• Journal of the Korean Recycled Construction Resources Institute
• /
• v.7 no.4
• /
• pp.302-309
• /
• 2019

This paper shows an experimental study for fundamental characteristics of alkali activated fly ash-slag cement paste exposed to seawater of 5℃. Fly ash and slag were blended in three different ratios; 6:4, 7:3, and 8:2. Activators (NaOH and Na2SiO3) used 5% of the binder weight. It was shown that as the fly ash substitution rate in creased, compressive strength and density decreased, and water absorption rate increased. The results of X-ray diffraction and thermogravimetry showed that hydration reactants formed in samples did not differ significantly, however, C-S-H gel increased as the slag substitution rate increased. It showed that mechanical properties of fly ash-slag cement pastes under 5℃ seawater condition were affected by the slag substitution rate rather than fly ash.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.21 no.6
• /
• pp.74-82
• /
• 2017

This research presents the results of the strength and drying shrinkage properties to study the effect of ground granulated blast furnace slag(GGBFS), fly ash(FA) and calcium sulfoaluminate(CSA) for activated ternary blended slag cement. The activated ternary blended cement(ATBC) mortar were prepared having a constant water-cementitious materials ratios of 0.4. The GGBFS contents ratios of 100%, 80%, 70% and 60%, FA replacement ratios of 10%, 20%, 30% and 40%, CSA ratios of 0%, 10%, 20% and 30% were designed. The superplasticizer of polycarboxylate type were used. The activator was used of 10% sodium hydroxide(NaOH) + 10% sodium silicate($Na_2SiO_3$) by weight of binder. Test were conducted for mini slump, setting time, V-funnel, water absorption, compressive strength and drying shrinkage. According to the experimental results, the contents of superplasticizer, V-funnel and compressive strength increases with an increase in CSA contents for all mixtures. Moreover, the setting time, water absorption ratios and drying shrinkage ratio decrease with and increase in CSA. One of the major reason for the increase of strength and decrease of drying shrinkage is the accelerated reactivity of GGBFS with alkali activator and CSA. The CSA contents is the main parameter to explain the strength development and decreased drying shrinkage in the ATBC.

• Journal of the Korea Concrete Institute
• /
• v.18 no.4 s.94
• /
• pp.449-458
• /
• 2006

The discharge of fly ash that is produced by coal-fired electric power plants is rapidly increasing in Korea. The utilization of fly ash in the raw materials would contribute to the elimination of an environmental problem and to the development of new high-performance materials. So it is needed to study the binder obtained by chemically activation of pozzolanic materials by means of a substitute for the cement. Fly ash consists of a glass phase. As it is produced from high temperature, it is a chemically stable material. Fly ash mostly consists of $SiO_2\;and\;Al_2O_3$, and it assumes the form of an oxide in the inside of fly ash. Because this reaction has not broken out by itself, it is need to supply it with additional $OH^-$ through alkali activators. Alkali activators were used for supplying it with additional $OH^-$. This paper concentrated on the strength development according to the kind of chemical activators, the curing temperature, the heat curing time. Also, according to scanning electron microscopy and X-Ray diffraction, the main reaction product in the alkali activated fly ash mortar is Zeolite of $Na_6-(AlO_2)_6-(SiO_2)_{10}-12H_2O$ type.

• Korean Journal of Materials Research
• /
• v.26 no.10
• /
• pp.521-527
• /
• 2016

Geopolymers have many advantages over Portland cement, including energy efficiency, reduced greenhouse gas emissions, high strength at early age and improved thermal resistance. Alkali activated geopolymers made from waste materials such as fly ash or blast furnace slag are particularly advantageous because of their environmental sustainability and low cost. However, their durability and functionality remain subjects for further study. Geopolymer materials can be used in various applications such as fire and heat resistant fiber composites, sealants, concretes, ceramics, etc., depending on the chemical composition of the source materials and the activators. In this study, we investigated the thermal properties and microstructure of fly ash and blast furnace slag based geopolymers in order to develop eco-friendly construction materials with excellent energy efficiency, sound insulation properties and good heat resistance. With different curing times, specimens of various compositions were investigated in terms of compressive strength, X-ray diffraction, thermal property and microstructure. In addition, we investigated changes in X-ray diffraction and microstructure for geopolymers exposed to $1,000^{\circ}C$ heat.

• Journal of the Korea Concrete Institute
• /
• v.26 no.2
• /
• pp.117-124
• /
• 2014

Globally, there are environmental problems due to greenhouse gas emissions. $CO_2$ emissions rate of the cement industry is very high, but the continued demand of cement is needed in the future. In this study, in order to reduce the environmental impact of $CO_2$ emissions from cement production. The experiments were carried out for the development of non-sintered cement (have not undergone firing burning) by granulated ground blast furnace slag. In order to compare the characteristics by curing, an experiment was conducted by changing the curing conditions such as atmospheric steam curing, observe the mechanical properties for the measurement of flexural compressive strength by mortar, observe the chemical properties such as acid resistance, $Cl^-$ penetrate resistance and analyzed the mechanism of hydration by XRD, SEM experiments. From the experimental results, as compared with portland cement usually confirm the mechanical and chemical properties excellent, it is expected be possible to apply to the undersea, underwater and underground structures that require superior durability. In addition, based on the excellent compressive strength by steam curing, it is expected to be possible to utilize as a cement replacement material in the secondary product of concrete. In the future, to solve the problem through continued research, it will be expected to reduce the effect of environmental load and to be excellent economics.

• Journal of the Korea Concrete Institute
• /
• v.23 no.6
• /
• pp.765-772
• /
• 2011

The present study summarizes a series of compressive tests on concrete cylinder in order to examine the stressstrain relationship of alkali-activated (AA) slag concrete. The compressive strength and unit weight of concrete tested ranged from 8.6 MPa to 42.2 MPa and from $2,186kg/m^3$ to $2,343kg/m^3$, respectively. A mathematical equation representing the complete stress-strain curve was developed based on test results recorded from 34 concrete specimens. The modulus of elasticity, strain at peak stress, slopes of ascending and descending branches of stress-strain curves were generalized as a function of compressive strength and unit weight of concrete. The mean and standard deviation of the coefficient of variance between measured and predicted curves were 6.9% and 2.6%, respectively. This indicates that the stress-strain relationship of AA slag concrete is represented properly with more accuracy in the proposed model than in some other available models for ordinary portland cement (OPC) concrete.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.9 no.1
• /
• pp.1-12
• /
• 2021

The present study proposes the modified-stoichiometric model for describing hydration of sodium silicate-based alkaliactivated slag(AAS), and compares the results with the thermodynamic modelling-based calculations. The proposed model is based on Chen and Brouwers(2007a) model with updated database as reported in recent studies. In addition, the calculated results for AAS are compared to those for hydrated portland cement. The maximum difference between the proposed model and the thermodynamic calculation for AAS was at most 20%, and the effects of water-to-binder ratio and activator dosages were identically described by both approaches. In particular, the amount of non-evaporable water was within 10% difference, and was in excellent agreement with the experimental results. Nevertheless, notable deviation was observed for the chemical shrinkage, which is largely dependent on the volume of hydrates and pores.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.1 no.2
• /
• pp.114-119
• /
• 2013

The present study tested 5 concrete mixes to develop reliable mixing proportions for the sustainable alkali-activated(AA) foamed concrete as a thermal insulation material for the floor heating system of buildings. The AA binder used was composed of 73.5% ground granulated blast-furnace slag, 15% fly ash, 5% calcium hydroxide, and 6.5% sodium silicate. As a main variable, the unit binder content varied from $325kg/m^3$ to $425kg/m^3$ at a space of $25kg/m^3$. The test results revealed that AA foamed concrete has considerable potential for practical applications when the unit binder content is close to $375kg/m^3$, which achieves the minimum quality requirements specified in KS F 4039 and ensures economic efficiency. In addition, lifecycle assessment demonstrated the reduction in the environmental impact profiles of all specimens relative to typical ordinary portland cement foamed concrete as follows: 99% for photochemical oxidation potential, 87~89% for global warming potential, 78~82% for abiotic depletion, and 70~75% for both acidification potential and human toxicity.

• Journal of the Korea Concrete Institute
• /
• v.20 no.3
• /
• pp.405-412
• /
• 2008

Six alkali-activated (AA) concrete mixes were tested to explore the significance and limitations of developing an environmental friendly concrete. Ground granulated blast-furnace slag and powder typed sodium silicate were selected as source material and an alkaline activator, respectively. The main parameter investigated was the replacement level of lightweight fine aggregate to the natural sand. Workability and mechanical properties of lightweight AA concrete were measured: the variation of slump with time, the rate of compressive strength development, the splitting tensile strength, the moduli of rupture and elasticity, the stress-strain relationship, the bond resistance and shrinkage strain. Test results showed that the compressive strength of lightweight AA concrete sharply decreased when the replacement level of lightweight fine aggregate exceeded 30%. In particular, the increase in the discontinuous grading of lightweight aggregate resulted in the deterioration of the mechanical properties of concrete tested. The measured properties of lightweight AA concrete were also compared, wherever possible, with the results obtained from the design equations specified in ACI 318-05 or EC 2, depending on the relevance, and the results predicted from the empirical equations proposed by Slate et al. for lightweight ordinary Portland cement concrete. The stress-strain curves of different concrete were compared with predictions obtained from the mathematical model proposed by Tasnimi. The measured mechanical properties of lightweight AA concrete generally showed little agreement with the predictions obtained from these equations.

• Advances in concrete construction
• /
• v.15 no.3
• /
• pp.149-159
• /
• 2023

Water glass (WG) and sodium sulfate (SS) were used to prepare polymeric aluminum chloride residue cement mortar (PACRM) by single and compound blending with polymeric aluminum chloride waste residue, respectively. The structural strength and textural characteristics examinations showed that PACRM consistency increased by incorporating WG, but decreased by incorporating SS. When WG and SS were compounded, the mortar consistency initially rose before falling. The compressive strength of PACRM increased and then decreased as WG was increased. The mechanical properties of PACRM were better enhanced by SS than WG, showing no strength deterioration. The main reason for the improved mechanical properties of polymeric aluminum chloride waste residue in the presence of activators is the increased precipitation of reactive substances, such as C-S-H gels, calcium silica, and Ca(OH)₂. The density of the specimens with PACRM and the degree of aggregation of hydration products were significantly enhanced by generating more hydration products in the mortar. Further, the cracks and pores were significantly reduced, and the matrix structure was continuous and dense at 5% SS doping and 3% compound doping.