• Title/Summary/Keyword: aluminate cement

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Neuro-fuzzy model of concrete exposed to various regimes combined with De-icing salts

  • Ghazy, Ahmed;Bassuoni, Mohamed. T.
    • Computers and Concrete
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    • v.21 no.6
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    • pp.649-659
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    • 2018
  • Adaptive neuro-fuzzy inference systems (ANFIS) can be efficient in modelling non-linear, complex and ambiguous behavior of cement-based materials undergoing combined damage factors of different forms (physical and chemical). The current work investigates the use of ANFIS to model the behavior (time of failure (TF)) of a wide range of concrete mixtures made with different types of cement (ordinary and portland limestone cement (PLC)) without or with supplementary cementitious materials (SCMs: fly ash and nanosilica) under various exposure regimes with the most widely used chloride-based de-icing salts (individual and combined). The results show that predictions of the ANFIS model were rational and accurate, with marginal errors not exceeding 3%. In addition, sensitivity analyses of physical penetrability (magnitude of intruding chloride) of concrete, amount of aluminate and interground limestone in cement and content of portlandite in the binder showed that the predictive trends of the model had good agreement with experimental results. Thus, this model may be reliably used to project the deterioration of customized concrete mixtures exposed to such aggressive conditions.

Setting Time and Strength Characteristics of Cement Mixtures with Set Accelerating Agent for Shotcrete (숏크리트용 급결제를 첨가한 시멘트 모르타르의 응결 및 강도특성)

  • Kim Jin-Cheol;Ryu Jong-Hyun
    • Journal of the Korea Concrete Institute
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    • v.16 no.1 s.79
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    • pp.70-78
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    • 2004
  • Although set accelerating agents are used generally in New Austrian Tunneling Method, the standards for test methods and quality of set accelerating agents are not prescribed domestically. In this study, the proprieties of the various standards and the characteristics of set accelerating agents for shotcrete were evaluated. The alkali contents of set accelerating agents based on silicate, aluminate and cement were higher than those of alkali-free ones. From the result, it is thought that the quality control of aggregate should be enhanced and that the number of test cycle of alkali-aggregate reaction should be increased. The setting times of cement paste with set accelerating agents based on silicate and alkali-free ones were different largely with mixing methods. Compressive strength of mortar with set accelerating agents based on silicate, aluminate and cement at one day satisfied the specifications of Korea Concrete Institute. However, the strength ratio compared to control mix at 28 days showed as $50{\~}65\%$ except for the alkali-free set accelerating agents. As a results of setting time and strength test, the establishment of domestic standards that can reflect the characteristics of materials and construction methods of tunnels and that can increase quality of set accelerating agents is required immediately.

Effects of Calcium Aluminate Compounds on Hydration of BFS

  • Song, Hyeon-jin;Kang, Seung-Min;Jeon, Se-Hoon;Kim, Jung-Won;Song, Myong-Shin
    • Journal of the Korean Ceramic Society
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    • v.52 no.6
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    • pp.483-488
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    • 2015
  • Blast furnace slag(BFS) is well known for its hardening mechanism in ordinary Portland cement with alkali activation due to its latent hydraulic property. The possibility of using calcium compound as activator for BFS has been investigated in this study. The hydration properties of calcium compound activated BFS binders were explored using heat of hydration, powder X-ray diffraction and compressive strength testing. Heat of hydration results indicate that the hydration heat of BFS is lower than OPC paste by about 50%. And ettringite as hydration product was formed continuously as the calcium sulfate was decreased. The maximum compressive strength of hardened BFS mortar at 28 days is confirmed to be 83% as compared with hardened OPC mortar.

Experimental Study on the Improvement of Shotcrete Performance by Addition of Calcium Aluminate Based Accelerator and Metakaolin (시멘트 광물계 급결제와 메타카올린에 의한 숏크리트의 고성능화에 대한 실험적 연구)

  • Bae, Gyu-Jin;Chang, Soo-Ho;Park, Hae-Geun;Won, Jong-Pil
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.8 no.3
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    • pp.237-247
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    • 2006
  • The use of high-performance shotcrete lining is indispensable to improve long-term durability of a tunnel and to apply the single-shell tunnelling method. Among a lot of shotcrete admixtures, pozzolan materials such as silica fume have positive effects on increasing the strength and the durability of shotcrete. It is also well known that a cement-based accelerator is much faster in setting time and more eco-friendly than conventional accelerators. This study aimed to improve the properties of wet-mix shotcrete by incorporating with Metakaolin and the calcium aluminate based accelerator. To compare Metakaolin with silica fume, mixing ratios of each material were varied as 4% and 8% of cement weight. Moreover, Metakaolin was blended with silica fume, and their binder was also set to 4% and 8% of cement weight. At each mixing condition, setting time, compressive strength, flexural strength, permeability and freezing-thawing resistance were measured. From the experiments, it was revealed Metakaolin could be a substituting material for silica fume.

Evaluation on the Performance of Mortars Made with Calcium Aluminate Cement (칼슘알루미네이트 시멘트 모르타르의 성능 평가)

  • Lee, Seung-Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.6
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    • pp.80-87
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    • 2015
  • In this study, several properties of mortars made with calcium aluminate cement (CAC) such as hydrated products, strength characteristics, absorption, surface electric resistivity and chloride ions penetration resistance were experimentally investigated. The properties of CAC mortars were compared to those of ordinary portland cement (OPC) mortars. From the test results, it was found that the main hydrated products for CAC mortars were of $C_2AH_8$ and $CAH_{10}$, while CH, ettringite and calcite for OPC mortars. The surface electric resistivity and chloride ions penetration resistance of CAC mortars were significantly beneficial compared to those of OPC mortars. However, it should be noted that the absorption properties of CAC mortars were negatively examined. Thus, it needs to have more study for the improvement of surface absorption of CAC matrices. In addition, the combined mixture of CAC and OPC were ineffective to improve some performances of mortars.

Characterizations of High Early-Strength Type Shrinkage Reducing Cement and Calcium Sulfo-aluminate by Using Industrial Wastes

  • Lee, Keon-Ho;Nam, Seong-Young;Min, Seung-Eui;Lee, Hyoung-Woo;Han, Choon;Ahn, Ji-Whan
    • Journal of the Korean Ceramic Society
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    • v.53 no.2
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    • pp.215-221
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    • 2016
  • In this study, the utilization of the by-products of various industries was examined using raw materials of CSA high-functional cement such as coal bottom ash, red mud, phosphate gypsum, etc. Technology to improve energy efficiency and reduce $CO_2$ was developed as part of the manufacturing process; this technology included lower temperature sintering ($150{\sim}200^{\circ}C$) than is used in the OPC cement manufacturing process, replacement of CSA cement with the main raw material bauxite, and a determination of the optimum mix condition. In order to develop CSA cement, a manufacturing system was established in the Danyang plant of the HANIL Cement Co. Ltd., in Korea. About 4,200 tons of low purity expansion agent CSA cement (about 16%) and about 850 tons of the lime-based expansion agent dead burned lime (about 8%) were produced at a rate of 60 tons per hour at the HANIL Cement rotary kiln. To improve the OPC cement properties, samples of 10%, 13%, and 16% of CSA cement were mixed with the OPC cement and the compressive strength and length variation rate of the green cement were examined. When green cement was mixed with each ratio of CSA cement and OPC cement, the compressive strength was improved by about 30% and the expansibility of the green cement was also improved. When green cement was mixed with 16% of CSA cement, the compressive strength was excellent compared with that of OPC cement. Therefore, this study indicates the possibility of a practical use of low-cost CSA cement employing industrial wastes only.

The corrosion behaviour of steel in high alumina cement concrete (알루미나 시멘트 콘크리트의 철근 부식 저항성)

  • Lee, Ho-Jae;Kim, Jae-Hwan;Ann, Ki-Yong;Song, Ha-Won
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.289-290
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    • 2009
  • In this study, the resistance of calcium aluminate cement (CAC) against chloride-induced corrosion was assessed by testing for the strength, chloride transport, and corrosion behaviour. The study found that the CAC concrete had better performance than ordinary Portalnd cement(OPC) in resisting the corrosion of steel.

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Fluidity and Compressive Strength Properties of Cement-Mortar admixed with II-Anhydrite and Pozollanic Fine Powders (불산부생 II -형 무수석고와 포졸란 미분체가 혼입된 시멘트.몰탈 유동성 및 압축강도 특성)

  • 김도수;김재호;조민형;전진환;남재현;노재성
    • Proceedings of the Korea Concrete Institute Conference
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    • 1996.10a
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    • pp.154-165
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    • 1996
  • As II-anhydrite reacts with C3A(aluminate), C4AF(ferrite) at initial hydration of cement and assists the hydrolysis of C3S(calcium silicate), the production rate of ettringite(3C3A.3CaSO4.32H2O) and C-S-H gel was acclerated. It was known that compressive strength of cement concrete improved due to the effect of II-anhydrite. For the checking these effects of II-anhydrite, the fluidity and compressive strength of cementmortar admixed with II-anhydrite and pozollanic fine powders were investigated. By means of SEM analysis, the surface structure of mortar with the condition of steam curing at curing days=28 was investigated. As a result of this experiment, it was examined that II-anhydrite had an increase on the fluidity of cementpaste and compressive strength of mortar.

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Evaluation of Durability Performance of Wet- Mixed Shotcrete with Powder Types Cement Mineral Accelerator (시멘트 광물계 급결제를 사용한 습식 숏크리트의 내구성 평가)

  • Won Jong-Pil;Sung Sang-Kyoung;Park Chan-Gi;Cho Yong-Jin;Choi Seok-Won;Park Hae-Geun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.253-256
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    • 2004
  • Recently, construction works of scale are getting larger with economic growth. Shotcreting is one of major processes in tunnels construction. Accelerator is used in tunnel and underground structures to ensure early strength of shotcrete. Silicate based accelerator and aluminate based accelerator is getting widely in the field. But these accelerators have many problems due to decesase of long-term strength and low quality of the hardened shotcrete. in order to solve these problems, recently developed powder types cement mineral accelerator. In this study, we tested chloride permeability, freezing and thawing and accelerated carbonation of shotcrete. As a result of the test, wet-mixed shotcrete with powder types cement mineral accelerator exhibited durability improvement compared to the conventional shotcrete accelerator.

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Setting Time, Strength and Rebound Rate of Shotcrete according In Accelerators (급결제에 따른 숏크리트의 응결, 강도 및 리바운드율)

  • Lee Seong-Haeng;Kim Yong-Ha;Hahm Hyung-Gil;Kim Kwan-Jin
    • Journal of the Korea Concrete Institute
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    • v.17 no.3 s.87
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    • pp.427-434
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    • 2005
  • An experimental investigation was carried out in order to verify the compressive strength, flexural strength, equivalent bending strength, rebound rate of shotcrete according to silicate accelerator, aluminate accelerator, cement mineral accelerator respectively and to especially evaluate the performance of shotcrete using cement mineral accelerator for high quality. The test result of compressive strength was showed that all accelerators were satisfied the required test value for each age, for the requirement of having the $75\%$ or higher compressive strength ratio to plain concretes at 28 days, cement mineral accelerator with $87\%$ compressive strength ratio was only satisfied. In flexural strength test, cement mineral accelerator was satisfied the flexural strength requirement in steel fiber reinforced shotcrete for each age. Aluminate type was conformed to the requirement for 28 days, but not at 1 day, silicate type was failed to satisfy standard requirement. Rebound rate was measured between $11{\~}19\%$ and cement mineral accelerator was showed comparatively lower rebound rate. Based on the test results, cement mineral accelerator exhibited excellent strength improvement and lower rebound rate compared to the conventional accelerator, its result is showed the possibility of making high performance shotcrete.