• 제목/요약/키워드: alkali washing

검색결과 69건 처리시간 0.025초

검정콩 함유 천연 안토시아닌의 염색성 연구 (Studies on the Dyeing Properties of Black Soybean Anthocyanin)

  • 김성연;염선경;이경남
    • 한국의류산업학회지
    • /
    • 제9권1호
    • /
    • pp.103-112
    • /
    • 2007
  • The purpose of this study was to investgate dyeing, moradnting properties and colorfastness activities of silk, polyamide, acetate treated black soybean extracts. The color of extract by buffer solution (pH=1) red, but the higher pH of extracted black soybean solution the paler of color strength. Black soybean extracts was approved anthocyanin of 3type(Delphinidin3-glucoside, Cyanidin 3-glucoside, Petunidin 3-glucoside) by chemiclal analysis. This anthocynin, in acid condition, is oxinium structure (red color, soluable) but, in alkali condition quinoid structure(dark brown, in soluable). The optimum dyeing condition of black soybean anthocynin was 10min at $30^{\circ}C$, pH -1. Colorfastness to washing and light showed generally low but crocking fastness was excellent.

Vat dyeing of Wool and Cotton fabrics with Sepia Melanin

  • Kim, Su-Jin;Jang, Jin-Ho
    • 한국염색가공학회지
    • /
    • 제22권2호
    • /
    • pp.88-93
    • /
    • 2010
  • Using extracted sepia melanin powder by repeated treatments with aqueous sodium hydroxide and acetic acid solutions, vat dyeing of wool and cotton fabrics was carried out under various dyeing conditions including concentration of melanin, alkali, reducing agent and salt, as well as dyeing time and temperature. A K/S of 25.3 for wool fabrics was obtained at the optimal dyeing condition with 9% owf melanin, 0.5g/L NaOH and 56g/L $Na_2S_2O_4$ without salt at $80^{\circ}C$ for 90minutes. The vat dyeing of sepia melanin was applicable to both cotton and wool fabrics but the wool showed higher dyeability. The color fastness properties of the dyed wool and cotton fabrics were excellent to washing, rubbing and light irradiation.

몽골지역의 신재생에너지 발굴: 바이오디젤 (Development of Renewable Energy Source in Mongolia: Biodiesel)

  • 홍연기
    • 융복합기술연구소 논문집
    • /
    • 제3권1호
    • /
    • pp.9-14
    • /
    • 2013
  • Recently, the development of renewable energy sources in Mongolia has been needed due to climate change and air pollution in Ulaanbaatar as rapid economic growth. Biodiesel can be considered as an alternative fuel for petroleum based diesel in order to decrease air pollution in Ulaanbaatar because of its no emission of particle materials from internal combustion engine in automobile. Rapeseed oil having low cloud point and pour point was suggested as a promising raw material for biodiesel production in Mongolia. Considering high population density and severe air pollution by particle materials and SOx in Ulaanbaatar, prior supplying site of biodiesel in Mongolia was the capital region including Ulaanbaatar. In the production of biodiesel in Mongolia, adsorption process was a effective alternative to washing process for the removal of residual alkali catalyst and reactants due to long winter time in Mongolia. For the stable supply of biodiesel, subsidy and no tax policy is needed in the early stage of biodiesel supply in Mongolia.

  • PDF

전처리약제에 따른 셀룰로오스 디지털텍스타일 프린팅소재의 개발에 관한 연구 (Development of Cellulosic Woven Fabric for Digital Textile Printing)

  • 손은종;이영목;장세찬;이성철
    • 한국염색가공학회지
    • /
    • 제17권6호
    • /
    • pp.20-26
    • /
    • 2005
  • For developing digital printing textiles, special pretreatment processes are necessary. These processes include developing formulation of coating agent and coating processes. The pretreatment were investigated with the variation concentration of anti-migration agent, fixation chemical etc.. The printing qualities according to pretreatment conditions were studied with color yield, printed capital letter sharpness and washing fastness. It was observed that the concentration of anti-migration agent, fixation agent(alkali) was closely related to printing qualities. For developing industrial technology of cellulosic digital printing textiles, optimum viscosity of pretreatment coating formulation is very important factor.

수산가공공장 폐액의 등전점 침전처리에 의한 유용성분 재회수 이용 1. 고등어 육 고기풀 제조시 발생되는 폐액의 처리장치 개발 (Recovery and Utilization of Proteins and Lipids from Washing Wastewater in Marine Manufacture by Isoelectric Point Precipitation Method 1. The Coagulation Treatment for Washing Wastewatfr of Minced Mackerel Meat)

  • 서재수;조순영
    • KSBB Journal
    • /
    • 제10권1호
    • /
    • pp.1-8
    • /
    • 1995
  • 냉통고기풀 또는 수산연제품 등의 수산가공품 제조시 수세공정에 의해 폐액 중으로 많은 수용성 단백질과 지질성분이 유출되고 있는데, 이로 인하여 폐수의 BOD 및 COD값이 상승되어 해양의 오염과 연안의 적조현상을 일으키는 원인이 되고 있다. 따 라서, 본 연구에서는 해양오염 방지 빛 미이용 자원 의 개발이라는 두 측면에서 수세폐액 중에 함유되어 있는 수용성 단백질을 등전점 pH이동침전법에 의해 최적으로 회수하는 조건을 규명하였고, 아울러 그 회수단백질의 이용가능성 타진을 위해 기초척인 성 분 분석도 행하였다. $\circled1$ 수세폐액 중의 수용성 단백질을 회수하기 위한 방법으로서 여러 가지 등전점 응집법 중 산이통법이 효율적이었다. 즉 수세폐액을 먼저 pH 2.5~3.0으 로 낮춘 후 pH 6.5~7.5로 재조절하여 원심분리한 것이 높은 단백질 회수율을 나타내였다. 한편, 폐액 내 잔존지방은 산이통 처리후 대부분 부유하여서 그 상충수를 따라 부어내어 유분리기로 쉽게 수거가능 하므로 본 처리 장치로써 잔존단백질과 지방을 동시 회수할 수가 있다. $\circled2$ 최척처리조건에서 회수한 단백질구분의 수분과 단백 질 함량은 80.6 및 14.4 % 였다. 한편, 회수단백 질구분의 VBN함량은 9.6mgj100g로서 선도가 양 호하였으며, 구성아미노산 중 lysine 등 필수아미노 산이 여전히 많은 비율로 존재해 있어 영향학적으로 도 손색이 없었다. 이상의 결과로 미루어 보아 냉통고기풀이나 어묵 의 제조공정 중에 나오는 수세폐액으로부터 수용성 단백질 벚 유지를 통전점침전법의 한 변형인 산이통 법으로 간단히 재회수할 수 있음을 얄 수 있었다. 그래서 이들 성분의 재회수로 수산가공공장폐액에 의 한 하천의 오염을 근본적으로 막을 수 있음은 물론 이고 수산가콩폐기물의 완전 식량화의 가능성도 찾 아볼 수 있게 되었다고 판단되어진다.

  • PDF

Fabrication of Cr$_2$O$_3$powder from waste MgO-Cr refractory

  • Lee, Hoon-Ha;Sohn, Jin-Gun;Lee, Jae-Young;Kim, Dae-Young
    • 대한전자공학회:학술대회논문집
    • /
    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
    • /
    • pp.357-361
    • /
    • 2001
  • The possibility of producing Cr$_2$O$_3$powder from waste magnesia-chromium refractory was investigated by sulfuric acid reaction, alkali fusion, water leaching & purification and heat treatment. The effects of temperature, the amount of NaOH added and the flow rate of air on chromium extraction efficiency in an alkali fusion step were investigated. The fusion product was leached with methanol to solve free-NaOH, and then leached with water to produce a Na$_2$CrO$_4$solution. The purity of chrome(Ⅵ) oxides, prepared both from monochromate with an impurity content and monochromate purified with $CO_2$were also examined. The purified monochromate solution was reduced from Cr(Ⅵ) to Cr(III) with NaHSO$_3$solution. The reduced solution was neutralized with NaOH to produce Cr(OH)$_3$. Water washing was treated to eliminate Na$_2$SO$_4$from neutralized Cr(OH)$_3$slurry. The washed Cr(OH)$_3$was dried and thermally treated to produce Cr$_2$O$_3$powder. The properties like lightness and hue of Cr$_2$O$_3$fabricated in this study were L=47.47, a=-14.40 and b=17.21.

  • PDF

오염중의 유이지방산이 세척에 미치는 영향(제일보 팔미트산의 세척 특성) (Studies on the Detergency Characteristics of Free Fatty Acid in Oily Soil. Part 1. Detergency of Palmitic Acid.)

  • 정혜원;김성련
    • 한국의류학회지
    • /
    • 제1권1호
    • /
    • pp.31-37
    • /
    • 1977
  • The effects of surfactants and concentration of NaOH in surfactant solution on the removal of free fatty acid soil from cotton fabrics were investigated. Cotton fabrics were soiled with palm itic acid which is the most common fatty acid found in natural oily soil and washed in Lauder-ometer with various types of surfactant with or without NaOH. The rate of soil removal was estimated by analyzing palmitic acid contents in fabric before ar d after washing. Analysis of palmitic contents was made by extracting palmitic acid with azeotropic mixture of alcohol-benzene and the extracts were titrated with standard NaOH solution. It was shown that the types of surfactant are important factor in free fatty acid removal and the efficiency increases in the following order: SLS$90\%$ of initial sorption. In relation to the mechanism of detergency, the suspending and emulsifying power of surfactants were also examined. From the results of this experiments, it could be concluded that the soap formation with alkali and the suspending power of surfactant arc significant factors in free fatty acid soil removal, but the emulsifying power of it is neglizible.

  • PDF

천연인디고를 이용한 셀룰로오스계 직물 염색의 표준화 연구: 일단계 환원/염색에 의한 마직물 염색 (Optimization of Cellulose Dyeing with Natural Indigo: Ramie dyeing by One-step Reduction/dyeing Process)

  • 손경희;신윤숙;류동일
    • 한국의류산업학회지
    • /
    • 제13권2호
    • /
    • pp.263-268
    • /
    • 2011
  • One-step reduction/dyeing method was applied for ramie dyeing with natural indigo powder. The effect of reduction/dyeing conditions including the pH of bath, dye temperature and time, and concentration of indigo powder and reduction agent on dye uptake and color properties were investigated. Regardless of addition of alkali, the dyed fabrics appeared in the PB Munsell color range(${\lambda}_{max}$: 660 nm) and the dye uptake was much higher with no addition of sodium hydroxide. Dyeing was carried out through the use of only sodium hydrosulfite in the bath. The maximum dye uptake was obtained at 60 for 30min. Saturated dye uptake was obtained at 2 g/L of sodium hydrosulfite concentration up to 2 g/ L of indigo powder. Whereas, at higher indigo powder concentration (4 g/L), more than 3 g/L of reducing agent concentration was required for obtaining the saturated dye uptake. Color reproducibility was reliable with color difference in the range of 0.03~0.16. Regardless of color strength, fastness to rubbing was acceptable with a 3/4~4/5. Fastness to washing, dry cleaning, and light of samples with low color strength were poor. Whereas, fastness to washing, dry cleaning, and light of samples with high color strength were very good.

산성이온수 농도제어를 위한 Microprocessor를 이용한 PWM 제어 (The PWM Control Which used Microprocessor for Intensity Control of Acid Ion Water)

  • 권윤중;남상엽
    • 전자공학회논문지
    • /
    • 제50권7호
    • /
    • pp.269-274
    • /
    • 2013
  • 전해 산성이온수는 알칼리성 이온수에 비해 응용분야가 음용을 목적으로 하는 알칼리이온수와 많이 다르게 이용되고 있으며 ph 농도에 따라 강산성인 경우 잔류염소에 의한 살균 목적의 소독제로 사용되고, 중산성인 경우 세척과 세안으로 사용하고, 약산성인 경우 식재료와 혼합하여 요리에 널리 사용할 수 있다. 이런 산성이온수를 생성하기 위해서는 물을 전기분해 하여 사용하는데 전기분해 하는 과정에서 염소가스와 수산화나트륨 등의 물질로 살균력을 가지며, 전기분해시 +전극 쪽으로 -이온을 띤 염소, 인, 유황 등의 유기물이 모여져 산성이온수를 만든다. 또한 산성수와 알칼리수를 분리하기 위해서 격막을 사용했다. ph 농도변화의 구현방법은 Microprocessor를 이용하여 강산성에서 약산성 사이의 ph 농도를 PWM(pulse width modulation) 제어로 3종류의 PWM 전압을 전해조 전극에 인가하여 PWM제어에 의한 연속적으로 농도가 조절된 산성수가 생성되게 구현하였다.

Triglyceride의 세척성에 영향을 미치는 몇가지 요인 (Some Factors Effect on the Detergency of Triglyceride)

  • 이미식;김성련
    • 한국의류학회지
    • /
    • 제5권1호
    • /
    • pp.15-21
    • /
    • 1981
  • The effect of fatty acid content in oily soil and conditions of washing on the removal of triglyceride have been studied. Cotton lawn was soiled with the four-component soil-tripalmitin, palmitic acid, dodecyl alcohol and dodecane-and washed in constant temperature waterbath shaker. The detergency was estimated by analysis of triglyceride labelled carbon-14 on fabrics before and after washing by means of liquid scintillation counting. It was shown that the detergency of triglyceride washed with the nonionic, nonylphenol poly (10)-ethylene oxide and soap was increased steadily with increasing temperature, whereas with the anionics Na-DBS and SLS, the detergency was rather decreased when the temperature was elevated above $40^{\circ}C$. To investigate the effects of free fatty acid content in soil on the removal of triglyceride, the fabrics were soiled altering palmitic acid content, and then washed. From the results, the detergency of triglyceride was developed with increasing free fatty acid content. With soils containing less than $30\%$ of free fatty acid, of the three detergents tested, the nonionic was by far the most effective soil removal. Soap was intermediate and the synthetic anionic was the poorest. With soil containing $45\%$ of free fatty acid, soap was the most effective soil removal. When NaOH was added to detergent solution. the detergency of triglyceride was improved without regard to detergents. The optimum alkalinity was obtained according to free fatty acid content. And the alkalinity changed to low NaOH concentration with increasing free fatty acid content. From the results mentioned above, it could be concluded that the major removal mechanisms of triglyceride containing oily soil were mesomorphic phase formation, solubilization and soap forma-tion when alkali was added in detergent solution.

  • PDF