• Journal of the Korean Recycled Construction Resources Institute
• /
• v.3 no.1
• /
• pp.58-63
• /
• 2015

Several researches on cement zero concrete using alkali-activators have been conducted to investigate its fundamental material properties such as slump, strength and durability, however, research on the structural behavior of relevant members involving the elastic modulus, stress-strain relationship is essential for the application of this cement zero concrete to structural members. In this paper the shear behavior of reinforced concrete beams using 50 MPa-alkali activated slag concrete was experimentally evaluated. To achieve such a goal, six reinforced concrete beam specimens were fabricated and their shear behaviors were observed. The maximum difference between test results and analysis results in crack shear stress for beam specimens without stirrups is 31%, while that for beam specimens with stirrup is 15%. Furthermore, it is also found that the shear strength of alkali activated slag concrete is by 22~57% greater than the nominal shear strength calculated by design code, implying that shear design equations would provide conservative results on the safety side.

• Journal of the Korea Institute of Building Construction
• /
• v.14 no.2
• /
• pp.170-176
• /
• 2014

This study examined the effect of chemical attack on the stress-strain relationship of alkali-activated Hwangtoh concrete. Water-to-binder ratio and air content were selected as mixture parameters. The stress-strain relationship of concrete was measured at chemical immersion times of 0, 7, 28, 56, and 91 days from an age of 28 days. Based on the test results, the reduction in compressive strength of alkali-activated hwangtoh concrete owing to chemical attack was formulated. In sddition the present study demonstrated that the stress-strain behavior of concrete under chemical attack is significantly dependent on the air content and chemical immersion time, indicating the rate of decrease of modulus of elasticity was greater than that of compressive strength at the same immersion time. As a result, the stress-strain behavior of concrete under chemical attack was significantly inconsistent with the conventional models specified in the CEB-FIP provision.

• Computers and Concrete
• /
• v.17 no.4
• /
• pp.523-539
• /
• 2016

Alkali-activated binder (AAB) is increasingly being considered as an eco-friendly and sustainable alternative to portland cement (PC). The present study evaluates 30 different AAB mixtures containing fly ash and/or slag activated by sodium hydroxide and sodium silicate by correlating their properties from micro to specimen level using regression. A model is developed to predict compressive strength of AAB as a function of volume fractions of microstructural phases (physicochemical properties) and ultrasonic pulse velocity (elastic properties and density). The predicted models are ranked and then compared with the experimental data. The correlations were found to be quite reasonable (R2 = 0.89) for all the mixtures tested and can be used to estimate the compressive strengths for similar AAB mixtures.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2011.11a
• /
• pp.105-106
• /
• 2011

The present tests examined the resistance to freezing and thawing of alkail-activated (AA) slag concrete having compressive strength between 30~56 MPa. To enhance the compressive strength and resistance to freezing and thawing of AA slag concrete, Na ions were used for an activator. Test results revealed that the resistance to freezing and thawing of AA slag concrete is comparable to that of cement concrete when compressive strength is more than 50 MPa.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2008.11a
• /
• pp.613-616
• /
• 2008

Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. Instead, the source of material such as fly ash and blast slag, that are rich in Silicon(Si) and Aluminium(Al), are activated by alkaline liquids to produce the binder. Hence concrete with no cement is effect reduction of CO$_2$ gas. In this study, we investigated the influence of the workability and compressive strength of mortar on water reducing agent, alkaline activator and curing method in oder to develop cementless blast slag based alkali-activated mortar. In view of the results, we found out that the flowability of mortar was lowered as increasing to mole concentration of NaOH, but not large the loss of flowability to 9M NaOH, most of water reducing agent was not effect. The compressive strength was improved as increasing to mole concentration of NaOH, was the most effect in 9M NaOH. The curing temperature and curing conditions on compressive strength of blast slag based alkali-activated mortar didn't influence.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.6 no.1
• /
• pp.63-71
• /
• 2011

Portland cement production is under critical review due to high amount of $CO_2$ gas released to the atmosphere. Attempts to increase the utilization of a by-products such as fly ash and ground granulated blast-furnace slag to partially replace the cement in concrete are gathering momentum. But most of by-products is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. In this study, we investigated the influence of alkali activator and superplasticizer on the flowability and compressive strength of the alkali-activated mortar in oder to develop cementless alkali-activated concrete using blast furnace slag. In view of the results, we found out that the type and mixture ratio of alkali activator, the type and adding order of superplasticizer results to be significant factors. When cementless alkali-activated mortar using blast furnace slag manufactured with 1:1 the mass ratio of 9M NaOH and sodium silicate, and added superplasticizer before alkali activator in the mixer, we can be secured workability with 180 mm of flow during 1 hours and compressive strength of about 50 MPa under $20^{\circ}C$ curing condition at age of 28days.

• Journal of the Korea Institute of Building Construction
• /
• v.15 no.5
• /
• pp.457-464
• /
• 2015

The alternative material for cement has been attracting attention in construction projects. Especially, the alkali activated slag(hereafter, AAS) concrete is able to use for a structural vertical member because of 40MPa of compressive strength, However, the research about time-dependent deformation such as creep which is important to strength member is insufficient. Therefore, in this study, experiments were performed with respect to time-dependent deformation including the drying shrinkage and creep deformation of AAS concrete. The creep deformed ratio of AAS concrete was more than OPC concrete by approximately 4.3% and the dry shrinkage deformation of AAS concrete was more than OPC concrete by approximately 69%. The large amount of sodium silicate, alkali activator, is added causing temperature crack than promoted drying and drying creep which is confirmed by water ration test and SEM.

• Structural Engineering and Mechanics
• /
• v.75 no.1
• /
• pp.123-131
• /
• 2020

The bond performance of glass fibre reinforced polymer (GFRP) bars and that of steel bars embedded in Alkali Activated Cement (AAC) concrete are analysed and compared using pull-out specimens. The bond failure modes, the average bond strength and the free end bond stress-slip curves are used for comparison. Tepfers' concrete ring model is used to further analyse the splitting failure in ribbed steel bar and GFRP bar specimens. The angle the bond forces make with the bar axis was calculated and used for comparing bond behaviour of ribbed steel bar and GFRP bars in AAC concrete. The results showed that bond failure mode plays a significant role in the comparison of the average bond stress of the specimens at failure. In case of pull-out failure mode, specimens with ribbed steel bars showed a higher bond strength while specimens with GFRP bars showed a higher bond stress in case of splitting failure mode. Comparison of the bond stress-slip curves of ribbed steel bars and GFRP bars depicted that the constant bond stress region at the peak is much smaller in case of GFRP bars than ribbed steel bars indicating a basic bond mechanism difference in GFRP and ribbed steel bars.

• Advances in concrete construction
• /
• v.10 no.3
• /
• pp.221-236
• /
• 2020

To reduce the CO₂ emissions associated with the manufacture of portland cement (PC), an efficient alternative like an alkali-activated binder (AAB) is the requirement of the industry. To promote the use of AAB in construction activities, a practically implementable mix proportion is required. Owing to the several raw ingredients of AAB concrete and their associated uncertainties, partial replacement of PC by AAB may be adopted instead of complete replacement as per industrial requirements. Hence, the present study aims to determine an optimal proportion for partial replacement of PC with AAB and recommend a technique for it based on site conditions. Three modes of partial replacement are followed: combining all the dry ingredients for AAB and PC followed by the addition of the requisite liquids (PAM); combining the PC and the AAB concrete in two horizontal layers (PAH); and two vertical layers (PAV). 28-day old specimens are exposed to 10% v/v solutions of HCl, H₂SO₄, and HNO₃ to evaluate changes in mechanical, physical, and microstructural characteristics through compressive strength, corrosion depth, and microscopy. Based on deterioration in strength and integrity, PAH or PAV can be adopted in absence of acid attack, whereas PAM is recommended in presence of acid attack.

• International Journal of Concrete Structures and Materials
• /
• v.8 no.3
• /
• pp.213-228
• /
• 2014

Alkali-activated binder (AAB) is recently being considered as a sustainable alternative to portland cement (PC) due to its low carbon dioxide emission and diversion of industrial wastes and by-products such as fly ash and slag from landfills. In order to comprehend the behavior of AAB, detailed knowledge on relations between microstructure and mechanical properties are important. To address the issue, a new approach to characterize hardened pastes of AAB containing fly ash as well as those containing fly ash and slag was adopted using scanning electron microscopy (SEM) and energy dispersive X-ray spectra microanalyses. The volume stoichiometries of the alkali activation reactions were used to estimate the quantities of the sodium aluminosilicate (N-A-S-H) and calcium silicate hydrate (CSH) produced by these reactions. The 3D plots of Si/Al, Na/Al and Ca/Si atom ratios given by the microanalyses were compared with the estimated quantities of CSH(S) to successfully determine the unique chemical compositions of the N-A-S-H and CSH(S) for ten different AAB at three different curing temperatures using a constrained nonlinear least squares optimization formulation by general algebraic modeling system. The results show that the theoretical and experimental quantities of N-A-S-H and CSH(S) were in close agreement with each other. The $R^2$ values were 0.99 for both alkali-activated fly ash and alkali-activated slag binders.