mixing Ratio)

  • 김주승;서부완;구할본;이경섭;박복기
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 추계학술대회 논문집 학회본부 C
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    • pp.997-999
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    • 1999
  • We fabricated white light-emitting organic electroluminescent device which have a mixed single emitting layer containing poly(N-vinylcarbazole)[PVK], tris(8-hydroxyquinoline)aluminum[Alq3] and poly(3-hexylthiophene)[P3HT] and investigated the emission properties of it. We expect to obtain a blue light from PVK, green light from Alq3 and red light from P3HT The fabricated device emits white light over 18V with slight orange light. We think that the energy transfer in a mixed layer occurred from PVK to $Alq_3$ and P3HT resulted in decreasing the blue light intensity from PVK. With mixing of N, N'-diphenyl-N, N'-(3-methylphenyl)-[1,1'-biphenyl]-4, 4'-diamine[TPD], hole transport material, to the emitting layer, the luminance intensity of device was increased 50 times than that of the device which not contain TPD. We find that the efficiency of the white light electroluminescent device can be improved by injecting electron more effectively and blue light need to improve the color purity of white light.

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마찰교반용접한 5456-H116 알루미늄 합금 용접부 표면의 기계적 및 전기화학적 특성 (Mechanical and Electrochemical Characteristics of Welding Parts Surface for Friction Stir Welded 5456-H116 Al Alloy)

  • 장석기;김성종
    • 한국표면공학회지
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    • 제41권4호
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    • pp.156-162
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    • 2008
  • Small FRP(fiber-reinforced polymer) fishing ships have numerous problems with the point of the environmental and recycling perspectives. In light of these aspects, aluminum can be used as a material for ship building. It is environmental friendly, easy to recycle, and provides a high added value to fishing boats. In this paper, we report on mechanical and electrochemical characteristics of welding parts for friction stir welded 5456-H116 Al alloy. In friction stir welded at various traveling speeds under the rotation speed of 500 RPM, the best characteristics presented in traveling speed of 15mm/min. The anodic polarizations of base metal and welding metal were observed tendency which current density from the open circuit potential suddenly increase. The cathodic polarization presented concentrated polarization caused by the dissolved oxygen reduction reaction and activation polarization caused by hydrogen generation. From result of Tafel analysis, the corrosion potential of 5456 alloy(Base metal) was lower than that of friction stir welded part, as were its corrosion current densities.

UV Roll 임프린팅 공정을 이용한 렌티큘러 렌즈 제작 (Fabrication of Lenticular Lens by Continuous UV Roll Imprinting)

  • 명호;차주원;김석민;강신일
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2005년도 추계학술대회 논문집
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    • pp.91-94
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    • 2005
  • With increasing demands for large-scale micro-optical components in the field of digital display, the establishment of large-scale fabrication technology fur polymeric patterns has become a priority. The starting point of any polymer replication process is the mold, and the mold often has flat surface. However, It is very hard to replicate large-scale micro patterns using the flat mold, because the cost of large-scale flat mold was very high, and some uniformity and releasing problems were often occurred in large scale flat molding process. In this study, a UV roll imprinting system to overcome the financial and fabrication issues of large-scale pattern replication process was designed and constructed. As a practical example of the system, a lenticular lens with radius of curvature of $223{\mu}m$ and pitch of $280{\mu}m$, which was used to provide wide viewing angle in projection TV, was designed and fabricated. The roll stamper was fabricated using direct machining process of aluminum roll base. Finally, the shape accuracy and uniformity of roll imprinted lenticular lens sheet were measured and analyzed.

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폴리머 기판위에 형성된 나노구조제어 알루미나의 캐패시터 특성 (Capacitance Properties of Nano-Structure Controlled Alumina on Polymer Substrate)

  • 정승원;민형섭;한정환;이전국
    • 한국재료학회지
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    • 제17권2호
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    • pp.81-85
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    • 2007
  • Embedded capacitor technology can improve electrical perfomance and reduce assembly cost compared with traditional discrete capacitor technology. To improve the capacitance density of the $Al_2O_3$ based embedded capacitor on Cu cladded fiber reinforced plastics (FR-4), the specific surface area of the $Al_2O_3$ thin films was enlarged and their surface morphologies were controlled by anodization process parameters. From I-V characteristics, it was found that breakdown voltage and leakage current were 23 V and $1{\times}10^{-6}A/cm^2$ at 3.3 V, respectively. We have also measured C-V characteristics of $Pt/Al_2O_3/Al/Ti$ structure on CU/FR4. The capacitance density was $300nF/cm^2$ and the dielectric loss was 0.04. This nano-porous $Al_2O_3$ is a good material candidate for the embedded capacitor application for electronic products.

Surface Coating and Electrochemical Properties of LiNi0.8Co0.15Al0.05O2 Polyaniline Composites as an Electrode for Li-ion Batteries

  • Chung, Young-Min;Ryu, Kwang-Sun
    • Bulletin of the Korean Chemical Society
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    • 제30권8호
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    • pp.1733-1737
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    • 2009
  • A new cathode material based on Li$Ni_{0.8}Co_{0.15}Al_{0.05}O_2$ (LNCA)/polyaniline (Pani) composite was prepared by in situ self-stabilized dispersion polymerization in the presence of LNCA. The materials were characterized by fourier transform infrared spectroscopy (FT-IR), ultraviolet-visible spectroscopy (UV-Vis), X-ray diffraction (XRD), and scanning electron microscopy (SEM). Electrochemical properties including galvanostatic charge-discharge ability, cyclic voltammetry (CV), capacity, cycling performance, and AC impedance were measured. The synthesized LNCA/Pani had a similar particle size to LNCA and exhibited good electrochemical properties at a high C rate. Pani (the emeraldine salt form) interacts with metal-oxide particles to generate good connectivity. This material shows good reversibility for Li insertion in discharge cycles when used as the electrode of lithium ion batteries. Therefore, the Pani coating is beneficial for stabilizing the structure and reducing the resistance of the LNCA. In particular, the LNCA/Pani material has advantageous electrochemical properties.

EAP 액추에이터를 이용한 해양 정보 취득용 무선 전원 발생에 관한 연구 (A study on wireless power generation for marine information acquisition using EAP actuator)

  • 정은아;이기윤;정황훈;윤소남
    • 동력기계공학회지
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    • 제15권5호
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    • pp.49-53
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    • 2011
  • This study concerns about wireless power generation that uses the energy harvester with EAP actuator. The UWSN(Underwater Wireless Sensor Network) has been considered many times by many researches. Because the information of underwater is getting important to secure the resource or to predict the meteorological phenomena. But the sensor node in the UWSN is driven by the acoustic wave to communicate with other sensor node. And this acoustic wave usually spends a 100 times energy than the RF(Radio Frequency) wave due to transfermation medium(sea water). Therefore the power source of the sensor node is very important that is needed to improve in the UWSN. For this purpose, the energy harvester is made by the acrylic elastomer in this study. And the electrode is modified with an aluminum impurity to improve the efficiency of energy harvester. After that, the modified energy harvester is experimented to confirm the improvement of the energy efficiency.

고분자전해질 연료전지 분리판을 위한 Ni-P-rGO 무전해 복합도금층의 미세조직 분석 (Microstructure Analysis of Ni-P-rGO Electroless Composite Plating Layer for PEM Fuel Cell Separator)

  • Kim, Yeonjae;Kim, Jungsoo;Jang, Jaeho;Park, Won-Wook;Nam, Dae-Geun
    • 한국표면공학회지
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    • 제48권5호
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    • pp.199-204
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    • 2015
  • Recently, fuel cell is a good alternative for energy source. Separator is a important component for fuel cell. In this study, The surface of separator was modified for corrosion resistance and electric conductivity. Reduced graphene oxide (rGO) was made by Staudenmaier's method. Nickel, phosphorus and rGO were coated on 6061 aluminum alloy as a separator of proton exchange membrane fuel cell by composite electroless plating. Scanning electron microscope, energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy were used to examine the morphology of Ni-P-rGO. Surface images were shown that the rGO was dispersed on the surface of Ni-P electroless plating, and nickel was combined with the un-reduced oxygen functional group of rGO.

Flexible poly(vinyl alcohol)-ceramic composite separators for supercapacitor applications

  • Bon, Chris Yeajoon;Mohammed, Latifatu;Kim, Sangjun;Manasi, Mwemezi;Isheunesu, Phiri;Lee, Kwang Se;Ko, Jang Myoun
    • Journal of Industrial and Engineering Chemistry
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    • 제68권
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    • pp.173-179
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    • 2018
  • Electrochemical characterization was conducted on poly(vinyl alcohol) (PVA)-ceramic composite (PVA-CC) separators for supercapacitor applications. The PVA-CC separators were fabricated by mixing various ceramic particles including aluminum oxide ($Al_2O_3$), silicon dioxide ($SiO_2$), and titanium dioxide ($TiO_2$) into a PVA aqueous solution. These ceramic particles help to create amorphous regions in the crystalline structure of the polymer matrix to increase the ionic conductivity of PVA. Supercapacitors were assembled using PVA-CC separators with symmetric activated carbon electrodes and electrochemical characterization showed enhanced specific capacitance, rate capability, cycle life, and ionic conductivity. Supercapacitors using the $PVA-TiO_2$ composite separator showed particularly good electrochemical performance with a 14.4% specific capacitance increase over supercapacitors using the bare PVA separator after 1000 cycles. With regards to safety, PVA becomes plasticized when immersed in 6 M KOH aqueous solution, thus there was no appreciable loss in tear resistance when the ceramic particles were added to PVA. Thus, the enhanced electrochemical properties can be attained without reduction in safety making the addition of ceramic nanoparticles to PVA separators a cost-effective strategy for increasing the ionic conductivity of separator materials for supercapacitor applications.

Free vibration of actual aircraft and spacecraft hexagonal honeycomb sandwich panels: A practical detailed FE approach

  • Benjeddou, Ayech;Guerich, Mohamed
    • Advances in aircraft and spacecraft science
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    • 제6권2호
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    • pp.169-187
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    • 2019
  • This work presents a practical detailed finite element (FE) approach for the three-dimensional (3D) free-vibration analysis of actual aircraft and spacecraft-type lightweight and thin honeycomb sandwich panels. It consists of calling successively in $MATLAB^{(R)}$, via a developed user-friendly GUI, a detailed 3D meshing tool, a macrocommands language translator and a commercial FE solver($ABAQUS^{(R)}$ or $ANSYS^{(R)}$). In contrary to the common practice of meshing finely the faces and core cells, the proposed meshing tool represents each wall of the actual hexagonal core cells as a single two-dimensional (2D) 4 nodes quadrangularshell element or two 3 nodes triangular ones, while the faces meshes are obtained simply using the nodes at the core-faces interfaces. Moreover, as the same 2D FE interpolation type is used for meshing the core and faces, this leads to an automatic handling of their required FE compatibility relations. This proposed approach is applied to a sample made of very thin glass fiber reinforced polymer woven composite faces and a thin aluminum alloy hexagonal honeycomb core. The unknown or incomplete geometric and materials properties are first collected through direct measurements, reverse engineering techniques and experimental-FE modal analysis-based inverse identification. Then, the free-vibrations of the actual honeycomb sandwich panel are analyzed experimentally under different boundary conditions and numerically using different mesh basic cell shapes. It is found that this approach is accurate for the first few modes used for pre-design purpose.

제올라이트가 함유된 시멘트의 수화 특성 (Hydration Characteristics of Cement Containing Zeolite)

  • 이창용;김연철;이종집
    • 공업화학
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    • 제22권4호
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    • pp.423-428
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    • 2011
  • 경북 대포 지역에서 채취한 제올라이트의 시멘트 혼합재료로의 이용 가능성을 검토하기 위하여 제올라이트가 함유된 시멘트의 수화 특성을 연구하였다. 제올라이트가 함유된 시멘트 페이스트에 대하여 수화발열 속도, XRD, EDS, 질소 흡착, 수은 침투 등의 분석을 수행하였다. 제올라이트가 함유된 시멘트 페이스트에서는 제올라이트 양이 증가함에 따라 응결시간이 빨라지고 시멘트의 수화가 촉진되는 경향을 나타내었다. 제올라이트가 함유된 모르터에서는 제올라이트 양이 증가함에 따라 플로우가 크게 감소하였다. 또한 플레인 모르터와 비교하여 단기에 강도증진이 나타났다. 이러한 결과는 시멘트의 수화시 알칼리에 의한 제올라이트의 탈알루미늄 과정에서 제올라이트 입자로부터 이탈한 활성 알루미늄 종과 관련이 있는 것으로 보인다.