• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2011년도 추계 학술논문 발표대회
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• pp.109-110
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• 2011

Gypsum is an important building material used to provide fire resistance to constructions by reducing their temperature rises. As the hardened gypsum is exposed to fire, evaporation of both the free water and the chemical bond water is easier than that in the cement extruding panel. The purpose of this study is to investigate the utilizability of alpha-hemihydrate gypsum to prevent spalling failure of cement extruding panel exposed to fire. This paper reports the fire-resistance property of a controled general cement extruding panel(C100), and gypsum-cement extruding panels(C50A50, A100) according to replacement ratio of alpha-hemihydrate gypsum. As a results, it is found that A100 and C50A50 are more effective to prevent the explosive spalling failure under standard fire condition than C100.

• 한국건설순환자원학회논문집
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• 제12권1호
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• pp.25-32
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• 2024

본 연구에서는 알파형 반수석고를 활용한 PHC 파일 콘크리트의 역학적 특성을 평가하였다. 알파형 반수석고의 치환율이 증가할수록 응결시간이 급격히 빨라졌으며, 특히 20 % 이상 치환 시 급격한 수화반응으로 응결시간이 단축되어 작업 시간 확보가 불가능하였다. 알파형 반수석고의 치환율이 증가할수록 ettringite와 Gypsum 피크가 증가하는 경향을 보였으며, ettringite 피크 증가로 인해 콘크리트의 수축량이 감소하는 것으로 판단된다. 알파형 반수석고 치환율 5~15 %에서는 OPC 대비 압축강도가 증가하거나 동등 수준으로 나타났으나 20 % 치환 시 급격한 응결로 인한 작업성이 저하되어 5~15 % 범위의 사용이 적절하다고 판단된다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2000년도 가을 학술발표회논문집(I)
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• pp.351-354
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• 2000

In recent years, the world development of alternative construction materials is associated with disposal problems of waste materials as a result of industrial activities. Technologies of refining gypsum to several gypsum modifications ($\alpha$ and $\beta$-hemihydrate) which can be used as construction material in a large scale do actually exist or are under development. This paper provides a technical and economic perspective of the waste gypsum treatment. Especially, several applications particularly of $\alpha$-hemihydrate will be presented, e.g. artificial gypsum aggregate and light-weight masonry units.

• 한국세라믹학회지
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• 제24권4호
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• pp.343-348
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• 1987

The effects of salts such as aluminum sulfate as inorganic salt(2-4%), and sodium salts of citrate, tartrate, succinate, potassium tartrate and gelatin as organic salts(0.1%) on the formation of ${\alpha}$-calcium sulfate hemihydrate from by-product gypsum of phosphoric acid process under hydrothermal condition at 123$^{\circ}C$ and 133$^{\circ}C$ were investigated. Aluminum sulfate solution exhibited the catalystic effected on the crystallization of ${\alpha}$-calcium sulfate hemihydrate of which was assumed in the prismatic form, and organic salts solution exhibited little effect on the catalystic action to the crystallization, than inorganic salts. In the acidic solution with sulfuric acid(pH=2), needle like crystal of calcium sulfate hemihydrate was obtained. Hydrothermal process with aluminum sulfate solution also showed certain amounts of impurity removal such as phosphorus penataoxide from calcium sulfate hemihydrate.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2014년도 추계 학술논문 발표대회
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• pp.158-159
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• 2014

In general, the shrinkage occurring in the floor mortar is large the influence by the dry shrinkage. In order to reduce the cracks occurring in the floor mortar, studies of physical methods are often performed, but these methods is difficult to prevent cracking of the floor mortar essentially. Therefore, in this study, the dry shrinkage properties of floor mortar of gypsum and red clay type using alpha-hemihydrate gypsum had been evaluated. The experimental variables were cement mortar(CM), gypsum mortar(GM), red-clay mortar(RM), the evaluation items was conducted experiment to evaluate the setting time, the compressive strength, drying shrinkage cracks, the dry shrinkage. As a result, it was confirmed that condensation time of GM is shorter that that of CM, and GM satisfied the compressive strength of the floor mortar standard. Also shrinkage deformation of GM reduced more than the CM.

• 한국건축시공학회지
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• 제11권2호
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• pp.181-188
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• 2011

고강도콘크리트 부재 표면에 내화모르타르를 피복하여 화재시 콘크리트 표층부의 온도상승을 저감시킴으로서 내부 철근온도 상승을 억제한다. 본 논문은 간이내화시험을 통하여 시멘트 및 석고계 내화모르타르 피복 고강도콘크리트의 내부철근 온도상승을 검토하기 위한 것이다. 그 결과 석고계 내화모르타르가 시멘트계 내화모르타르보다 고강도콘크리트의 내부철근 온도상승을 저감시키는데 효과적인 것으로 나타났으며 내화모르타르 피복두께가 작을수록 시멘트계 내화모르타르와의 내부 철근 온도차이가 증가하였다. 또한 ${\alpha}$형 반수석고와 ${\beta}$형 반수석고 종류에 따른 내화모르타르의 온도상승 저감효과의 차이는 없는 것으로 나타났지만, ${\alpha}$형 반수석고 내화모르타르의 압축강도가 ${\beta}$형 반수석고 내화모르타르보다 높게 나타났다.

• 한국세라믹학회지
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• 제25권3호
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• pp.300-306
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• 1988

The catalytic effect of salts on formation of ${\alpha}$-calcium sulfate hemihydrate under water vapor at atmospheric pressure was studied and the formation of q-calcium sulfate hemilydrate from by-product gypsum of phosphoric acid process was investigated. The order of catalytic effect of salts are as follow: Ammonium chloride>Sodium succinate>Calcium chloride>Sodium tartrate>Magnesium chloride The prismatic crystals was formed when ammonium chloride, calcium chloride and magnesium chloride was added, whereas the needle crystals was formed when sodium tartrate was added. Ammonium chlorideis most successful in catalytic effects in formation of ${\alpha}$-calcium sulfate hermihydrate for the by-product gypsum of phosphoric acid process.

• 한국세라믹학회지
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• 제25권1호
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• pp.66-72
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• 1988

The effect of salts on the formation of ${\alpha}$-hemihydrated gypsum at boiling temperature under atmospheric pressure was studied by the solubility measurement method, and the formation of ${\alpha}$-hemihydrated gypsum from by-product gypsum of phosphoric acid process in the salts solution were investigated. The order of catalytic effect of salt on the formation of ${\alpha}$-hemihydrated gypsum are as follows: NH4Cl>NaCl>NaNO3. In the salts solution of sodium nitrate, sodium chloride, and ammonium chloride, prismatic ${\alpha}$-hemihydrated gypsum was obtained and the crystal form was converted to needle form in complex solution with sulfuric acid. The P2O5 content in gypsum was largely decreased in this atmosphoric solution process.

• 공업화학
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• 제17권6호
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• pp.619-624
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• 2006

유연탄을 연소하는 화력발전소의 탈황설비에서 생산된 배연탈황석고를 대상으로 가압반응기를 이용하여 수열반응을 통한 알파형 반수석고의 생성과정을 살펴보았다. 실험 결과 첨가제를 사용하지 않아도 반응온도 $120{\sim}140^{\circ}C$ 범위 하에서는 용해-재석출 기구에 의하여 알파형 반수석고가 생성되었으나 아스펙트 비가 매우 높은 침상형 결정이 생성되었다. 호박산나트륨을 첨가제로 주입한 결과 결정형상은 침상형에서 각주형으로 변화되었으며 혼수 비(water/powder ratio)는 33%까지 감소하였다. 호박산나트륨의 농도는 20 mM이 적정하였으며 반응도중 성형체의 붕괴를 방지하고 성형체의 기공부피에 의한 모세관 효과를 최대화하기 위한 최적의 성형체 성형압력은 $30kgf/cm^2$이었다.

• 자원리싸이클링
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• 제15권3호
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• pp.20-29
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• 2006

본 연구는 인산부생석고를 결정성장시켜 고순도의 결정질 이수석고를 제조하여 다용도의 석고를 얻고자 하였다. $99^{\circ}C$의 수중에서 약 2시간 동안에 이수석고는 $\alpha$형의 반수석고로 탈수가 완료되었다. 수중탈수된 반수석고를 매정제 $Na_2SO_4$를 10wt%, 슬러리 농도는 20%, pH가 $5{\sim}6$, 결정성장온도 $65^{\circ}C$의 조건에서 4시간 동안 결정성장 시키면 장경이 $200{\mu}m$정도인 결정을 얻을 수 있었다. 결정성장이 끝난 슬러리를 325#로 습식사분하여 사상산물로 고순도 결정성장 석고를 얻었으며, 이 때 석고의 회수율은 약 93.9%, 순도는 99% 정도 였다.